Notes

We have designed, fabricated, and characterized a micro-optical beam-shaping device that is intended to optimize the coupling of an incoherent, linearly extended high-power diode laser into a multimode fiber
The device uses two aligned diffractive optical elements (DOEs) in combination with conventional optics. With a first prototype, we achieved an overall efficiency of 28%. Straightforward improvements, such as antireflective coatings and the use of gray-tone elements, are expected to lead to an efficiency of approximately 50%. The device is compact, and its fabrication is suited for mass production at low cost. Seebio Light-Induced Acid Source -optical device, used in a range-finder measurement system, will extend the measurement range. In addition to the direct laser writing technique, which was used for fabrication of the DOEs of the prototype, we applied two other technologies for the fabrication of the micro-optical elements and compared their performance.

The technologies were multiple-projection photolithography in combination with reactive-ion etching in fused silica and high-energy beam-sensitive glass gray-tone lithography in photoresist. We found that refractive-type elements (gray tone) yield better efficiency for large deflection angles, whereas diffractive elements (multilevel or laser written) give intrinsically accurate deflection angles.Transitional adsorption and partition of nonpolar and polar aromatic contaminants by biochars of pine needles with different pyrolytic temperatures.The combined adsorption and partition effects of biochars with varying fractions of noncarbonized organic matter have not been clearly defined. Biochars, produced by pyrolysis of pine needles at different temperatures (100-700 degrees C, referred as P100-P700), were characterized by elemental analysis, BET-N2 surface areas and FTIR. Sorption isotherms of naphthalene, nitrobenzene, and m-dinitrobenzene from water to the biochars were compared. Sorption parameters (N and logKf) are linearly related to sorbent aromaticities, which increase with the pyrolytic temperature.

Sorption mechanisms of biochars are evolved from partitioning-dominant at low pyrolytic temperatures to adsorption-dominant at higher pyrolytic temperatures. The quantitative contributions of adsorption and partition are determined by the relative carbonized and noncarbonized fractions and their surface and bulk properties. The partition of P100-P300 biochars originates from an amorphous aliphatic fraction, which is enhanced with a reduction of the substrate polarity; for P400-P600, the partition occurs with a condensed aromatic core that diminishes with a further reduction of the polarity. Simultaneously, the adsorption component exhibits a transition from a polarity-selective (P200-P400) to a porosity-selective (P500-P600) process, and displays no selectivity with P700 and AC in which the adsorptive saturation capacities are comparable to predicted values based on the monolayer surface Aromaticity of benzene derivatives: an exploration of the Cambridge Structural Technology, Piastow Av. 42, Szczecin, 71-065, Poland.The harmonic oscillator model of aromaticity (HOMA) index, one of the most popular aromaticity indices for solid-state benzene rings in the Cambridge Structural Database (CSD), has been analyzed. The histograms of HOMA for benzene, for benzene derivatives with one formyl, nitro, amino or hydroxy group as well as the histograms for the derivatives with two formyl, nitro, amino or hydroxy groups in ortho, meta and para positions were investigated.

The majority of the substituted benzene derivatives in the CSD are characterized by a high value of HOMA, indicating fully aromatic character; however, the distribution of the HOMA value from 1 to about 0 indicates decreasing aromaticity down to non-aromatic character. Among the benzene derivatives investigated, a significant decrease in aromaticity can be related to compounds with diamino and A comparative study of the aromaticity of pyrrole, furan, thiophene, and their The relative aromaticity of pyrrole, furan, thiophene, and their aza-derivatives has been examined using TRE (topological resonance energy), MRE (magnetic resonance energy), ring current (RC), and ring current diamagnetic susceptibility (χG) methods. The results obtained were compared with results obtained by others who used the energetic method ASE (aromatic stabilization energy), the geometric method HOMA (harmonic oscillator model of aromaticity), of nitrogen atoms on the aromaticity of the aza-derivatives of pyrrole, furan, and thiophene is discussed. An excellent correlation was found between the energetic (TRE, MRE) and magnetic (RC and χG) criteria of aromaticity for all compounds. It was expected that inclusion of a heteroatom would decrease the aromaticity relative to the cyclopentadienyl anion. Our results show that the type of the first heteroatom, which donates two electrons to the system, as well as the number of nitrogen atoms and their positions in the molecule have a strong effect on aromaticity. In general, aromaticity is enhanced when the nitrogen atom is adjacent to the first heteroatom.
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