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Those disrupt the ozone equilibrium within the atmosphere via. a series of chemical reactions
Chlorofluorocarbons are as there name describes, they're made up of carbon, chlorine and flourine.

the most common is CF2CL2 = Di-chloro, di-flouro methane. The most common CFC.
They're man-made chemicals which were used in a variety of appliances and stuff, the most common was as a refridgerate in refridgerators.

If the ozone layer was depleted, there would be no protective layer to absord the UV rays that the sun outputs, so the UV rays would come straight into earths inner atmosphere and "hit" living organisms.
Now UV rays are known for their genetically destructive properties, it's why people who spend alot of time in the sun can sometimes get skin cancer etc.
     
 
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