Notes

Mutual multi-field T1 quantification pertaining to quick field-cycling MRI.
Significantly, TC exhibited the potential of binding with the divalent cation of AGS-EPS and caused the conformation changes of the protein. Therefore, AGS-EPS could resist the TC at a certain concentration range by trapping antibiotics, while over-loaded TC would cause the instability of AGS due to the limited interaction site of AGS-EPS and the destructive effect of antibiotics on AGS-EPS. This study provided a theoretical basis for understanding the interaction mechanism between antibiotics and AGS-EPS and offered a reference for AGS to maintain the stability of granules under the threat of antibiotics.The toxicology of microplastics in combination with other pollutants has attracted widespread attention. In this study, zebrafish were exposed to 3 mg/L polystyrene microplastic, 0.2 mg/L phenanthrene, and a combination of both. Zebrafish microplastic uptake, phenanthrene accumulation, antioxidant-associated enzyme activity and related gene expression, immune-associated gene expression, and the gut microflora were measured after 12 and 24 days of exposure. Phenanthrene and microplastic accumulation increased with exposure time and was also greater in the combined exposure group than in the single exposure group. Combined analysis of antioxidant enzyme activity and immune and antioxidant-related genes shows that exposure alone causes oxidative stress in zebrafish, ultimately increasing immunity and the expression of oxidative stress genes, while combined exposure exacerbates these changes. Fusobacteria decreased and Proteobacteria and Bacteroidetes increased in the three exposure groups of gut microorganisms. Overall, our study demonstrates that microplastics enhance the toxicity of phenanthrene and that the two have a synergistic effect.There is growing evidence that ecosystem services and especially the exposure to the natural world (blue-green spaces) have potential benefits for mental health and well-being. The COVID-19 pandemic and the measures adopted to control it provide a natural experiment to investigate the links between nature exposure and mental health under extreme conditions. Using a survey distributed online, we tested the following hypotheses 1) People will show greater symptoms of depression and anxiety under lockdown conditions that did not allow contact with outdoor nature spaces; 2) Where access to public outdoor nature spaces was strictly restricted, (2a) those with green/blue nature view or (2b) access to private outdoor spaces such as a garden or balcony will show fewer symptoms of depression and anxiety, and a more positive mood. Based on 5218 responses from 9 countries, we found that lockdown severity significantly affected mental health, while contact with nature helped people to cope with these impacts, especially for those under strict lockdown. People under strict lockdown in Spain (3403 responses), perceived that nature helped them to cope with lockdown measures; and emotions were more positive among individuals with accessible outdoor spaces and blue-green elements in their views. These findings can help decision-makers in developing potential future lockdown measures to mitigate the negative impacts, helping people to be more resilient and maintain better mental health, using the benefits that ecosystem services are providing us.Despite increasing interests in osmotic membrane bioreactors, the information regarding the bacterial toxicity effects of reversely transported draw solute (RTDS) is limited. In this study, two representative draw solutes (NaCl and MgCl2) were used at different concentrations (0, 2.5, 5.0, 7.5 and 10.0 g/L) to evaluate their toxicity in a continuous nitrifying bioreactor. Notably, Mg2+ selectively inhibited the activity of ammonia-oxidizing bacteria (AOB), which decreased to 11.3% at 7.5 g-Mg2+/L. The rRNA-based analysis was more effective than the rDNA-based analysis to elucidate the relationship between active communities of nitrifying bacteria and the actual nitrifying performance. Nitrosomonas europaea, a representative AOB, was vulnerable to Mg2+ in comparison to Na+. In contrast, the dominant nitrite-oxidizing bacteria (NOB), Nitrobacter winogradskyi and Nitrolancea hollandica, maintained a relevant level of relative abundance for achieving nitrite oxidation after exposure to 10 g/L Na+ and Mg2+. This fundamental inhibition information of the draw solute can be applied to set the operational regime preventing the critical solute concentration in mixed liquor of nitrifying OMBRs.Interspecies interaction is an essential mechanism for bacterial communities to develop antibiotic resistance via horizontal gene transfer. Nonetheless, how bacterial interactions vary along the environmental transmission of antibiotics and the underpinnings remain unclear. To address it, we explore potential microbial associations by analyzing bacterial networks generated from 16S rRNA gene sequences and functional networks containing a large number of antibiotic-resistance genes (ARGs). Antibiotic concentration decreased by more than 4000-fold along the environmental transmission chain from manure samples of swine farms to aerobic compost, compost-amended agricultural soils, and neighboring agricultural soils. Akt inhibitor Both bacterial and functional networks became larger in nodes and links with decreasing antibiotic concentrations, likely resulting from lower antibiotics stress. Nonetheless, bacterial networks became less clustered with decreasing antibiotic concentrations, while functional networks became more clustered. Modularity, a key topological property that enhances system resilience to antibiotic stress, remained high for functional networks, but the modularity values of bacterial networks were the lowest when antibiotic concentrations were intermediate. To explain it, we identified a clear shift from deterministic processes, particularly