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The densities of state diagrams were determined to calculate contributions to the molecular orbitals. The molecular electrostatic potential surfaces are determined to give a visual representation of charge distribution of these ligands and to provide information linked to electrophilic and nucleophilic sites localization. Caspofungin mouse Finally, these derivatives were evaluated for the inhibition of COVID-19 activity by using the molecular docking method.Extracorporeal cardiopulmonary resuscitation (ECPR) is a salvage procedure in which extracorporeal membrane oxygenation (ECMO) is initiated emergently on patients who have had cardiac arrest (CA) and on whom the conventional cardiopulmonary resuscitation (CCPR) has failed. Awareness and usage of ECPR are increasing all over the world. Significant advancements have taken place in the ECPR initiation techniques, in its device and in its post-procedure care. Caspofungin mouse ECPR is a team work requiring multidisciplinary experts, highly skilled health care workers and adequate infrastructure with appropriate devices. Perfect coordination and communication among team members play a vital role in the outcome of the ECPR patients. Ethical, legal and financial issues need to be considered before initiation of ECPR and while withdrawing the support when the ECPR is futile. Numerous studies about ECPR are being published more frequently in the last few years. Hence, keeping updated about the ECPR is very important for proper selection of cases and its management. This article reviews various aspects of ECPR and relevant literature to date.Quantification of hazard-induced losses plays a significant role in risk assessment and management of civil infrastructure subjected to hazards in a life-cycle context. Caspofungin mouse A rational approach to assess long-term loss is of vital importance. link2 The loss assessment associated with stationary hazard models and low-order moments (i.e., expectation and variance) has been widely investigated in previous studies. This paper proposes a novel approach for the higher-order analysis of long-term loss under both stationary and nonstationary hazards. link2 An analytical approach based on the moment generating function is developed to assess the first four statistical moments of long-term loss under different stochastic models (e.g., homogeneous Poisson process, non-homogeneous Poisson process, renewal process). link2 Based on the law of total expectation, the developed approach expands the application scope of the moment generating function to nonstationary models and higher-order moments (i.e., skewness and kurtosis). Furthermore, by employing the convolution technique, the proposed approach effectively addresses the difficulty of assessing higher-order moments in a renewal process. Besides the loss analysis, the mixed Poisson process, a relatively new stochastic model, is introduced to consider uncertainty springing from the stochastic occurrence rate. Two illustrative examples are presented to demonstrate practical implementations of the developed approach. Ultimately, the proposed framework could aid the decision-maker to select the optimal option by incorporating higher-order moments of long-term loss within the decision-making process.This study explored the COVID-19 pandemic's impacts on domestic violence (DV) with the following research questions 1) Did DV occurring during the pandemic differ on certain variables from cases occurring on a typical day the previous year? 2) Did DV occurring after the implementation of shelter-in-place orders differ (on these same variables) from cases occurring prior to shelter-in-place orders? Two logistic regression models were developed to predict DV case differences before and during the pandemic. DV reports (N = 4618) were collected from the Chicago Police Department. Cases from March 2019 and March 2020 were analyzed based on multiple variables. One model was set to predict case differences since the pandemic began, and another model was set to predict case differences during the shelter-in-place period later that month. Both models were significant with multiple significant predictors. During the pandemic period, cases with arrests were 20% less likely to have occurred, and cases at residential locations were 22% more likely to have occurred. During the shelter-in-place period, cases at residential locations were 64% more likely to have occurred, and cases with child victims were 67% less likely to have occurred. This study offers a rapid analysis of DV case differences since the pandemic and shelter-in-place began. Additional variables and data sources could improve model explanatory power. Research, policy, and practice in this area must pivot to focus on protecting children whose access to mandated reporters has decreased and moving victims out of dangerous living situations into safe spaces.In the 1970s intimate partner violence became recognized as a major societal problem in Europe. The study of the processes that enable victims to emerge from this violence is still topical. Even more so when it concerns male victims, who remain an under-studied population. This article examines the processes involved in bringing an end to intimate partner violence, including female and male victims. This qualitative study examines the intra- and inter-subjective changes underlying the processes of ending IPV in victims by using a narrative approach. Semi-structured interviews including the use of qualitative life calendars were conducted with 21 victims, 18 women and 3 men. The thematic analysis highlighted eight stages of a process of getting out from intimate partner violence. From the change in perception to the post-separation, victims' trajectories contain