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Uranyl nitrate was shown to be rejected from the organic phase as the formation of HNO3·TBP and HNO3·TBP·H2O in acid was extracted at high acid concentrations.Efforts to enhance the transformative potential of biofuels is an important step to achieving an environment-friendly and sustainable energy source. Fremyella diplosiphon is an ideal third-generation biofuel agent due to its ability to produce lipids and desirable essential fatty acids. In this study, the impact of Nanofer 25s nanoscale zero-valent iron nanoparticles (nZVIs) on total lipid content and fatty acid composition of F. diplosiphon strains SF33 and B481 was investigated. We observed significant increases (P less then 0.05) in the growth of F. diplosiphon treated with 0.2-1.6 mg L-1 Nanofer 25s, indicating that trace concentrations of nZVIs were not toxic to the organism. Chlorophyll a, carotenoids, and phycobiliprotein levels were not altered in F. diplosiphon treated with nZVIs ranging from 0.4 to 1.6 mg L-1, confirming that these concentrations did not negatively impact photosynthetic efficacy. In addition, Nanofer 25s ranging from 0.2 to 1.6 mg L-1 had an optimal impact on SF33 and B481 total lipid content. We identified significant increases in unsaturated fatty acid methyl esters (FAMEs) from F. diplosiphon Nanofer 25s-treated transesterified lipids. Theoretical chemical and physical biofuel properties revealed a product with elevated cetane number and oxidative stability for both strains. Scanning electron microscopy and energy-dispersive X-ray spectroscopy validated the localization of nZVIs. Our findings indicate that Nanofer 25s nZVIs significantly enhance F. diplosiphon total lipid content and essential FAMEs, thus offering a promising approach to augment the potential of the cyanobacterium as a large-scale biofuel agent.This study presents a quick, low-cost, and easy technique for the detection of norovirus in several food samples, including cucumber, lettuce, and chicken. The developed sandwich immunoassay method depends on employing nanotechnology for the detection step. Lactoferrin immobilized on activated Q-tips cotton swabs was used as a general capturing reagent to bind viruses from the sample surface. The cotton swabs were then submerged in a gold nanoparticle solution, which had previously decorated with a specific antibody for noroviruses. Positive samples retained the red color of the gold nanoparticles on the surface of Q-tips, even after washing, while the negative control samples easily lost their color through washing. The results confirmed that the developed assay has superior sensitivity and selectivity with a LOD between 10 and 53 pfu/mL for all tested samples. In light of the difficulty, complexity, and high cost of the methods recently used for detecting viruses in food samples, this method presents a promising reliable technique that can be employed for the rapid detection of norovirus in food samples with an acceptable accuracy.Amphiphilic molecules can alter the wettability of soil minerals. To determine how the headgroup chemistry of amphiphiles determines these effects, we investigate a system of the clay montmorillonite with long-chain phospholipids. We use phosphatidylglycerol (PG) phospholipids to contrast with our previous work using phosphatidylethanolamine (PE) lipids. Zwitterionic PE lipids can sorb to the negatively charged montmorillonite surface, whereas negatively charged PG lipids cannot. Employing a suite of techniques from molecular dynamics, atomic force microscopy, fluorescence microscopy, and contact angle measurements, we define sample characteristics from molecular-scale structure to the macroscopic wettability. We find that PG lipids do not significantly alter montmorillonite wetting characteristics, such as the contact angle, flow viscosity, and the characteristic time scale for droplet imbibition. On comparing PE and PG lipid/clay films, we find that, among the phospholipids compared, they must have three characteristics to change clay/lipid film wettability they must bind to the mineral surface, be solid at room temperature, and have a relatively continuous distribution throughout the film.Five new withanolides (1-5) along with five known ones (6-10) were isolated from the whole plants of Physalis minima Linn. The chemical structures of the new compounds were identified as (20S,22R) 15a-acetoxy-5β,6β-epoxy-4β,14a,28-trihydroxy-3β-methoxy-1-oxowitha-16,24-dienolide (1), (20S,22R) 15a-acetoxy-5β,6β-epoxy-3β,4β,14β,17β,20β-pentahydroxy-1-oxowitha-24-enolide (2), (20R,22R) 15α-acetoxy-4β,5α,6β,14α,20β-pentahydroxy-1-oxowitha-2,24-dienolide (3), (20R,22R) 15α-acetoxy-5α,6β,14α,20β-tetrahydroxy-1-oxowitha-2,24-dienolide (4), and (20S,22R) 5α,6β,14β-trihydroxy-1,15-dioxowitha-2,16,24-trienolide (5) on the basis of integration combining IR, UV, HR-ESI-MS, 1D-NMR, and 2D-NMR analyses. Biologically, compounds (1-10) were subjected to evaluate their anti-inflammatory activities via inhibiting nitric oxide production in lipopolysaccharide-stimulated murine RAW 264.7 cells in vitro. The activity screening indicated that all of the compounds showed a moderate inhibitory effect against nitric oxide production with IC50 values of 23.53-66.28 μM.Carbon dots (CDs) as a kind of potential materials have drawn much attention due to their excellent optical properties. However, it is a challenge to fabricate new CDs-based thin films with intelligent responses. Herein, a kind of CDs with mechanical- and basic/acidic vapor-stimulated responsive behaviors was prepared using glutathione as a passivation agent via a one-pot solvothermal reaction. The high solubility of CDs enhanced