Notes

Recognition of a Prognostic Index According to a Metabolic-Genomic Scenery Investigation regarding Hepatocellular Carcinoma (HCC).
The increase in the number of products containing nanoparticles (NPs) poses a real threat to the environment. Recently, more evidence has been added to predictive models about the presence of NPs in various natural and anthropogenic systems. The acute toxicity of most aquatic NPs has now been well documented. However, data such as the ecotoxicological significance of the long-lasting effects of NPs on the reproductive system and gamete quality of aquatic organisms are still relatively scarce. Therefore, a 10-day experiment was carried out on the sand dollar Scaphechinus mirabilis (Agassiz, 1864) exposed to low (20 and 40 μg/L) concentrations of copper oxide nanoparticles (CuO NPs). An accumulation of copper in tissues and a significant increase in lipid peroxidation product concentrations after exposure to NP were observed. A significant decrease in the fertilization rate was shown at 40 μg/L. No significant changes in embryonic or larval development were found. However, comet analysis results showed a significant increase in DNA damage in spermatozoa exposed to CuO NPs, which may further manifest as negative effects at later developmental stages or in subsequent generations.Sodium pentachlorophenol (NaPCP) is a highly toxic and persistent organic pollutant. With sepiolite as the support, a series of TiO2-Sep nanocomposites (NCs) with different Ti/Sep ratios were developed. The objective was to understand the effect of Ti/Sep ratio on the structure and activity of the NCs in aqueous and soil systems and to evaluate the feasibility of the NCs for in situ soil remediation. The prepared NCs were characterized with XRD, SEM, TEM, and N2 adsorption-desorption, respectively. The results showed that high surface area and good dispersion of TiO2 on sepiolite surface were obtained. The photocatalytic activities in aqueous and soil of the as-developed NCs were examined using NaPCP as a model pollutant. Compared with bare sepiolite and TiO2, the heterogeneous NCs showed significantly higher photocatalytic performance in decomposing NaPCP, and the photocatalytic activities varied with the content of TiO2 in the NCs. In aqueous media, treatment with TiO2-S-30 showed excellent degradation efficiency with about 90% NaPCP decomposed in 140 min. Nevertheless, the sample TiO2-S-20 promotes maximum rate reduction of NaPCP with above 90% within 20-h irradiation in soil. The results indicate that an appropriate Ti/Sep ratio could significantly enhance the activities of NCs on NaPCP remediation and the role of carrier sepiolite is more important in soil media than that in aqueous phase. The excellent performance of the TiO2-Sep in wastewater degradation and soil remediation can be attributed to the synergistic effects between the high photocatalytic activity of TiO2 nanoparticles and the strong adsorption capacity of sepiolite nanofibers. This work revealed that sepiolite adsorption coupled with TiO2 photocatalysis can be one promising technique for in situ remediation of NaPCP-contaminated soil.Biochar has been used to alleviate the contamination of antibiotic resistance genes (ARGs) in soil and to inhibit ARGs transfer from soil to plants. However, the effect of aged biochar on ARGs abundance in soil and ARGs enrichment in plants are scarcely investigated. In this study, a pot experiment was conducted to compare the effects of fresh and aged biochars on the accumulation of five typical ARGs including tetX, tetW, sul2, ermB, and intI1 in a chicken manure-fertilized soil and in pakchoi (Brassica chinensis L.). Results showed that both biochars significantly decreased the abundance of tetW, sul2, and ermB and increased the abundance of tetX and intI1 in soil. However, the accumulation of all tested ARGs in pakchoi were significantly decreased by both biochars. At the lower addition rate (1%), the fresh biochar was superior to the aged biochar in decreasing the accumulation of some genes (tetW, tetX, and sul2) in pakchoi, whereas an opposite tendency was observed for other genes (ermB and intI1). As the addition rate increased to 2%, the difference between the two biochars diminished, and a similar capacity of decreasing ARGs transfer was observed. The reduction in ARGs accumulation in pakchoi was highly related to the type of ARGs, the biochar addition level, and the aging of biochar. Our results provide insights into the naturally aged biochar on the fate of ARGs in a soil-plant system.In this work, two different types of ZnAl-layered double hydroxide (LDH) mixed metal-oxide composites (CeO2 and SnO2) were synthesized and applied for the photodegradation of 4-chlorophenol (4-CP) in wastewater. PBIT The fabricated CeO2/ZnAl-LDH and SnO2/ZnAl-LDH were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, UV-visible diffuse reflectance spectroscopy (UV-vis DRS), and theoretical density functional theory (DFT) calculations, suggesting that the band gaps of the synthesized hybrid composites were much lower than those of traditional ZnAl-LDH. In addition, the photocatalytic activity for 4-CP degradation and reaction kinetics were investigated to evaluate the catalytic behavior of the prepared composites. The results indicated that the photocatalytic process in this case followed a pseudo-first-order kinetic model, and SnO2/ZnAl-LDH illustrated the optimum performance for 4-CP degradation with an efficiency of 95.2% due to its stability and recyclability. Additionally, the reaction mechanism of 4-CP photodegradation was studied over SnO2/ZnAl-LDH; it presented that 4-CP could be oxidized by hydroxyl radicals, holes, and superoxide radicals, where hydroxyl radicals were identified as