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The high actuation response of soft gel from a graphene oxide/gelatin composite was prepared as an alternative material in soft robotics applications. Graphene oxide (GO) was selected as the electroresponsive (ER) particle. GO was synthesized by modifying Hummer's method at various ratios of graphite (GP) to potassium permanganate (KMnO4). To study the effect of ER particles on electromechanical properties, GO was blended with gelatin hydrogel (GEL) at various concentrations. The electrical properties of the ER particles (GO and GP) and matrix (GEL) were measured. The capacitance (C), resistance (R), and dielectric constant of the GO/GEL composite were lower than those of the GO particles but higher than those of the GEL and GP/GEL composite at the given number of particles. The effects of external electric field strength and the distance between electrodes on the degree of bending and the dielectrophoresis force (Fd) were investigated. When the external electric field was applied, the composite bent toward electrode, because the electric field polarized the functional group of polymer molecules. Under applied 400 V/mm, the GO/GEL composite (5% w/w) showed the highest deflection angle (θ = 82.88°) and dielectrophoresis force (7.36 N). From the results, we conclude that the GO/GEL composite can be an alternative candidate material for electromechanical actuator applications.Textile-reinforced conveyor belts are most widely used in various industries, including in the mining, construction, and manufacturing industries, to transport materials from one place to another. The conveyor belt's tensile strength, which primarily relies on the property of the carcass, determines the area of application of the belt. Selleckchem RSL3 The main aim of the current work was to investigate the influence of vulcanization temperature and duration of the vulcanization process on the tensile properties of the carcass part of the conveyor belt. An extensive experiment was carried out on the tensile properties of woven fabrics that were intended to reinforce conveyor belts by aging the fabrics at the temperature of 140 °C, 160 °C, and 220 °C for six and thirty-five minutes of aging durations. Afterward, the textile-reinforced conveyor belts were produced at vulcanization temperatures of 140 °C, 160 °C, and 220 °C for six and thirty-five minutes of vulcanizing durations. The influence of the vulcanization process parameters on the tensile property of fabrics utilized for the reinforcement of the conveyor belt was analyzed. In addition, the effect of the dipping process of woven fabric in resorcinol-formaldehyde-latex on the tensile property of polyester/polyamide 66 woven fabric (EP fabric) was investigated. The investigation results revealed that the tensile strength of the carcass of the conveyor belt was significantly affected by vulcanization temperature. The conveyor belt vulcanized at 160 °C for 35 min has shown the optimum tensile strength, which is 2.22% and 89.06% higher than the samples vulcanized at 140 °C and 220 °C for 35 min, respectively. Furthermore, the tensile strength and percentage elongation at break of conveyor belts vulcanized at 220 °C were almost destroyed regardless of the vulcanization duration.Lightweight carbon foams with excellent electromagnetic interference (EMI) shielding performance were prepared by carbonization process, using isocyanate-based polyimide foams as carbon precursors. The influence of carbonization temperature and graphene-doping on the morphological, electrical and EMI shielding effectiveness (SE) of corresponding carbon foams was studied in detail. Results showed that the addition of graphene was beneficial to the improvement of electrical conductivity and EMI shielding performance of carbon foams. The electrical conductivity of carbon foams increased with the carbonization temperature which was related to the increase of graphitization degree. Collapse of foam cells was observed at higher carbonization temperatures, which was detrimental to the overall EMI SE. The optimal carbonization temperature was found at 1100 °C and the carbon foams obtained from 0.5 wt% graphene-doped foams exhibited a specific EMI SE of 2886 dB/(g/cm3), which shows potential applications in fields such as aerospace, aeronautics and electronics.A modern scanning electron microscope equipped with a pixelated detector of transmitted electrons can record a four-dimensional (4D) dataset containing a two-dimensional (2D) array of 2D nanobeam electron diffraction patterns; this is known as a four-dimensional scanning transmission electron microscopy (4D-STEM). In this work, we introduce a new version of our method called 4D-STEM/PNBD (powder nanobeam diffraction), which yields high-resolution powder diffractograms, whose quality is fully comparable to standard TEM/SAED (selected-area electron diffraction) patterns. Our method converts a complex 4D-STEM dataset measured on a nanocrystalline material to a single 2D powder electron diffractogram, which is easy to process with standard software. The original version of 4D-STEM/PNBD method, which suffered from low resolution, was improved in three important areas (i) an optimized data collection protocol enables the experimental determination of the point spread function (PSF) of the primary electron beam, (ii) an improved data processing combines an entropy-based filtering of the whole dataset with a PSF-deconvolution of the individual 2D diffractograms and (iii) completely re-written software automates all calculations and requires just a minimal user input. The new method was applied to Au, TbF3 and TiO2 nanocrystals and the resolution