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Designed bioactives represented 83% of detected analytes. Contaminant summary metrics correlated strong-positive (rho (ρ) 0.569-0.719) to multiple watershed-development metrics, only weak-positive to point-source discharges (ρ 0.225-353), and moderate- to strong-negative with multiple instream invertebrate metrics (ρ -0.373 to -0.652). Risk screening indicated common exposures with high probability of vertebrate-centric molecular effects and of acute toxicity to invertebrates, respectively. The results confirm exposures to broad and diverse contaminant mixtures and provide convincing multiple lines of evidence that chemical contaminants contribute substantially to adverse multi-stressor effects in headwater-stream communities.Few studies have addressed how the diversity of basal resources change with stream regulation and the potential consequences on river biota. We sampled invertebrates above and below a series of dams, over two years, at both downwelling and upwelling zones. In each zone, we recorded the daily temperature and flow variations, estimated the algal development, measured the available resources, and analysed carbon and nitrogen stable isotope compositions of the invertebrate community. The number of hydrological pulses were typically higher below the dams than above the dams especially during high-flow periods whereas the groundwater outlets had minor effects on invertebrate assemblages. Invertebrate abundance, richness and diversity tended to decrease below the dams. Co-inertia analysis showed that flow and temperature variations, and eutrophication explained most of the variance in the invertebrate assemblages, which comprised a higher number of resilient taxa below than above the dams. The proportions of pesticiem functioning. The relative utilization of traits indicates the functional potential of aquatic invertebrate assemblages to face multiple stressors whereas isotope analysis is an expression of the actual effect of the stressors on the trophic structure of aquatic invertebrate assemblages.This study aims to offer insights into how ciprofloxacin (CIP) impact bacterial community structures in the Sponge-MBR process when CIP is spiked into hospital wastewater. We found that the CIP toxicity decreased richness critical phylotypes such as phylum class ẟ-, β-, ɣ-proteobacteria, and Flavobacteria that co-respond to suppress denitrification and cake fouling to 37% and 28% respectively. Cluster analysis shows that the different community structures were formed under the influence of CIP toxicity. CIP decreased attached growth biomass by 2.3 times while increasing the concentration of permeate nitrate by 3.8 times, greatly affecting TN removal by up to 26%. Ammonia removal was kept stable by inflating the ammonia removal rate (p less then 0.003), with the wealthy Nitrospira genus guaranteeing the nitrification activity. In addition, we observed an increasing richness of Chloroflexi and Planctomycetes, which may play a role in fouling reduction in the Sponge-MBR. Therefore, if the amount of antibiotics in hospital wastewater continues to increase, it is so important to extend biomass retention for denitrification recovery.Air pollution associated with wildfire smoke transport during the summer can significantly affect ozone (O3) and particulate matter (PM) concentrations, even in heavily populated areas like New York City (NYC). Here, we use observations from aircraft, ground-based lidar, in-situ analyzers and satellite to study and assess wildfire smoke transport, vertical distribution, optical properties, and potential impact on air quality in the NYC urban and coastal areas during the summer 2018 Long Island Sound Tropospheric Ozone Study (LISTOS). We investigate an episode of dense smoke transported and mixed into the planetary boundary layer (PBL) on August 15-17, 2018. The horizontal advection of the smoke is shown to be characterized with the prevailing northwest winds in the PBL (velocity > 10 m/s) based on Doppler wind lidar measurements. The wildfire sources and smoke transport paths from the northwest US/Canada to northeast US are identified from the NOAA hazard mapping system (HMS) fires and smoke product and NOAA-(PM with diameter ≤ 2.5 μm), organic carbon (OC) and CO measurements show coincident and sharp increase (e.g., PM2.5 from 5 μg/m3 before the plume intrusion to ~30 μg/m3) with the onset of the plume intrusions into the PBL along with hourly O3 exceedances in the NYC region. We further evaluate the NOAA-National Air Quality Forecasting Capability (NAQFC) model PBL-height, PM2.5, and O3 with the observations and demonstrate good consistency near the ground during the convective PBL period, but significant bias at other times. The aloft smoke layers are sometimes missed by the model.Life cycle assessment (LCA) is a widely applied approach used to evaluate the environmental impacts of a product or service across its life cycle stages; however, the impacts of land use on ecosystem services are less addressed in most LCA studies. This study, therefore, aims to improve the LCA model by incorporating a new impact category of land use on ecosystem services at both midpoint and endpoint levels in the existing ReCiPe2016 impact assessment method. The impacts of land use in the LCA model included land occupation and land transformation. The soil quality-based indicator, soil organic carbon (SOC), was adopted to quantify the soil quality change in ecosystem services caused by land use. A site with contaminated soils was adopted to validate the proposed impact assessment approach and to compare the results of various remediation practices. Our results revealed that the characterization factors (CFs) varied with the type of land use intervention, with land occupation of settlements presenting the highest CFs and land occupation of forest presenting the most negative CFs and thus benefitting ecosystem services. These results were well reflected in the case study, while the type of land intervention was the key factor determining the impact level. learn more The results suggested that long-term occupation, high contamination levels, and high material or energy use contributed to relatively higher impacts of land use on ecosystem services. The proposed approach enables the quantification of land use impacts on ecosystem services as expressed in monetary loss or benefit at the endpoint resource level. The impact assessment results indicated that the in situ bioremediation scenario contributed relatively higher impacts ($12,667 USD) than the excavation and thermal treatment scenario ($-37 USD). These monetary assessment results are informative and are expected to be used in the decision-making process towards achieving beneficial environmental outcomes.
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