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For painless skin penetration, microneedles require optimal geometry due to human skin's inherent elastic properties. The fabrication of desired shape microneedle is very critical. To our knowledge, the polygonal geometry microneedle has not been investigated before. To address this issue, in this communication, we propose a novel cleanroom free fabrication of single metal microneedle with square cross section. The microneedle was fabricated using sputtering technique without any mask or template. The morphological analysis with respect to various sputtering parameters via. Argon (Ar) pipe position, rotating speed, working pressure was discussed in detail. The microneedle geometry, its assisted pain was visualized using finite element analysis (FEM). The theoretical evaluations were subsequently compared with experimentally fabricated microneedle. This is the first step towards more rational design of polygonal microneedle geometry.Flexible in-plane gate SnO₂ nanowire (NW) transistor gated by SiO₂ acting as a solid electrolyte was fabricated on a paper substrate by using a transmission electron microscopy (TEM) Ni grid shadow mask. The operating voltage of in-plane gate SnO₂ NW transistor was down to 1 V because of the large electric-double-layer (EDL) capacitance of the SiO₂ electrolyte layer. Current on/off ratio (Ion/Ioff) and field-effect electron mobility (µEF) as well as subthreshold slope of this device were ~106, 74.7cm²·V-1s-1 and 80 mV·dec-1, respectively. The proposed flexible and low-voltage SnO₂ NW transistors on paper substrate exhibit immense potential for applications in portable and flexible electronic devices.The fabrication of inexpensive nano-gaps is vitally important for the research and application of nanochannel-based devices. This study presents a low-cost and simple method for the fabrication of nano-gaps using thermal evaporation and stripping techniques. The structural morphology of metal films deposited on the convex structures of photoresist by sputtering and thermal evaporation was studied. The effect of angles of thermal evaporation on the width of nano-gaps was investigated. The characteristics of metal film deposited on the convex structures of photoresist and spaces between these convex structures after stripping were investigated, and the adhesive force between the metal film and silicon substrate was also analyzed. Finally, a metal film of Cu was deposited on the convex structures of photoresist by thermal evaporation. After stripping, nano-gaps with a width of 187 nm were fabricated. The method proposed in this paper can be employed to mass-produce two-dimensional nanochannels based devices at low cost.Birnessite-MnO₂ nanoflakes were synthesized via an aqueous oxidation method at 90 °C using Mn(CH₃COO)₂, NaOH, and KMnO₄. The samples' morphology, crystalline structure, and optical property were determined by field emission scanning electron microscopy, X-ray powder diffraction and UV-Vis spectrophotometry. The birnessite-MnO₂ nanoflakes were converted to K x Mn8O16 and Mn suboxides following a decrease in the concentration of KMnO₄ in the reaction. The amount of NaOH in the reaction determined the type of precursor. Without NaOH, the precursor was converted from Mn(OH)₂ to Mn2+ (from Mn(CH₃COO)₂), thereby enabling the synthesis of birnessite-MnO₂ nanoflowers. The formation mechanism of birnessite-MnO₂ nanoflowers and nanoflakes was clarified via the corresponding simulated crystal structures. Evaluation of the synthesized samples confirmed that the birnessite-MnO₂ nanoflakes and nanoflowers exhibited excellent degradation properties.The new wood-plastic nanocomposites (WPC) based on acrylonitrile-butadiene-styrene (ABS) resin was successfully blended with ABS and poplar flour (PF) through a HAAKE rheomix. The mechanical properties of nanocomposites, except for flexural modulus, were reduced after increasing the PF content. SEM photos show the reduction resulting from weak interfacial adhesion between the PF phase and ABS phase. Higher PF content leads to a low thermal stability and a high water absorption ratio. Different coupling agents (CA) were employed to improve the compatibility between PF and ABS. The results suggest that ABS-g-MAH is more effective than POE-g-MAH, EVA and SEBS. Maleic anhydride (MA) was blended in situ with PF and ABS as the reactive compatibilizer and mechanical properties of nanocomposites were improved except impact strength.In this study, microparticles of bionanomaterials were obtained by polyvinylpyrrolidone, montmoril-lonite, and zinc oxide bionanosystems produced through solution intercalation technique combined with a spray-drying process, aiming for possible application as drug delivery systems. The final microparticles obtained were evaluated in terms of their production yield, which varies between 39.2% and 56.9%. Thermal analysis showed no major changes in Tg of the nanocomposites, compared to the pure PVP polymer. Scanning electron microscopy analysis revealed a pseudo-spherical shape and confirmed the micrometric size of the microparticles. Transmission electron microscopy analysis corroborated the embedding of montmorillonite and ZnO within the polymer phase. Nuclear magnetic resonance and X-rays diffraction were used to study the nanoparticles dispersion, indicating a predominant intercalated morphology. This study suggests that the applied methodology is suitable for the high yields synthesis of nanocomposites PVP based microparticles with uniform size and shape, which can be promising for the production of a new drug delivery system.A facile