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This suggests that the spin state of the metal ion is the key to tuning the MR effect.As a vital antioxidant molecule, H2S can make an important contribution to regulating blood vessels and inhibiting apoptosis when present at an appropriate concentration. Higher levels of H2S can interfere with the physiological responses of the respiratory system and central nervous system carried out by mammalian cells. This is associated with many illnesses, such as diabetes, mental decline, cardiovascular diseases, and cancer. Therefore, the accurate measurement of H2S in organisms and the environment is of great significance for in-depth studies of the pathogenesis of related diseases. In this contribution, a new coumarin-carbazole-based fluorescent probe, COZ-DNBS, showing a rapid response and large Stokes shift was rationally devised and applied to effectively sense H2S in vivo and in vitro. Upon using the probe COZ-DNBS, the established fluorescent platform could detect H2S with excellent selectivity, showing 62-fold fluorescence enhancement, a fast-response time ( less then 1 min), high sensitivity (38.6 nM), a large Stokes shift (173 nm), and bright-yellow emission. Importantly, the probe COZ-DNBS works well for monitoring levels of H2S in realistic samples, living MCF-7 cells, and zebrafish, showing that COZ-DNBS is a promising signaling tool for H2S detection in biosystems.The usage of aqueous lubricants in eco-friendly bio-medical friction systems has attracted significant attention. Several bottle-brush polymers with generally ionic functional groups have been developed based on the structure of biological lubricant lubricin. However, hydrophilic nonionic brush polymers have attracted less attention, especially in terms of wear properties. We developed bottle-brush polymers (BP) using hydrophilic 2-hydroxyethyl methacrylate (HEMA), a highly biocompatible yet nonionic molecule. The lubrication properties of polymer films were analyzed in an aqueous state using a ball-on-disk, which revealed that BPHEMA showed a lower aqueous friction coefficient than linear poly(HEMA), even lower than hyaluronic acid (HA) and polyvinyl alcohol (PVA), which are widely used as lubricating polymers. Significantly, we discovered that the combination of HA, PVA, and BPHEMA is demonstrated to be essential in influencing the surface wear properties; the ratio of 1  2 (HA  BPHEMA) had the maximum wear resistance, despite a slight increase in the aqueous friction coefficient.We have examined the electronic structure and optical properties of intermetallic IrSn4 for three polymorphic modifications, α-IrSn4, β-IrSn4, and γ-IrSn4, utilizing the first-principles PAW-PBEsol-GGA and FP-LAPW-LSDA methods. The obtained electronic structure data reveal clear-cut differences between α-IrSn4 and the remaining morphs. This observation may be used to explain the appearance of superconductivity in β-IrSn4, and also provides reasonable grounds to suspect eventual superconductivity in γ-IrSn4. Therefore, it is highly desirable to carry out extended measurements on γ-IrSn4 at lower temperatures.Prevention of residual ridge resorption is important for tooth socket healing in clinical treatment. As a well known biomaterial, titanium dioxide (TiO2) has been reported to show desirable bone regeneration capability. On the other hand, strontium plays a role in maintaining normal function in organisms and balancing bone remodeling. read more Hence, we synthesized strontium-doped titanium dioxide mesoporous nanospheres functionalized with amino-group using diphenyl diisocyanate. After incorporation with segmented polyurethane, the obtained injectable SPU/Sr-TiO2/MDI nanocomposite adhesive showed satisfactory antibacterial activity and cell nontoxicity. This nanocomposite was used for tooth socket healing, and greatly promoted the formation of new bone tissue in the tooth extraction socket.Two kinds of donor-acceptor π-conjugated copolymer based on poly[N-hexyl-dithieno(3,2-b2',3'-d)pyrrole-2,6-diyl]alt-[isoindigo] (PDTP-IID) and poly[N-hexyl-dithieno(3,2-b2',3'-d)pyrrole-2,6-diyl]alt-[thiazol-2,5-diyl] (PDTP-Thz) were investigated. These copolymers were synthesized via a Stille coupling reaction. The results showed the structure-property relationships of different donor-acceptor (D-A) combinations. The polymer structures and photophysical properties were characterized by 1H NMR, TGA, DSC, UV-vis absorption spectroscopy, AFM, CV, and XRD measurement. Through UV-vis absorption and cyclic voltammetry (CV) measurements, it showed that the copolymers exhibit not only a low bandgap of 1.29 eV and 1.51 eV but also a deep highest occupied molecular orbital (HOMO) of -5.49 and -5.11 eV. Moreover, photovoltaic properties in combination with the fullerene derivatives were investigated. The device based on the copolymers with PC71BM exhibited higher maximum power conversion efficiency and higher maximum short-circuit current density of 0.23% with 1.64 mA cm-2 of PDTP-IIDPC71BM and 0.13% with 1.11 mA cm-2 of PDTP-ThzPC71BM than those of the copolymers with PC61BM. Measurements performed for N-hexyl-dithieno(3,2-b2',3'-d)pyrrole-based copolymers proved the potential of these polymers to be applied in optoelectronic applications.The modification of silicon nanoparticles for lithium-ion battery anode materials has been a hot exploration subject in light of their excellent volume buffering performance. However, huge volume expansion leads to an unstable solid electrolyte interface (SEI) layer on the surface of the silicon anode material, resulting in short cell cycle life, which is an important factor limiting the application of silicon nanoparticles. Herein, a dual protection strategy to improve the cycling stability of commercial silicon nanoparticles is demonstrated. Specifically, the Si/s-C@TiO2 composite was produced by the hydrothermal method to achieve the embedding of commercial silicon nanoparticles in spherical carbon and the coating of the amorphous TiO2 