of the 4D-STEM/PNBD diffractograms was even slightly better than that of TEM/SAED.The aim of this work was to study the effect of samarium oxide doping on a SrTiO3 perovskite ceramic. After analyzing the data obtained on the morphological features of the synthesized structures, it was found that an increase in the dopant concentration led not only to a change in the morphological features, but also in the density of the ferroelectrics. Using the X-ray diffraction method, it was found that doping with Sm2O3 led to the formation of a multiphase system of two cubic phases of SrTiO3 and Sm2O3. At the same time, an increase in the concentration of Sm2O3 dopant led to a change in the crystallinity degree, as well as deformation of the structure. Evaluation of the efficiency of use of synthesized ferroelectrics as catalysts for purification of aqueous media from manganese showed that an increase in the concentration of Sm2O3 dopant led to an increase in purification efficiency by 50-70%.One of the most commonly applied methods of joining dissimilar materials is gluing. This could be mainly attributed to the applicability of this technique in various industries. The article presents a method of material surface treatment, which increases the shear strength of adhesive joints for lightweight metals such as aluminum with plastics. For this purpose, laser surface microstructuring was performed on each of the selected construction materials. As a result of the performed treatment, the active surface of the glued area was increased, which increased the adhesive strength. The picosecond laser with UV radiation used in the research is TruMicro 5325c with which material can be removed as a result of the cold ablation phenomenon. The applied parameters of the laser device did not cause thermal damage to the surface of the microstructured materials, which was confirmed by microscopic examination. Laser micromachining did not deteriorate the degree of wetting of the tested materials, either, as was confirmed by the contact angle and surface energy measurements with the use of water as the measuring liquid. In investigated cases of microstructure types, the presented method significantly increased the shear strength of the joints formed, as demonstrated by the presented strength test results. Research has shown that created joints with microstructure made according to the described method, are characterized by a significant increase in strength, up to 376%, compared to materials without microstructure. The presented results are part of a series of tests aimed at selecting the operating laser parameters for the implementation of geometric shapes of microstructures which will increase the strength of adhesive joints in selected materials.A clean energy revolution is occurring across the world. As iron and steelmaking have a tremendous impact on the amount of CO2 emissions, there is an increasing attraction towards improving the green footprint of iron and steel production. Among reducing agents, hydrogen has shown a great potential to be replaced with fossil fuels and to decarbonize the steelmaking processes. Although hydrogen is in great supply on earth, extracting pure H2 from its compound is costly. Therefore, it is crucial to calculate the partial pressure of H2 with the aid of reduction reaction kinetics to limit the costs. This review summarizes the studies of critical parameters to determine the kinetics of reduction. The variables considered were temperature, iron ore type (magnetite, hematite, goethite), H2/CO ratio, porosity, flow rate, the concentration of diluent (He, Ar, N2), gas utility, annealing before reduction, and pressure. In fact, increasing temperature, H2/CO ratio, hydrogen flow rate and hematite percentage in feed leads to a higher reduction rate. In addition, the controlling kinetics models and the impact of the mentioned parameters on them investigated and compared, concluding chemical reaction at the interfaces and diffusion of hydrogen through the iron oxide particle are the most common kinetics controlling models.Conventional osteotomy techniques can, in some cases, induce higher stress on bone during implant insertion as a result of higher torque. The aim of the present study was to evaluate and compare the stress exerted on the underlying osseous tissues during the insertion of a tapered implant using different osteotomy techniques through a dynamic finite element analysis which has been widely applied to study biomedical problems through computer-aided software. In three different types of osteotomy techniques, namely conventional (B1), bone tap (B2), and countersink (B3), five models and implants designed per technique were prepared, implant insertion was simulated, and stress exerted by the implant during each was evaluated. Comparison of stress scores on the cortical and cancellous bone at different time points and time intervals from initiation of insertion to the final placement of the implant was made. There was a highly statistically significant difference between B1 and B2 (p = 0.0001) and B2 and B3 (p = 0.0001) groups. In contrast, there was no statistically significant difference in the stress scores between B1 and B3 (p = 0.3080) groups at all time points of implant placement. Overall, a highly significant difference was observed between the stresses exerted in each technique. Within the limitations of our study, bone tap significantly exerted lesser stresses on the entire bone than conventional and countersink type of osteotomy procedures. Considering the stress distribution at the crestal region, the countersink showed lower values in comparison to others.
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