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33 (28.58) min) was significantly shorter than that of the NG surgery (378.83 (379.35) min;
< 0.05). While the time spent only for the fully guided implant surgery (from the start of the surgical guide sitting onto the dentiform model to the final installation of the implant fixture) was comparable (
> 0.05), the presurgical preparation time spent on virtual implant planning and surgical guide fabrication in the VG surgery (19.63 (20.93) min) was significantly shorter compared to the NG surgery (372.93 (372.95) min;
< 0.05).
Regardless of experience, both VG and NG surgery showed reliable positional accuracy; however, the total procedure time and the preparation time were much shorter in the VG surgery compared to the NG surgery.
Regardless of experience, both VG and NG surgery showed reliable positional accuracy; however, the total procedure time and the preparation time were much shorter in the VG surgery compared to the NG surgery.Two naphthalene diimides derivatives containing two different (alkyl and alkoxyphenyl) N-substituents were studied, namely, N,N'-bis(sec-butyl)-1,4,5,8-naphthalenetetracarboxylic acid diimide (NDI-s-Bu) and N,N'-bis(4-n-hexyloxyphenyl)-1,4,5,8-naphthalenetetracarboxylic acid diimide (NDI-4-n-OHePh). These compounds are known to exhibit electron transport due to their electron-deficient character evidenced by high electron affinity (EA) values, determined by electrochemical methods and a low-lying lowest unoccupied molecular orbital (LUMO) level, predicted by density functional theory (DFT) calculations. These parameters make the studied organic semiconductors stable in operating conditions and resistant to electron trapping, facilitating, in this manner, electron transport in thin solid layers. https://www.selleckchem.com/products/shp099-dihydrochloride.html Current-voltage characteristics, obtained for the manufactured electron-only devices operating in the low voltage range, yielded mobilities of 4.3 × 10-4 cm2V-1s-1 and 4.6 × 10-6 cm2V-1s-1 for (NDI-s-Bu) and (NDI-4-n-OHePh), respectively. Their electron transport characteristics were described using the drift-diffusion model. The studied organic semiconductors can be considered as excellent candidates for the electron transporting layers in organic photovoltaic cells and light-emitting diodes.In this paper, we investigated theimpact of glassy carbon (GC) reinforcement oncrystal structure and the mechanical performance of high-density polyethylene (HDPE). We made composite samples by mixing HDPE granules with powder in ethanol followed bymelt mixing in a laboratory extruder. Along with the investigated composite, we also prepared samples with carbon nanotubes (CNT), graphene (GNP) and graphite (Gr) to compare GC impact with already used carbon fillers. To evaluate crystal structure and crystallinity, we used X-ray diffraction (XRD) and differential scanning calorimetry (DSC). We supported the XRD results with a residual stress analysis (RSA) according to the EN15305 standard. Analysis showed that reinforcing with GC leads to significant crystallite size reduction and low residual stress values. We evaluated the mechanical properties of composites with hardness and tensile testing. The addition of glassy carbon results inincreased mechanical strength incomposites with CNT and GNP.The remarkable properties of shape memory alloys (SMA) are attracting significant technological interest in many fields of science and engineering. In this paper, a nonlinear dynamic analytical model is developed for a laminated beam with a shape memory alloy layer. The model is derived based on Falk's polynomial model for SMAs combined with Timoshenko beam theory. In addition, axial velocity, axial pressure, temperature, and complex boundary conditions are also parameters that have been taken into account in the creation of the SMA dynamical equation. link2 The nonlinear vibration characteristics of SMA laminated beams under 13 internal resonance are studied. The multi-scale method is used to solve the discretized modal equation system, the characteristic equation of vibration modes coupled to each other in the case of internal resonance, as well as the time-history and phase diagrams of the common resonance amplitude in the system are obtained. The effects of axial velocity and initial conditions on the nonlinear internal resonance characteristics of the system were also studied.Materials from theA2M3O12 family are known for their extensive chemical versatility while preserving the polyhedral-corner-shared orthorhombic crystal system, as well as for their consequent unusual thermal expansion, varying from negative and near-zero to slightly positive. The rarest are near-zero thermal expansion materials, which are of paramount importance in thermal shock resistance applications. Ceramic materials with chemistry Al2-xInxW3O12 (x = 