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The simulation predicts a step for the 27.9 Å pore that can be correlated with experimental steps in literature. Finally, the adsorption isotherms of chlorophenols for other activated carbons were predicted with the help of the model.The local thermal property evaluation of pavement materials has not received enough attention, making the implementation of cool material measures to alleviate the urban heat island difficult. This study aims to conduct a control experiment on cool pavement bricks selection from the local market. The surface temperature difference and change characteristics of 28 bricks with different physical properties (i.e. colour, thickness, size and internal structure) were recorded by an infrared thermal imager and thermometers. Comparative analysis shows that the maximum surface temperature of the light-yellow brick is 7.3 °C lower than that of the ash black one, and the maximum surface temperature of hollow bricks is 5.6 °C lower than that of solid bricks. Thick bricks have a slightly low mean and maximum surface temperatures, and large bricks also have a low maximum surface temperature, but only deep coloured bricks. The analysis of variance revealed that for the maximum surface temperature, the three factors (i.e. colour, thickness and internal structure) have an interactive effect; for the mean surface temperature, only the colour and internal structure factors have a significant independent effect. This paper provides a feasible bottom-up cooling scheme for urban underlying surface.One of the most commonly debated concerns regarding foreign direct investment inflows is the associated environmental adversities that accompany the influx of foreign funds. As a result, assessing the environmental impacts of foreign direct investment inflows is necessary for achieving environmentally friendly economic growth in the contemporary era. Accordingly, the global economies including the members of the Group of Twenty (G-20) should focus on attracting clean foreign direct investments. Against this backdrop, controlling for energy consumption and urbanization, this extant study scrutinizes the effects of foreign direct investment inflows on the carbon dioxide emission figures of selected G-20 countries between 1992 and 2018. The econometric analysis conducted in this paper involves recently developed methods that are efficient in handling cross-sectionally dependent heterogeneous panel data sets. Besides, the analysis is also conducted for sub-panels of high-, upper-middle-, and lower-middle-income Ganization policies for achieving higher economic growth without marginalizing environmental well-being.The main aim of the present study is to examine the possible nonlinear relations between foreign direct investments and environmental deterioration for subpanels separated according to the income levels of countries by using the classification made by the World Bank. Total energy consumption, economic growth, and renewable energy share are also considered as determinants of environmental deterioration in the model. Cross-sectional dependence is observed; hence, appropriate panel data unit root and cointegration tests are utilized for which results pointed out mixed integration order. Pooled mean group (PMG) estimator panel auto-regressive distributed lag (ARDL, hereafter) approach is adapted to observe short- and long-run relationships between the variables. Long-run results supported the pollution haven hypothesis as foreign direct investments caused an increase in ecological footprint. Findings are sensitive to different income levels of the subpanels of countries. This empirical study suggests tailored policymaking for every income level subpanel to ensure sustainable development.Microbial sulfate reduction, a vital mechanism for microorganisms living in anaerobic, sulfate-rich environments, is an essential aspect of the sulfur biogeochemical cycle. FXR agonist However, there has been no detailed investigation of the diversity and biogenesis contribution of sulfate-reducing bacteria in arsenic-contaminated soils from realgar deposits. To elucidate this issue, soil samples from representative abandoned realgar deposits were collected. Microcosm assays illustrated that all three samples (2-1, 2-2, and 2-3) displayed efficient sulfate and As(V)-respiring activities. Furthermore, a total of 28 novel sequence variants of dissimilatory sulfite reductase genes and 2 new families of dsrAB genes were successfully identified. A novel dissimilatory sulfate-reducing bacterium, Desulfotomaculum sp. JL1, was also isolated from soils, and can efficiently respiratory reduce As(V) and sulfate in 4 and 5 days, respectively. JL1 can promote the generation of yellow precipitates in the presence of multiple electron acceptors (both contain sulfate and As(V) in the cultures), which indicated the biogenesis contribution of sulfate-reducing bacteria to the realgar mine. Moreover, this area had unique microbial communities; the most abundant populations belonged to the phyla Proteobacteria, Chloroflexi, and Acidobacteriota, which were attributed to the unique geochemistry characteristics, such as total organic carbon, total As, NO3-, and SO42-. The results of this study provide new insight into the diversity and biogenesis contributions of sulfate-reducing bacteria in arsenic-contaminated soils from realgar deposits.The effects of sodium dodecyl benzene sulfonate (SDBS), polyoxyethylene (20) sorbitan monolaurate (Tween 20), and their mixtures on the depuration of anthracene (Ant) and fluoranthene (Fla) individually adsorbed on the Kandelia obovata (Ko) leaf surfaces were in situ investigated. The Ko original leaf-wax microstructures have been destroyed by SDBS, Tween 20, and their mixtures at or above their critical micelle concentration (CMC). The volatilization rate constants (kV) of the adsorbed PAHs decreased with surfactants at or above their CMC resulting from the plasticizing effect and a decrease in the polarity of the Ko leaf-waxes induced by surfactants. Moreover, the photolysis rate constants (kP) of the adsorbed PAHs decreased with SDBS while increased with Tween 20 and their mixtures at or above their CMC, which can be attributed to effects of surfactants on the light adsorption behavior of Ko leaf-waxes. Overall, the effects of surfactants on the depuration of the adsorbed PAHs were dependent not only on the physical-chemical properties of surfactants but also on the micro-environment of the substrates adsorbed the PAHs. These results are of great significance for further understanding the accumulation of PAHs and could expand our knowledge about the migration mechanism of PAHs from the atmosphere by mangrove leaf surface micro-zones.Determining the circularity of a system through a criteria and indicators approach has been the focus of research in many branches of science. In this way, this work aims to review multiple criteria decision-making (MCDM) methods employed for measuring circular economy (CE) indicators and CE aspects at different levels (micro, meso, and macro). For this purpose, a systematic literature review (SLR) was conducted in ISI Web of Science and Scopus databases. Further, the results summarized 22 MCDM techniques, 27 CE aspects, and 36 CE indicators The SLR provides a concept map highlighting the relation of the level of circularity implementation (subdivided into micro-, meso-, and macro-levels) and MCDM techniques and demonstrates the interaction between CE aspects and indicators. The review provides an outline as to how MCDM techniques can solve problems related to CE aspects and marks the relevance in the use of CE indicators to support circularity aspects and to construct criteria in the methodologies applied.Microplastics, as emerging pollutants, have received great attention in the past few decades due to its adverse effects on the environment. Microplastics are ubiquitous in the atmosphere, soil, and water bodies, and mostly reported in aqueous environment. This paper summarizes the abundance and types of microplastics in different aqueous environments and discusses the interactions of microplastics with other contaminants such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), antibiotics, and heavy metals. The toxicity of microplastics to aquatic organisms and microorganisms is addressed. Particularly, the combined toxic effects of microplastics and other pollutants are discussed, demonstrating either synergetic or antagonistic effects. Future prospectives should be focused on the characterization of different types and shapes of microplastics, the standardization of microplastic units, exploring the interaction and toxicity of microplastics with other pollutants, and the degradation of microplastics, for a better understanding of the ecological risks of microplastics.Increased industrialization and consumption of fossil fuels in the Metropolitan Region of São Paulo (MRSP), Brazil, have caused a growth of the particulate matter emissions to the atmosphere and an increase in population health problems. Particulate and gaseous phase samples were collected in different short campaigns (2015, 2016, and 2017) near an urban-industrial area. Organic carbon (OC), elemental carbon (EC), polycyclic aromatic hydrocarbons (PAH), and its derivatives (nitro and oxy-PAH), n-alkanes, hopanes, and pesticides were determined. The Salmonella/microsome test confirmed the mutagenic activity of these samples. Among PAH, benzo(a)pyrene was detected as one of the most abundant compounds. Benzo(a)pyrene equivalent concentrations for PAH and nitro-PAH, and the associated risk of lung cancer, showed values above those recommended in the literature. The profile of n-alkanes confirmed the predominance of anthropogenic sources. Pesticide concentrations and estimated risks, such as the daily inhalation exposure and hazard quotient, suggest that exposure to these compounds in this area may be dangerous to human health.Overutilized hydro-energy production through non-sustainable mode is detrimental for both the economy and the environment. Intermittent consumption of hydro-energy from non-sustainable production methods may induce deleterious impacts in terms of rapid pollution in the economy. This paper investigates the impacts of hydro-power consumption upon pollution for 5 BRICS countries from 1965 to 2019. Our balanced panel model shows that infrequent usages of hydro-power consumption led to more pollution over the year. This relation is also further explained by considering several macroeconomic factors, in the context of the growth scenario. Our empirical findings show that an increase in population and consequent rise in per capita income have exhibited positive impacts on pollution. Even, improved industrialized led production and investment in these economies contribute heavily towards pollution and declined environmental standards. Our results further state that intermittent usages of natural resources by population in terms of rising ecological footprint have resulted in higher emission intensity over the year. These findings underscore how rising hydro-power energy consumption has led to the rising pollution amidst the growth scenario in BRICS economies.
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