Notes

Biosensors to the discovery involving organophosphate exposure with a fresh diethyl thiophosphate-specific aptamer.
Widespread dam construction has reduced the hydrological connectivity of catchments of various sizes. Nutrients lost from upper catchments can be intercepted by dams and deposited in reservoir sediments, and this reduces downstream nutrient transportation. Few previous studies have assessed historical nutrient deposition rates (NDRs) in man-made reservoirs. Using 137Cs and 210Pbex deposition chronologies, this paper examines the total nitrogen (TN), total phosphate (TP), and organic matter (OM) concentrations in six sediment cores recovered from Xujiaya reservoir (catchment area 580 km2), provides estimates of historical NDRs by referencing the original capacity curve, and explores temporal changes to the NDR since dam construction. The results show that anthropogenic sources resulted in the increase in nutrient concentrations in the upper parts of the cores, whereas natural sources were the main contributors to nutrient deposition across the whole reservoir. In addition, sediment supply from the catchment was the main source of the nutrients deposited in the reservoir, and the changing patterns of NDRs were overall regulated by sediment yields. The TN, TP, and OM profiles in the six cores, together with the historical NDRs, reflect the pattern of nutrient deposition in the reservoir derived from this agricultural catchment over the past 60 years. The results provide new insight into the effect of dam construction on nutrient deposition at a medium-sized catchment scale against a background of recent environmental change influenced by human activity.In this study, we report on the applicability of passive sampling with Carbopack X adsorbent tubes followed by thermal desorption gas-chromatography-mass spectrometry (TD-GC-MS) to monitor the concentrations of emerging organic contaminants (EOCs) and solvents in ten indoor environments in a conventional and a vocational training school. However, if passive sampling is to be used as a reliable sampling technique, a specific diffusive uptake rate is required for each target compound. Accordingly, the aim of the present study was twofold. The first was to determine the experimental diffusive uptake rates of the target EOCs and solvents in one of the sampling sites of the vocational training school using Carbopack X adsorbent tubes and active sampling as the reference technique. The results showed experimental diffusive uptake rates between 0.46 mL min-1 and 0.94 mL min-1 with RSD % below 5% for the 28 target compounds. The second was to apply the uptake rates obtained experimentally to determine EOCs and solvents in schools. The monitoring results showed that solvents were ubiquitous throughout the conventional school with a concentrations range between 51.93 μg m-3 and 164.6 μg m-3, while EOCs were detected to a lesser extent. Moreover, the concentrations of EOCs in the vocational training school were much higher than those in the conventional school with concentrations of up to 562.9 μg m-3 for solvents and 344.3 μg m-3 for acrylate polymer monomers. After actively sampling for seven days in each school, we concluded that the concentrations of EOCs and solvents found are mostly linked to cleaning products (conventional school) and the activities carried out in the classroom (vocational training school).Toxic elements cause degradation in agricultural land quality. Phytoremediation of polluted sites is the safest technique to sustain ecosystem. Field trial was established to examine the performance of two Atriplex species (A. numularia and A. amnicola) and two traditional forage plants (pearl millet and cowpea) cultivated on polluted sandy soil and clean one. The studied contaminated soil was irrigated with untreated sewage wastewater for more than 60 years and contained Zn, Cu, Pb and Cd levels excessed the permissible limits. The growth of Atriplex plants was not affected by the soil pollution, while the traditional forage plants lost 40-50% of their biomass. The roots biomass of Atriplex plants was higher by 54% than those of cowpea and pearl millet plants. The crude protein (CP) and chlorophyll in the tested species were reduced as a result of soil pollution, but the reduction was higher in pearl millet and cowpea than Atriplex plants. CP in Atriplex plants that were grown in the contaminated soil was reduced by 10%, while in the case of pearl millet and cowpea; the reduction was more than 20%. Atriplex plants were more effective in reducing the metal bioavailability than pearl millet and cowpea. Atriplex plants were able to protect the photosynthesis process in the presence of toxic elements; moreover, they produced some substances that increasing the resistance of toxic metal stress such as proline. The cultivation of metal-contaminated soil with Atriplex plants enhanced the soil quality and increased the aggregation and porosity of soil; besides, it reduced the soil salinity and concentration of toxic elements. Cultivation of halophyte and traditional fodder plants in contaminated lands is a good strategic management of the ecosystem, and the resulting plant may be used to feed animals due to their low content of pollutants or be recycled to soil organic amendments.This article presents investigations into the removal of PO4-P from biologically treated wastewater using raw material taken from drinking water treatment filters - quartz sand grains coated with iron and manganese oxide coating (OG). The experiments carried out in laboratory stands used real household wastewater and demonstrated that OG filter media accumulated and removed from wastewater two times more PO4-P than known reactive filter media Filtralite P. The mean effectiveness of PO4-P removal from wastewater by filtering at a rate of 2.2 m/h and using OG filter media reached 68%. The pH of the filtrate from OG filter media was stable