the dominant active species during the degradation process. Finally, decomposition intermediates were measured to deduce the reaction pathway of 4-CP, and three tentative pathways were proposed and discussed.Green innovation has become a norm and crucial element of success for modern firms. Manufacturing firms come up with alternative ideas to achieve green innovation. This study proposes that green innovation can be enhanced by amalgamating green business strategies and mastering green competencies within a firm. It isolates itself from previous research by focusing on inherent internal competencies, which could bolster green innovation performance. This integration not only helps firms achieve green innovation but could also improve green value co-creation. Meanwhile, green value co-creation will also mediate the relationship between integrated competencies and green innovation. Data has been collected from the managers of original equipment manufacturers within Pakistan via survey. A total of 319 responses were analyzed using partial least squares structural equation modeling, and empirical results support the proposed hypotheses. The study's findings suggest that green competencies coupled with green business strategy positively influence green value co-creation and green innovation. Moreover, green value co-creation elevates firms' green performance and help firms to achieve green innovation. Consequently, theoretical and managerial implications are presented, which adds to this study's significance under the dynamic capability view.Food-energy-water (FEW) systems in the Bohai mega-urban region (MUR) have experienced astonishing changes in recent decades; however, the dynamics of these changes are not fully understood. This study combined an ecological multiscale input-output model and a structural decomposition analysis (SDA) to explore the variation in embodied FEW consumption and its drivers. The results showed that, although almost all sectoral embodied FEW intensities decreased, embodied FEW demands increased by approximately 9.9×108 tons, 4.61×107 TJ and 1.1×1011 m3 over 10-year period. The embodied FEW flow diagrams show that local consumption and trade were strengthened. Urban household consumption, fixed capital formation and exports were the main components affecting the embodied FEW use increases. An SDA revealed that the consumption level effect (∆c) was the dominant contributor that promoted the increase in the Bohai MUR's embodied FEW consumption. The scale effect (∆p) also had a positive effect on the embodied FEW consumption increases. The technological effect (∆e) was the primary contributor to offset the embodied FEW consumption increase. The economic efficiency effect (∆L) and structural effect (∆sd) also contributed to offsetting the total embodied FEW consumption increase. The effect of the change in domestic and foreign imports (∆D and ∆F) impacted the increase in embodied FEW mainly through the change in the embodied FEW intensities and trade volumes. This study identified the changes in FEW systems and highlighted future coping strategies.Phosphorus, a limiting element, is essential for living organisms, but the total amount available is decreasing with its increasing use. This problem can be solved by studying the methods of phosphorus recovery from waste. Phosphorus (P2O5, 13.75%) is abundantly present in cattle manure bottom ash (CMBA), indicating its potential as a source for phosphorus recovery. Herein, phosphorus recovery from CMBA was investigated by acid extraction and precipitation methods. The optimum concentration of sulfuric acid for extraction was 1.4 M, which eluted approximately 90% of the phosphorus contained in CMBA. In the precipitation method, sodium hydroxide and calcium silicate hydrate (CSH, CaSiO3∙nH2O) were used to adjust the solution pH to 4 and 8, where more than 99% of the eluted phosphorus was recovered when the pH was adjusted to 8 using CSH alone. The chemical composition and crystal forms of the recovered precipitates were analyzed using X-ray fluorescence and an X-ray powder diffractometer. The results indicated monetite and brushite were the main crystal forms of precipitates at pH 4, and struvite, hydroxyapatite, and tricalcium phosphate were the main crystal forms at pH 8. The availability of phosphorus in the precipitates was also evaluated by quinoline gravimetric analysis using water and 2% citric acid, and the water-soluble precipitate was less than 35%, whereas it ranged from 65 to 97% in 2% citric acid. This study suggests that CMBA can be used as a promising source to recover phosphorus via acid extraction and precipitation processes.Dissolved oxygen (DO) is an important water quality monitoring parameter of great significance in aquaculture. Accurate prediction of dissolved oxygen can help farmers to take necessary measures in advance to ensure the healthy growth of cultured species. The characteristics of multivariate and long-term correlation of water quality time series in the traditional methods make it difficult to achieve the expected prediction accuracy. To solve this problem, we propose the combined prediction method LSTM-TCN (long short-term memory network and temporal convolutional network). After the preprocessing of time series, the LSTM extracts the features of the series in time dimension, and then combines with TCN to build the fusion prediction model. In this study, we have carried out the DO predictions of LSTM and TCN algorithms separately, followed by the analysis of DO prediction, based on CNN-LSTM and LSTM-TCN combined models. The effects of attention mechanism and window size of historical time on the prediction results were also investigated.
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