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Ambient assisted existing systems to aid older adults' overall wellness: an organized maps review.
resource conservation.Electro-catalytic activities of carbonaceous cathodes including graphite plate, graphite felt, carbon felt, activated carbon felt (ACF) and carbon fiber felt (CFF) for degradation of Reactive Red X-3B (RRX-3B) in residual dyeing liquid were compared. The best electrochemical performance was obtained using dimensional stable anode (DSA) and CFF cathode due to the higher capacity for electro-generation of H2O2 by selective two-electron oxygen reduction. The CFF/DSA electrolysis system realized 78.2% COD removal and complete decolorization over a wide pH range. The efficacy of RRX-3B degradation was found to be dependent on the nature of carbonaceous materials. Electrochemical measurements showed that CFF possessed higher electrochemical surface area and hydrogen evolution reaction over-potential. Furthermore, the intrinsic graphitic N in CFF was proved to be catalytic active site by DFT calculations. Reactive Red X-3B degradation intermediates with benzene structures and carboxylic acids via hydroxylation in RRX-3B oxidation were identified by GC-MS. It was found that S/Cl/N-containing groups in RRX-3B molecule were mineralized to SO42-, NO3- and Cl- ions in the electrolysis.
To evaluate the influence of hydrophilicity on the surface integrity of implants after insertion in low-density artificial bone and to determine the distribution of titanium (Ti) particles along the bone bed.

Forty-eight dental implants with different designs (Titamax Ex, Facility, Alvim, and Drive) and surface treatments (Neoporos® and Aqua™) were inserted into artificial bone blocks with density compatible with bone type III-IV. Hydrophobic Neoporos® surfaces were obtained by sandblasting and acid etching while hydrophilic Aqua™ surfaces were obtained by sandblasting, acid etching, and storage in an isotonic 0.9% NaCl solution. The surface integrity was evaluated by Scanning Electron Microscope (SEM) and the surface roughness parameters (Sa, Sp, Ssk, Sdr, Spk, Sk, and Svk) and surface area were measured with Laser Scanning Confocal Microscopy before and after installation. Bone beds were inspected with Digital Microscopy and micro X-Ray Fluorescence (μ-XRF) to analyze the metallic element distribution a alterations, resulting in more Ti particle release into the bone bed during surgical insertion. The higher Ti intensities detected in the cervical region of bone beds may be related to peri-implantitis and marginal bone resorption.
Mechanical damages can occur from dental restoration processing and fitting, or while it is in-service. This study evaluates the damage sensitivity of translucent zirconia (5Y-PSZ) relative to conventional 3Y-PSZ following mouth-motion simulations at various loads.

5Y-PSZ and 3Y-PSZ discs were adhesively bonded to a dentin-like substrate and divided into groups according to the load (50 N or 200 N) and number of cycles (up to 10
) used in the chewing simulation. Specimens were mounted with 30° inclination in an electrodynamic mouth-motion simulator, and subjected to contact-slide-liftoff cyclic loading in water. Surface and sub-surface damages were analyzed using a sectioning technique. After the simulation, specimens were removed from the substrate and loaded with the damaged surface in tension for biaxial strength testing to assess their damage tolerance.

The strength of both ceramics underwent significant degradation after mouth-motion simulations. For 5Y-PSZ, the strength degradation was greater (∼60%) and occurred at a lower number of cycles than 3Y-PSZ. Herringbone cracks emerged on 3Y-PSZ and 5Y-PSZ surfaces under a 200-N load after 50 and 10 cycles, respectively. Meanwhile at a 50-N load, cracks formed at ∼1000 cycles in both ceramics. Further increasing the number of cycles only had moderate effects on the strength of both ceramics, despite an increase in surface and sub-surface damage. More significantly, a 50-N occlusal load can debase the zirconia strengths as much as a 200-N load.