and peculiar synthesis strategy is designed for the fabrication of transparent superhydrophobic surfaces on simple glass substrate. The synthesis methodology comprises of two steps of hydrothermal treatment of cleaned glass substrate with ultrapure water as a solvent followed by coating of 1H, 1H, 2H, 2H-perflourooctyltriethoxysilane (POTS) also by hydrothermal treatment in hydrothermal reactor. The hydrothermal treatment of glass substrate lead to the nanostructured surface morphology consisting of nanofibers and a blend of nanofibers/nanoflakes. Aforesaid nanostructured surface morphology upon hydrophobic coating resulted in superhydrophobic properties, increasing the water contact angle (WCA) from 92.0° to as high as 145.3°. Moreover, the developed synthesis approach also resulted in the optical transparent superhydrophobic glass substrate thus offering an attractive methodology to employ for self-cleaning applications.A gold plating technique with wet chemical solution is widely used to make different metallic colors for various industrial applications. However, it results in environmental pollution due to the generation of contaminated water, and it is also an expensive process. As an alternative approach, it is often desirable to use the Physical Vapor Deposition coating method that does not generate such pollution, and to use cheaper material to imitate gold colors. In this letter, target materials consisting of Ti-Zr alloy are employed to realize tens of nanometers thickness metallic thin film that can produce a metallic color that is close to that of natural gold. TiZrN thin films with a thickness ranging (2,000 to 4,000) nm are formed on a substrate using Arc Ion Plating. The results showed that the thin films exhibited an adhesion force of 50 N or more and a hardness of 1,500 Hv or more under a -100 V bias condition, and various gold colors could be realized by changing the ratio of Ti and Zr element of the alloy target.Tungsten oxide (WO₃) is semiconductor material which can be used for various applications. Especially, one-dimensional (1-D) nanostructured WO₃ shows the high photoelectrochemical (PEC) performance due to high surface area and short transport route of electron-hole pair. The flame vapor deposition (FVD) process is an efficient and economical method for preparation of the 1-D nanos-tructured WO₃ thin film. Molybdenum doping is a well-known method to improve the PEC performance of WO₃ by reducing band gap and increasing electrical property. MMAF In this study, we prepared the 1-D WO₃ nanostructures doped with Mo by FVD single step process. We confirmed that Mo was successfully doped on WO₃ without changing significantly the original nanostructure, crystal structure and chemical bonding state of WO₃ thin film. As a result of PEC measurement, the pho-tocurrent densities of WO₃ thin film with Mo doping were higher by about 1.4 to 2 times (for applied voltage above 0.7 V vs. SCE) than those without Mo doping.In this study, nanotube morphology changes of Ti-xTa-Ag-Pt alloys with Ta content for biomaterials were researched using various experimental instruments. Ti-xTa-Ag-Pt alloys were manufactured in an Ar atmosphere using a vacuum arc-melting furnace with Ta contents of 10 and 50, and then heat-treated at 1100 °C for 1 hr. Nanotube formation of Ti-xTa-Ag-Pt (x = 10, 50 wt%) alloys were performed using a DC power of 30 V in 1.0 M H₃PO₄ + 0.8 wt% NaF electrolyte solution. Surface characteristics were investigated using an optical microscope, X-ray diffractometer, field-emission scanning electron microscope, energy-dispersive X-ray spectroscopy, and Image analyzer (Image J). Ti-10Ta-Ag-Pt alloy had a needle-like structures, and Ti-Ti-50Ta-Ag-Pt showed the mixed structure (equiaxed and needle-like structures). As the Ta content increased, the α-phase decreased and the β-phase increased. The highly ordered nanotubes were formed on the β-phase, whereas disordered nanotubes were formed on needle-like structure of α-phase in Ti-10Ta-Ag-Pt alloy. As the Ta content increases, large and small nanotube diameters became smaller in size. Anatase and rutile phases were formed on the alloy surface. Ta, Ag, and Pt elements were uniformly distributed over the entire surface and at the edge or inside of the nanotube.This study investigated the effects of heat treatment on changes in the nanostructure of amorphous silicon oxycarbide thin films. Hydrogenated amorphous silicon oxycarbide (a-Si0.6C0.3O0.1H) thin films were prepared via plasma-enhanced chemical vapor deposition. The films were subjected to post-deposition heat treatments via microwave-assisted heating, which resulted in the formation of nanocrystals of SiC and Si in the a-Si0.6C0.3O0.1H matrix at temperatures as low as ~800 °C. The crystallization activation energies of SiC and Si were determined to be 1.32 and 1.04 eV, respectively lower than those obtained when the sample was heat-treated via conventional heating (CH). Microwaves can be used to fabricate nanocrystals at a temperature approximately ~300 °C lower than that required for CH. The optical and nanostructural evolutions after post-deposition heat treatments were examined using photoluminescence (PL) and X-ray diffraction. The position of the PL peaks of the nanocrystals varied from ~425 to ~510 nm as the annealing temperature was increased from 800 to 1000 °C. In this study the optical band gap of SiC and Si varied from ~2.92 to ~2.40 eV and from ~2.00 to ~1.79 eV, as the size of the SiC and Si nanocrystals varied with respect to the heating temperature and isothermal holding time, respectively.
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