by glutathione passivation was suitable for the preparation of CDs-based thin film. It is worth noting that the fluorescence of CDs-based poly(methyl methacrylate) (PMMA) thin film can be enhanced under grinding treatment, and it was also sensitive to the presence of ambient acids or bases. These CDs-based films with high stability and excellent mechanical and acid/base responses have great potentials for environmental monitoring.Direct visualization of soft organic molecules like cellulose is extremely challenging under a high-energy electron beam. Herein, we adopt two ionization damage extenuation strategies to visualize the lattice arrangements of the β-(1→4)-d-glucan chains in carboxylated nanocellulose fibers (C-NCFs) having cellulose II crystalline phase using high-resolution transmission electron microscopy. Direct imaging of individual nanocellulose fibrils with high-resolution and least damage under high-energy electron beam is achieved by employing reduced graphene oxide, a conducting material with high electron transmittance and Ag+ ions, with high electron density, eliminating the use of sample-specific, toxic staining agents, or other advanced add-on techniques. Furthermore, the imaging of cellulose lattices in a C-NCF/TiO2 nanohybrid system is accomplished in the presence of Ag+ ions in a medium revealing the mode of association of C-NCFs in the system, which validates the feasibility of the presented strategy. The methods adopted here can provide further understanding of the fine structures of carboxylated nanocellulose fibrils for studying their structure-property relationship for various applications.The presence of marine pollution in Cartagena Bay (Colombia) is an alarming environmental issue because of the ecotoxicological properties of contaminants such as polycyclic aromatic hydrocarbons (PAHs) that may affect the biodiversity of coastal ecosystems. In this sense, there is a need to propose alternatives to remediate the environmental pollution of such bodies of water. The aim of this work was to design an adsorption-based treatment process for the removal of PAHs from seawater and sediments. Two design cases were considered (i) a base process without a PAH desorption unit and (ii) an alternative process including a PAH desorption unit. Both designs were simulated using Aspen Plus to obtain mass and energy balances. A parametric sensitivity analysis was carried out to determine optimum operating conditions for solvent recovery and treatment efficiency. The pressure and temperature of evaporators were selected as key parameters, as well as PAH loads in the influent. The environmental performance of base and alternative designs was also evaluated via waste reduction algorithm (WAR) methodology. A maximum recovered solvent flow rate was found when the evaporator operates at 56 °C and 0.81-0.83 atm. In addition, the total generation rate of potential environmental impacts (PEI) reported negative values for cases 1, 3, and 4 (-9.80 × 10-1, -9.25 × 10+1, -1.19 × 10+1, and 1.04 × 10+1 PEI/h). The major concern derived from this analysis is the high environmental impacts reached by the photochemical oxidation potential (PCOP) category associated with the use of hexane and acetone as solvents during PAH removal from sediments. In general, both designs of seawater and sediment treatment seem to be an environmentally friendly alternative for marine pollution remediation.Depleted uranium (DU) is an emerging heavy metal pollutant with considerable environmental and occupational concerns. Its radiotoxicity is known to be low. However, its chemical toxicity should not be ignored. In order to explore the chemical toxicity of DU, the effects of uranyl nitrate, prepared from DU, on the model organism Caenorhabditis elegans were investigated. Chronic exposure to DU did not affect the lifespan or reproduction of the worm. Gandotinib purchase DU had little effect on the physiological processes of C. elegans. Additionally, DU treatment did not make C. elegans more susceptible to UV, heat, or oxidative stress. Interestingly, chronic exposure of DU decreased the in vivo reactive oxygen species-scavenging ability through inhibiting the expression of antioxidant genes ctl-1, ctl-2, ctl-3, gst-7, and gst-10. Chronic but not acute exposure of DU induced a statistically significant degeneration of the dopaminergic (DAergic) neurons of treated worms and promoted the increase of α-synuclein aggregation and DAergic neurotoxicity. These findings may raise the public concerns regarding DU as an etiologic agent of Parkinson's disease and underline its potential neurotoxicity.Regulating the states of hydrogen bonds in ionic liquids (ILs) is an effective way to improve their catalytic performance. In this paper, disulfonic-functionalized acidic ionic liquids (DSFAILs) were synthesized successfully, including novel SO3H-functionalized binuclear IL (bis[3-(CH2)3SO3H-1-(CH2)2-Im][HSO4]2). For the biodiesel synthesis, compared with the traditional ILs catalysts, DSFAILs bis[(3-(CH2)3SO3H-1-(CH2)2-Im][HSO4]2, [Im(N (CH2)3SO3H)2][HSO4]) had higher catalytic activity even under mild reaction conditions. Using the density functional theory (DFT) method, the role of hydrogen bonds in different SO3H-functionalized acidic ionic liquids (SFAILs) was explored. The forms of hydrogen bonds existing in different ILs directly determine their acidity. It suggested that the forming status of the active sites (hydrogen bonds) were diverse in different SFAILs. Also, deep ionization of the hydrogen atoms from the cation-anion strong interaction could increase the acidity and catalytic performance of SFAILs.
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