Surface flaws produced during the chewing simulation are capable of significant strength degradation in zirconia, even after a small number of low-load cycles.
Surface flaws produced during the chewing simulation are capable of significant strength degradation in zirconia, even after a small number of low-load cycles.Four solidification methods for self-emulsifying drug delivery systems (SEDDS) were compared to evaluate the impact of solidification on storage stability of an incorporated protein. Papain was loaded in SEDDS via hydrophobic ion pairing (HIP). Liquid SEDDS (l-SEDDS) were either solidified by adsorption to solid excipients such as magnesium-aluminometasilicate via wet granulation (ssilica-SEDDS) and carbohydrates via lyophilisation (scarbo-SEDDS) or by incorporation of high-melting PEG-surfactants (sPEG-SEDDS) and triglycerides (soil-SEDDS) in SEDDS preconcentrates. L- and s-SEDDS were compared regarding intrinsic emulsion properties, solid-state form of papain, enzyme stability and activity during storage. HIP with deoxycholate showed a precipitation efficiency of 82% and papain maintained 90% of its initial activity. Incorporated papain was present in an amorphous state, confirming a molecular dispersion in all preconcentrates. In comparison to l-SEDDS each solidification method investigated improved the storage stability of incorporated papain. Neither precipitation nor phase separation was observed for s-SEDDS. sPEG-SEDDS demonstrated with 87.8% the highest enzymatic activity and displayed according to the following rank order sPEG-SEDDS > soil-SEDDS > ssilica-SEDDS > scarbo-SEDDS > l-SEDDS the highest remaining papain activity after 30 days of storage. This work clearly demonstrates that solidified SEDDS can provide a significantly improved storage stability for therapeutic proteins compared to corresponding liquid formulations.Finely engineering the morphology and regulating the hybrid interface of each component in a heterojunction are important for facilitating charge carrier separation. In this study, a flower-like bismuth oxycarbonate/bismuth oxybromide (Bi2O2CO3/BiOBr, BOC/BiOBr) Z-scheme heterojunction was prepared via generation of BOC followed by in situ self-growth of BiOBr on just generated BOC. The obtained photocatalyst has an interlaced nanosheet structure with oxygen vacancies, which enhances light adsorption and facilitates the migration and separation of charge carriers. The highest apparent rate constants (k) in the degradation of tetracycline and ciprofloxacin using the BOC/BiOBr-2 photocatalyst under visible-light irradiation were 0.0282 and 0.0220 min-1, respectively; these values were 6.1 and 6.2 times, respectively higher than that achieved using BOC as a photocatalyst. The hybrid mode of BOC and BiOBr, and the Z-scheme electron transfer path and oxygen vacancies present in BOC/BiOBr are the factors responsible for its high photocatalytic activity.The search for earth-abundant water oxidation electrocatalysts with low-cost and high-performance is essential to the energy conversion field. Brequinar manufacturer Well defined, rational designed two-dimensional materials have attracted enormous interest in light of much more specific surface areas and unique electronic properties. Herein, we report a facile two-phase solvothermal approach for the synthesis of Fe doped amorphous single-layered (~0.85 nm) vanadyl phosphate nanosheets (Fe-Am VOPO4). The obtained electrocatalyst exhibits excellent OER electrocatalytic performance, only require overpotential of 215 mV and 270 mV to reach current densities of 10 and 100 mA cm-2 in 1.0 M KOH electrolyte, and long-term electrochemical stability of 40 h. This work strikes out a path of synthesis of graphene-like materials with amorphous phase, and explores a new type of phosphate for efficient OER electrocatalysts.The design of electrocatalysts with lower overpotential is of great significance for water splitting. Herein, cobalt hydroxide carbonate (CCH) has been used as a model to demonstrate the boost of its oxygen evolution reaction (OER) activity by atomic doping of W6+ (W-CCH). The 5 at % W doping reduced the OER overpotential of CCH by 95.3 mV at 15 mA cm-2, and increased the current density by 2.8 times at 1.65 V. 5%W-PCCH || 5%W-CCH-based electrolyzer only required a potential of 1.65 V to afford 10 mA cm-2 for full water splitting. The W6+ in CCH are active sites for O2- adsorption and induced an incesaed electron density near the Fermi level, which facilitates the charge transfer during electrocatalysis. The W6+ doping has been validated as an efficient booster for transition-metal carbonate hydroxides-based electrocatalysts, which has half or more than half-filled d-bands.Developing structurally stable sorbents for high-temperature H2S direct removal is recognized as a valuable energy-saving strategy for efficient utilization of hot coal gas (HCG), which depends upon their mesoporous features and desulfurization capabilities. Herein, tailored hierarchical CaxCuyMnzOi/MAS-9 sorbents were fabricated via a facile sol-gel method using high-activity phase CaxCuyMnzOi anchored onto versatile mesoporous MAS-9. After O/S-exchange procedure, noteworthy straight channels of MAS-9 (SBET = 808 m2 g-1) provided enough available spaces for the storage of generative large MeSy nanoparticles, which was better than other conventional zeolites. The probing of variables (i.e. support type, active ingredient, loadings, and sulfidation temperature) on H2S removal revealed that 50%Ca3Cu10Mn87Oi/MAS-9 shared an excellent breakthrough sulfur capacity (171.57 mg g-1) at 800 °C, even it experienced six reusable cycles, due to synergistic stabilizing effect of Ca-Cu-Mn and high-temperature tolerance of SiOAl framework of MAS-9. Especially, CaO dopant endowed the sorbent with superficial alkalinity and high-temperature resistance. The brilliant desulfurization behavior was also described by the fast H2S diffusion or component deactivation vs. duration time on stream according to the followed kinetic investigation. Thus, the refined Ca3Cu10Mn87Oi/MAS-9 possesses the expected representative desulfurization nature and great potentiality for raw HCG in practical applications.Evaporation of sessile droplet containing suspension of cellulose nanocrystals (CNC) results on birefringent coffee ring pattern (CR), due to the concentration increase and self-assembly of CNC carried by the flow at the edge of evaporating droplet. In this work, we studied the apparition of Maltese cross pattern, (MC) after addition of an hydrosoluble biopolymer belonging to the hemicellulose family, i.e. arabinoxylan (AX). To investigate the mechanisms that control MC pattern apparition, distribution of the two components inside the dried droplet was investigated using FTIR. CNC and AX were found to be homogenously deposited and CNC self-assembly induces nanoparticles orientation in the CR deposit. We demonstrate that the increase of concentration during drying induces gelation of CNC/AX mixture leading to MC pattern apparition. We take advantage of the apparition of MC pattern to develop a novel catalytic activity detection assay based on the variation of viscosity. Indeed, addition of Endo-1,4-β-Xylanase (Xyl) addition to a suspension containing CNC/AX complex leads to hydrolysis of AX that decrease in droplet viscosity leading to MC disappearance. The enzymatic detection assay is thus simple, easy to handle, fast, sensitive and do not require complex analytical devices.
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