similar stages nuanced by individual and environmental specificities for both female and male. Getting out from intimate partner violence involves a sequence of changes in the perception of self, partner, couple and violence that allows for cognitive and relational transitions.Ebeko is one of the most active volcanoes of the Kurile island arc, producing frequent mild Vulcanian explosions with eruption clouds up to 5 km high. The volcano poses a serious threat to the Severo-Kurilsk town with a population of around 2500 inhabitants, located at a distance of only 7 km on a fan of the volcano's laharic deposits. Here, we report an overview of the activity of the volcano in the 20th-21st centuries and the results of our geological and petrological investigations of the ongoing Vulcanian eruption that started in 2016. We have found that eruptions of Ebeko span a range of mechanisms from purely magmatic to phreatic/hydrothermal. Three of its historical eruptions (the 1934-1935, 1987-1991, and the 2016-ongoing) involved fresh magma, while during the others (1967-1971, 2009-2011) fresh magma was not erupted. Juvenile material of the ongoing eruption represents highly crystalline and highly viscous (more than 108 pa s) low-silica (56-58 wt% SiO2) andesite. Historical data and our observations of the ongoing eruption allowed us to suggest a functional model of the volcano where Vulcanian explosions are caused by shallow intrusions of small diapir-like batches of strongly crystallized and highly viscous andesitic magma ascending into water-saturated, hydrothermally altered rocks composing the volcano summit. We suggest that the diapir's ascent is governed by their positive buoyancy. Some of the diapirs reach and breach the ground surface producing magmatic eruptions of Ebeko, while the others are stuck at the shallow subsurface level and feed intensive hydrothermal activity as well as phreatic eruptions of the volcano. link3 Positive buoyancy of the diapirs is too weak to allow them to extrude high above the ground surface to form lava domes.
The online version contains supplementary material available at 10.1007/s00445-020-01426-z.
The online version contains supplementary material available at 10.1007/s00445-020-01426-z.This study reports the sugaring-out extraction of erythromycin from fermentation broth using acetonitrile (ACN) as solvent and glucose as a mass separating agent. Different process parameters-glucose concentration, temperature, ACN/water ratio and pH-were optimized to achieve maximum extraction of erythromycin. 88% (w/w) of erythromycin was extracted from the model system with following optimized conditions glucose 156.3 g/L; temperature 4 °C; ACN/water ratio 1 and pH 8.3. Further, the effect of typical fermentation media components (starch, soybean flour, CaCO3, NaCl and (NH4)2SO4) on sugaring out extraction of erythromycin was also investigated. Starch, soybean flour and CaCO3 were observed to affect erythromycin extraction only at higher concentration. Removal of suspended solids from simulated as well as real broth prior to extraction enhanced the extraction efficiency (from 72% to 87%). Sugaring out extraction of erythromycin was found to be more effective than salting out extraction. Also, higher partition coefficient was achieved in the present work than other reported methods using carbohydrates as mass separating agent. Further, it was found that the antimicrobial activity of erythromycin was preserved during sugaring out extraction of erythromycin.Should a government repay its international debts even if this imposes severe hardships on its citizens? Drawing on moral psychology, we investigate when people think a government is morally obligated to pay its debts. Participants read about a government that has to decide whether to default on its debt payments or cut vital programs. Across conditions, we varied the number of jobs at stake and whether a full or partial default is required to save them. Overall, most participants judged that a government should pay its debt even when the damage to the debtor is greater than the benefit to the lender. As the damage to the debtor became extreme, participants increasingly said the government should default, but they still judged that defaulting is morally wrong. In Experiment 2, we find in a national sample of Americans that political conservatives were more opposed to default than liberals. We discuss implications for policy, public opinion, and public welfare during economic downturns.
The online version of this article (10.1007/s11109-020-09675-6) contains supplementary material, which is available to authorized users.
The online version of this article (10.1007/s11109-020-09675-6) contains supplementary material, which is available to authorized users.The human rights violation of sex trafficking continues to occur in the United States at alarming rates. Although sex trafficking affects individuals across various demographic groups, this crime disproportionately affects children. Counselors who work with children and adolescents are uniquely positioned to identify, support, and advocate on behalf of sex trafficked youth who may experience barriers to emotional and physical wellness. link3 Extant literature on counseling sex trafficking survivors remain scarce and illuminate the need for victim identification, trauma-informed interventions, and advocacy strategies that support the unique needs of child sex trafficking survivors. link3 To address these disparities, this article describes victim identification techniques, outlines trauma-focused interventions for counseling sex trafficked youth, and presents advocacy strategies. The implications for counseling child sex trafficking survivors are illuminated through a case study.
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