variable selection, to stochastic processes at intermediate antibiotic concentrations as the dominant mechanism in shaping bacterial communities. Collectively, our results revealed microbial network dynamics and suggest that the modularity value of association networks could serve as an important indicator of antibiotic concentrations in the environment.The chemical analysis of tree rings has attracted the interest of researchers in the past five decades in view of the possibility of exploiting this biological indicator as a widely available, high-resolution environmental archive. Information regarding the surrounding environment can be derived either by directly measuring environmental variables (nutrient availability, presence of pollutants, etc.) or by exploiting proxies (e.g. paleoclimatic and paleoenvironmental reconstructions). This review systematically covers the topic and provides a critical view on the reliability of dendrochemical information. First, we introduce the determinable chemical species, such as major elements, trace metals, isotopic ratios, and organic compounds, together with a brief description of their uptake mechanisms and functions in trees. Subsequently, we present the possibilities offered by analytical techniques in the field of tree ring analysis, focusing on direct methods and recent developments. The latter strongly improved ctives related to the advancements in analytical instrumentation and further extension of application fields.Benzotrifluoride (BTF) and its derivatives (BTFs) were found in the groundwater of the Veneto region (Italy) as a result of industrial contamination dating back to the 1970s. In the first survey, BTF and 6 BTFs were identified, out of which 4-chloro-3nitrobenzotrifluoride (3N4CBTF) was the only quantified analyte (concentration up to 1 mg L-1) and was used to trace the contamination plume. A survey carried out in 2008-2009 after the development of more suitable analytical procedures based on GC-MS, allowed to determine 4 new derivatives in addition to BTF and BTFs previously identified, with the most abundant compounds found at concentrations up to 11.9 μg L-1 and 7.2 μg L-1 respectively. A systematic monitoring program for the evaluation of persistence and distribution of fluorinated compounds was carried out in 2013-2018, and new data about the BTF and BTFs occurrence and distribution were gathered. Additional BTFs were identified and high concentrations of individual BTFs were recorded near the contamination source (e.g. 20.3 μg L-1 of 4-chloro-3-nitrobenzotrifluoride in 2017) as well as at large distance (e.g. 22.4 μg L-1 of 3N4CBTF and 12.5 μg L-1 of 4-chlorobenzotrifluoride in 2018). The results of BTFs monitoring campaigns carried out in 2008-2009 and 2017-2018 are compared and related to the historical data to assess the overall occurrence and distribution of BTFs contamination over a time range of ∼40 years. Remarkably, BTFs were still found (2018) at μg L-1 range. Spatial and temporal occurrence of BTF and BTFs in groundwater has been assessed for the first time.The consecutive application of herbicide acetochlor has resulted in the widespread drug resistance of weeds and the high risks to environment and human health. To assess environmental behaviors and minimal dosage of acetochlor application in the realistic soil, we systematically investigated the acetochlor adsorption/desorption, mobility, leaching, degradation, weed bioavailability and lethal dosage of acetochlor in three soil types including Nanjing (NJ), Yancheng (YC) and Yingtan (YT). Under the same conditions (60% moisture and darkness), acetochlor had a half-life of disappearance 3 days in NJ, 4.9 days in YC and 25.7 days in YT soils. The HRLC-Q-TOF-MS/MS analyses identified ten metabolites and eight conjugates generated through dealkylation, hydroxylation, thiol conjugation and glycosylation pathways. The acetochlor adsorption to soils ranked in the order of YT > YC > NJ and was committed to the Freundlich model. By examining the effects of soil moisture, microbial activity, illumination/darkness, etc. on acetochlor degradation in soils, we showed that the chemical metabolisms could undergo multiple processes through soil microbial degradation, hydrolysis or photolysis-mediated mechanisms. The longitudinal migration assay revealed that acetochlor leaching ability in the three soils was YT > YC > NJ, which was negatively associated with the order of adsorption behavior. Four kinds of weed were grown in the acetochlor-contaminated NJ soil. The lethal concentrations for the weed plantlets were 0.16-0.3 mg/kg, much lower than the dosage of realistic field application. Overall, our work provided novel insights into the mechanism for acetochlor behaviors in soils, the natural degradation process in the environment, and the lethal concentration to the tested weed plants.The rapid development of industrialization and urbanization results in a numerous production of various organic chemicals to meet the increasing demand in high-quality life. During the synthesis and utilization of these chemical products, their residues unavoidably emerged in environments to severely threaten human's health. It is thus urgent to exploit effective technology for readily removing the organic pollutants with high selectivity and good reusability. As one of the most promising approaches, molecular imprinting technology (MIT) employs a chemically synthetic route to construct artificial recognition sites in highly-crosslinked matrix with complementary cavity and functional groups to target species, which have been attracting more and more interest for environmental remediation, such as the selective adsorption/separation and improved catalytic degradation of pollutants. In this review, MIT is first introduced briefly to understand their preparing process, recognition mechanism and common imprinted systems.
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