and reached 7.7 ± 0.2 thus meeting requirements for the discharge of treated wastewater into the natural environment. OG grains are mechanically resistant, do not pollute the filtrate and could therefore be used as filter media for tertiary wastewater treatment.To avoid potential risks of biofuels on the environment and human, ecotoxicity investigation should be integrated into the early design stage for promising biofuel candidates. In the present study, a green toxicology testing strategy combining experimental bioassays with in silico tools was established to investigate the potential ecotoxicity of biofuel candidates. Experimental results obtained from the acute immobilisation test, the fish embryo acute toxicity test and the in vitro micronucleus assay (Chinese hamster lung fibroblast cell line V79) were compared with model prediction results by ECOSAR and OECD QSAR Toolbox. Both our experimental and model prediction results showed that 1-Octanol (1-Oct) and Di-n-butyl ether (DNBE) were the most toxic to Daphnia magna and zebrafish among all the biofuel candidates we investigated, while Methyl ethyl ketone (MEK), Dimethoxymethane (DMM) and Diethoxymethane (DEM) were the least toxic. Moreover, both in vitro micronucleus assay and OECD QSAR Toolbox evaluation suggested that the metabolites present higher genotoxicity than biofuel candidates themselves. Overall, our results proved that this green toxicology testing strategy is a useful tool for assessing ecotoxicity of biofuel candidates.The use of cadmium to produce inexpensive jewelry has recently been documented. Governments have adopted varying standards, with US states focused on either total cadmium content or extractable cadmium from children's jewelry, while the European Union has adopted a limit of 100 mg/kg cadmium for all jewelry. This study evaluated 80 items purchased at a discount jewelry store. The objective was to determine prevalence of cadmium in this jewelry, the amount of cadmium released by simulated mouthing or ingestion, and to confirm previous reports that damage to jewelry can increase cadmium release. selleck inhibitor Finally, a modified toxicity characteristic leaching procedure (TCLP) assessed the potential for jewelry to release cadmium after disposal. Thirty-two (40%) items showed detectable cadmium by X-ray fluorescence. Nine high‑cadmium pendants and rings with cadmium content ranging from 31.3 to 89.2% were subjected to extractions simulating mouthing or ingestion. Seven of nine items extracted in dilute saline to simulate mouthing released more than the US recommended maximum of 18 micrograms. Damaged jewelry released more cadmium for most items tested, with one ring yielding an average of 10,600 micrograms. Two pendants small enough to be swallowed were tested using dilute HCl to simulate ingestion. While one pendant did not release cadmium in excess of the US recommended maximum of 200 micrograms even when damaged, the other released an average of 63,100 micrograms after being damaged. Fourteen of fifteen samples of two high cadmium charms extracted using a modified TCLP extraction exceeded the 1.0 mg/L TCLP limit for cadmium, averaging 13.1 and 9.6 mg/L respectively for the two charms. These results demonstrate that high‑cadmium jewelry may pose a serious hazard if mouthed or ingested, and that regulatory standards that do not take into account the potential for increased release of cadmium resulting from damage to jewelry electroplating are inadequate.Economic surveillance for securing water projects driven by non-conventional energy sources is a challenge. The carrying out of these initiatives in economies based on liberalized markets faces governments against the need for guaranteed profits. As water availability has become a relevant global problem, and desalination an energy-intensive demand solution, it is common to combine both kinds of technologies, renewable energy systems and desalination plants. This research investigates the influence of grants, investment rates, and energy and water sales on the commercialization of two desalination technologies. A performance analysis has been carried out taking into account different scenarios. Following this approach, a simulated reverse osmosis desalination plant has been compared with respect to an already granted novel pilot plant. Results show a better fulfilment of the non-economic objectives, and economically profitable not only under certain conditions of conceded grants, and investor's expected benefits but also of sales of water-energy, that highlighted as a limiting factor. The Levelized Cost of Energy might be similar than the Spanish generation means, depending on the cost escalation rate of the loans, and conceded grants. It was found a reduction of 11 euro cents under the average price that could be achieved, for the standard scenario.Protists in aquaculture ponds are key components associated with primary productivity, nutrient cycling, and fish healthy. However, the protist metacommunity diversity, as well as the ecological and environmental factors that structure protist metacommunity in aquaculture ponds remain poorly understood. This study examined protist metacommunities in water and sediment of larval, small juvenile and large juvenile grass carp ponds. The results indicated sediment resuspension became stronger with the increased fish size, which led to high levels of total suspended solids and nitrogen but low levels of phosphate, chlorophyll a and transparency in water. Moreover, sediment resuspension subsequently increased the alpha diversity indexes (i.e., OTU number, Shannon index and Simpson index) of protist communities in water and sediment. Meanwhile, sediment resuspension increased the relative abundance of heterotrophic Ciliophora and Cercozoa, but decreased the relative abundance of autotrophic Chlorophyta, Stramenopiles X, and Ochrophyta.
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