Notes

Non-toxic near-infrared light-emitting diodes.
Currents trends in DI-SDME and possible future direction of the procedure are discussed. Herein, a new magnetic hydrochar was prepared through co-hydrothermal treatment of vinasse with red mud, two abundant industrial wastes, and its adsorption property was evaluated on Pb(II), selected model ion in aqueous solution. During co-hydrothermal process, Fe2O3 species in red mud was reduced to Fe3O4 form, hereby, in situ magnetization of hydrochar was achieved, which was confirmed by characterization studies. YD23 cost Produced hydrochar with porous structure (Vtotal = 0.071 cm3/g and BET surface area = 23 m2/g) had saturation magnetization (44.7 emu/g), providing easier separation from water by a magnet. Maximum Pb(II) adsorption was favored at pH ≥ 5.0 within 120 min of equilibrium time and Freundlich isotherm model was preferable. The contribution percentage of different mechanisms including cation-exchange (40.8 %), (electrostatic attraction + "cation-π" interaction) (31.2 %), precipitation (25.4 %) and complexation (2.6 %) to overall Pb(II) adsorption indicated that cation-exchange was the dominant mechanism. Finally, application to fortified real water demonstrated that in situ magnetic hydrochar produced by suggested approach was successful at adsorptive removal of Pb(II) from water with no matrix effects. Graphene related materials (GRMs) are currently being used in products and devices of everyday life and this strongly increases the possibility of their ultimate release into the environment as waste items. GRMs have several effects on plants, and graphene oxide (GO) in particular, can affect pollen germination and tube growth due to its acidic properties. Despite the socio-economic importance of sexual reproduction in seed plants, the effect of GRMs on this process is still largely unknown. Here, Corylus avellana L. (common Hazel) pollen was germinated in-vitro with and without 1-100 μg mL-1 few-layer graphene (FLG), GO and reduced GO (rGO) to identify GRMs effects alternative to the acidification damage caused by GO. At 100 μg mL-1 both FLG and GO decreased pollen germination, however only GO negatively affected pollen tube growth. Furthermore, GO adsorbed about 10 % of the initial Ca2+ from germination media accounting for a further decrease in germination of 13 % at the pH created by GO. In addition, both FLG and GO altered the normal tip-focused reactive oxygen species (ROS) distribution along the pollen tube. The results provided here help to understand GRMs effect on the sexual reproduction of seed plants and to address future in-vivo studies. This study investigated mercury contamination with respect to the sediment characteristics in Gumu Creek near the Pohang Industrial Complex, South Korea. The contaminated sediment had high levels of Hg, exceeding 250 mg Hg/kg sediment at the sampling position, and high concentrations of iron, sulfur, and organic carbon under extreme anaerobic conditions. The anoxic condition of the sediment produced large amounts of FeS. Hg L3-edge EXAFS analysis revealed that FeS controlled the Hg species in the sediment mainly as β-HgS like precipitation or Hg-S complexation. We also speculated that the presence of FeS induced the abiotic reduction of Hg(II) to Hg(0) and consequently suppressed the formation of highly toxic methylated mercury species. The results obtained in this study are mostly consistent with those reported in previous studies of geochemical reactions of FeS in controlling Hg(II) under pure FeS mineral systems under laboratory scenarios. This study demonstrates that the laboratory controlled reaction scenarios can explain the field behavior of Hg in the contaminated anoxic sediment of the Gumu Creek site. A common method to measure radon exhalation rates relies on the accumulation chamber technique. Usually, this approach only considers one-dimensional gas transport within the soil that neglects lateral diffusion. However, this lateral transport could reduce the reliability of the method. In this work, several cylindrical-shaped accumulation chambers were built with different heights to test if the insertion depth of the chamber into the soil improves the reliability of the method and, in that case, if it could limit the radon lateral diffusion effects. To check this hypothesis in laboratory, two reference exhalation boxes were manufactured using phosphogypsum from a repository located nearby the city of Huelva, in the southwest of Spain. Laboratory experiments showed that insertion depth had a deep impact in reducing the effective decay constant of the system, extending the interval where the linear fitting can be applied, and consistently obtaining reliable exhalation measurements once a minimum insertion depth is employed. Field experiments carried out in the phosphogypsum repository showed that increasing the insertion depth could reduce the influence of external effects, increasing the repeatability of the method. These experiments provided a method to obtain consistent radon exhalation measurements over the phosphogypsum repository. An efficient Sb-doped SnO2 electrode featuring superior electrocatalytic characteristic and long stability was constructed by adopting clustered TiO2 nanotubes-covered Ti mesh as substrate (M-TNTs-SnO2). Compared with the electrodes prepared with mere Ti mesh or Ti plate grew with TiO2 nanotube, the M-TNTs-SnO2 exhibited higher TOC removal (99.97 %) and mineralization current efficiency (44.0 %), and longer accelerated service lifetime of 105 h for electrochemical degradation of phenol. The enhanced performance was mainly ascribed to the introduction of mutually self-supported TiO2 nanotube clusters in different orientations. Such unique structure not only favored a compact and smooth surface of catalyst layer which improved the stability of electrode by reinforcing the binding force between substrate and catalyst layer, but also increased the loading capacity for catalysts, leading to 1.5-2.2 times higher of ·OH generation, the main active species for indirect electrochemical oxidation of phenol. Meanwhile, the transverse electron transfer from TiO2 nanotube to catalyst layer was possibly achieved to further prompt the generation of ·OH. This study may provide a feasible option to design of efficient electrodes for electrocatalytic degradation of organic pollutants. V.
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