Notes

The ubiquitously present dissolved organic matter (DOM) greatly influence the efficiency of UV-based technologies due to its reactivity to UV irradiation
In this work, UV-induced changes within three hydrophobic DOM fractions isolated from different surface waters were investigated. Analysis on UV absorbance at 254 nm, electron donating capacity, fluorescence intensity and carbon content revealed small changes in DOM bulk properties associated with the UV-induced photochemical reactions. Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was further used to explore the modification of the molecular distribution based on H/C and O/C ratios, m/z and DBE. The molecular-level investigation revealed that an average of 296 aromatic and lignin-like molecules were degraded, leading to the production of around 306 new molecules. The UV-reactive community were identified as CHO molecules with higher DBE (>10) and carbon number (>25) which could be readily transformed into smaller saturated molecules. Molecules containing nitrogen (N) or sulfur (S) atom, independent of aromaticity and molecular weight (m/z), were also highly UV susceptible and transformed into molecules with larger DBE and m/z.

Possible reaction pathways responsible for the observations were discussed. The results indicated that UV-reactivity and subsequent transformation of DOM are remarkably correlated with its molecular composition and characteristics. Though the changes in bulk properties of DOM following UV irradiation were observed to be very small, the significant alteration in its molecular structures would have a profound impact on the UV-based treatment processes.declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this Mechanisms by which different polar fractions of dissolved organic matter affect sorption of the herbicide MCPA in ferralsol.Experimental Station of Agro-Environment, Ministry of Agriculture, Danzhou Experimental Station of Agro-Environment, Ministry of Agriculture, Danzhou Exogenous dissolved organic matter (DOM) modifies the sorption of 4-chloro-2-methylphenoxyacetic acid (MCPA, a polar herbicide) in soil. However, how the chemodiversity and diverse fractions of DOM affect MCPA sorption is still unknown. Here, DOM was extracted from compost and rice straw; the structure-activity correlations between DOM chemodiversity and their effects on MCPA sorption were investigated by redundancy analysis.

Moreover, the mechanism involved was explored by spectroscopic techniques, microbeam and modeling. DOM mainly affected MCPA sorption by altering soil surface properties and MCPA complexed form. Hydrophobic neutral (HON) and acid insoluble matter (AIM) were the fractions of DOM that most inhibited MCPA sorption through soil pore blockage, and were related to the humic-like substances with high aromaticity and large molecular weight. Chemical Properties and Reactions of 6-butyl-n-hydroxynaphthimide trifluoromethanesulfonic acid (HOA) only showed an intermediate inhibition on the sorption, although the largest competitive sorption occurred. This was because HOA contained abundant aromatic acid and polar groups with moderate polarity. Thus, the reduced effect caused by competitive sorption was partly compensated by the greatest co-sorption by HOA. The hydrophilic matter (HIM) had the weakest inhibition on MCPA sorption, because this fraction was rich in simple sugars, poly- and oligosaccharides, but lacked aryl groups.

The results will aid in the risk assessments and prevention Importance of the structure and micropores of sedimentary organic matter in the sorption of phenanthrene and nonylphenol.Laboratory of Environmental Protection and Resources Utilization, Guangzhou, Provincial Key Laboratory of Environmental Protection and Resources Utilization, Provincial Key Laboratory of Environmental Protection and Resources Utilization, The demineralized fraction (DM), lipid-free fraction (LF), nonhydrolyzable organic carbon fraction (NHC), and black carbon (BC) were isolated from five marine surface sediments, and they were characterized by elemental analysis as well as CO2 and N2 adsorption techniques, respectively. The NHC fractions were characterized using advanced solid-state 13C nuclear magnetic resonance (NMR) and x-ray photoelectron spectroscopy (XPS). Then, the sorption isotherms of phenanthrene (Phen) and nonylphenol (NP) on all of the samples were investigated by a batch technique. The CO2 micropore volumes were corrected for the outer specific surface areas (SSAs) by using the N2-SSA. Significant correlations between the micropore-filling volumes of Phen and NP and the micropore volumes suggested that the micropore-filling mechanism dominated the Phen and NP sorption. Meanwhile, the (O + N)/C atomic ratios were negatively and significantly correlated with the sorption capacities of Phen and NP, indicating that the sedimentary organic matter (SOM) polarity also played a significant role in the sorption process.
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