shell on the outer surface. Buffering of silicon nanoparticle volume expansion by spherical carbon and also the stabilization of the TiO2 shell with high mechanical strength on the surface constructed a stable outer surface SEI layer of the new Si/s-C@TiO2 electrode during longer cycling. In addition, the spherical carbon and lithiated TiO2 further enhanced the electronic and ionic conductivity of the composite. Electrochemical measurements showed that the Si/s-C@TiO2 composite exhibited excellent lithium storage performance (780 mA h g-1 after 100 cycles at a current density of 0.2 A g-1 with a coulombic efficiency of 99%). Our strategy offers new ideas for the production of high stability and high-performance anode materials for lithium-ion batteries.Singlet oxygen (1O2) is a promising reactive species for the selective degradation of organic pollutants. However, it is difficult to generate 1O2 from H2O2 activation with high efficiency and selectivity. In this work, a graphene-supported highly dispersed cobalt catalyst with abundant Co-N x active sites (Co-N-graphene) was synthesized for activating H2O2. The Co-N-graphene catalyzed H2O2 reaction system selectively catalyzed 1O2 production associated with the superoxide radical (O2˙-) as the critical intermediate, as proven by scavenger experiments, electron spin resonance (ESR) spin trapping and a kinetic solvent isotope effect study. This resulted in excellent degradation efficiency towards the model organic pollutant methylene blue (MB), with an outstanding pseudo-first-order kinetic rate constant of 0.432 min-1 (g Lcatalyst -1)-1 under optimal reaction conditions (C H2O2 = 400 mM, initial pH = 9). Furthermore, this Co-N-graphene catalyst enabled strong synergy with HCO3 - in accelerating MB degradation, whereas the scavenger experiment implied that the synergy herein differed significantly from the current Co2+-HCO3 - reaction system, in which contribution of O2˙- was only validated with a Co-N-graphene catalyst. Therefore, this work developed a novel catalyst for boosting 1O2 production from H2O2 activation and will extend the inventory of catalysts for advanced oxidation processes.Identifying the limiting processes of electroactive biofilms is key to improve the performance of bioelectrochemical systems (BES). For modelling and developing BES, spatial information of transport phenomena and biofilm distribution are required and can be determined by Magnetic Resonance Imaging (MRI) in vivo, in situ and in operando even inside opaque porous electrodes. A custom bioelectrochemical cell was designed that allows MRI measurements with a spatial resolution of 50 μm inside a 500 μm thick porous carbon electrode. The MRI data showed that only a fraction of the electrode pore space is colonized by the Shewanella oneidensis MR-1 biofilm. The maximum biofilm density was observed inside the porous electrode close to the electrode-medium interface. Inside the biofilm, mass transport by diffusion is lowered down to 45% compared to the bulk growth medium. The presented data and the methods can be used for detailed models of bioelectrochemical systems and for the design of improved electrode structures.For a long time, people have been eager to realize continuous real-time online monitoring of biological compounds. Fortunately, in vivo electrochemical biosensor technology has greatly promoted the development of biological compound detection. This article summarizes the existing in vivo electrochemical detection technologies into two categories microdialysis (MD) and microelectrode (ME). Then we summarized and discussed the electrode surface time, pollution resistance, linearity and the number of instances of simultaneous detection and analysis, the composition and characteristics of the sensor, and finally, we also predicted and prospected the development of electrochemical technology and sensors in vivo.A precursor diblock copolymer with a silicon backbone, polystyrene-block-poly(methylvinylsiloxane), was synthesized, and 1H,1H,2H,2H-perfluorodecanethiol was quantitatively introduced into the backbone via a thiol-ene reaction to yield a novel coil-rod diblock copolymer, poly(styrene-block-poly(2-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)thio)ethyl)methylsiloxane). The ultra-hydrophobicity of the introduced perfluoroalkyl side chain enhanced the segregation between counter-blocks and significantly increased the χ value, which is essential for minimizing the size of self-assembled domains for lithographic applications. Thus, self-assembled domains with a minimal spacing of approximately 10 nm were formed. A hexagonally packed array with significant anisotropy was observed in the self-assembled morphology by small-angle X-ray scattering and transmission electron microscopy. Such an array was precisely reproduced by modified self-consistent field theory (SCFT) calculation developed for the coil-rod structure. Furthermore, the phase diagram was estimated, and the morphological dependence on the relative scale of the rod unit was investigated by SCFT prediction.In this study, a drug delivery system was prepared by grafting the targeting molecule arginine-glycine-aspartic acid (RGD) onto hyperbranched polyglycerol (HPG)-modified β-cyclodextrin (β-CD-HPG) for the targeted inhibition of nasopharyngeal carcinoma (NPC) cells. The obtained β-CD-HPG-RGD with a relatively small size and low surface charge delivered docetaxel (Doc) effectively and displayed a targeting effect to human NPC HNE-1 cells, as confirmed by confocal laser scanning microscopy and flow cytometry. The in vitro drug release analysis exhibited the controlled drug release kinetics of the β-CD-HPG-RGD/Doc nanomedicine. β-CD-HPG-RGD/Doc effectively inhibited the proliferation of HNE-1 cells and promoted apoptosis. Moreover, its biocompatibility in vitro and in vivo was assessed. The results indicate that the β-CD-HPG-RGD/Doc nanomedicine has potential application in NPC targeting therapy.
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