0.2-1.0) were synthesized using a modified reverse-strike co-precipitation method and prepared into solid specimens using traditional ceramic sintering. The resulting materials were characterized by X-ray powder diffraction (ambient and in situ high temperatures), differential scanning calorimetry and dilatometry to delineate thermal expansion, phase transitions and crystal structures. It was found that the x = 0.2 composition had the lowest thermal expansion, 1.88 × 10-6 K-1, which was still higher than the end member Al2W3O12 for the chemical series. Furthermore, the AlInW3O12 was monoclinic phase at room temperature and transformed to the orthorhombic form at ca. 200 °C, in contrast with previous reports. Interestingly, the x = 0.2, x = 0.4 and x = 0.7 materials did not exhibit the expected orthorhombic-to-monoclinic phase transition as observed for the other compositions, and hence did not follow the expected Vegard-like relationship associated with the electronegativity rule. Overall, compositions within the Al2-xInxW3O12 family should not be considered candidates for high thermal shock applications that would require near-zero thermal expansion properties.To date, research on the physical and mechanical behavior of nickel-titanium shape-memory alloy (NiTi SMA) has focused on the macroscopic physical properties, equation of state, strength constitution, phase transition induced by temperature and stress under static load, etc. The behavior of a NiTi SMA under high-strain-rate impact and the influence of voids have not been reported. In this present work, the behavior evolution of (100) single-crystal NiTi SMA and the influencing characteristics of voids under a shock wave of 1.2 km/s are studied by large-scale molecular dynamics calculation. The results show that only a small amount of B2 austenite is transformed into B19' martensite when the NiTi sample does not pass through the void during impact compression, whereas when the shock wave passes through the hole, a large amount of martensite phase transformation and plastic deformation is induced around the hole; the existence of phase transformation and phase-transformation-induced plastic deformation greatly consumes the energy of the shock wave, thus making the width of the wave front in the subsequent propagation process wider and the peak of the foremost wave peak reduced. In addition, the existence of holes disrupts the orderly propagation of shock waves, changes the shock wave front from a plane to a concave surface, and reduces the propagation speed of shock waves. The calculation results show that the presence of pores in a porous NiTi SMA leads to significant martensitic phase transformation and plastic deformation induced by phase transformation, which has a significant buffering effect on shock waves. The results of this study provide great guidance for expanding the application of NiTi SMA in the field of shock.Composite materials are increasingly used to strengthen existing structures or new load-bearing elements, also made of timber. In this paper, the effect of the number of layers of Carbon Fiber Reinforced Polymer (CFRP) on the load-bearing capacity and stiffness of Glued Laminated Timber beams was determined. Experimental research was performed on 32 elements-a series of eight unreinforced beams, and three series of eight reinforced beams with one, three and five layers of laminate each. The beams with a cross-section of 38 mm × 80 mm and a length of 750 mm were subjected to the four-point bending test according to standard procedure. For each series, destructive force, deflection, mode of failure, and equivalent stiffness were determined. link3 In addition, for the selected samples, X-ray computed tomography was performed before and after their destruction to define the quality of the interface between wood and composite. The results of the conducted tests and analyses showed that there was no clear relationship between the number of reinforcement layers and the load-bearing capacity of the beams and their stiffness. Unreinforced beams failed due to tension, while reinforced CFRP beams failed due to shear. Despite this, a higher energy of failure of composite-reinforced elements was demonstrated in relation to the reference beams.From the perspective of damage mechanics, the damage parameters were introduced as the characterizing quantity of the decrease in the mechanical properties of powder superalloy material FGH96 under fatigue loading. By deriving a damage evolution equation, a fatigue life prediction model of powder superalloy containing inclusions was constructed based on damage mechanics. The specimens containing elliptical subsurface inclusions and semielliptical surface inclusions were considered. The CONTA172 and TARGE169 elements of finite element software (ANSYS) were used to simulate the interfacial debonding between the inclusions and matrix, and the interface crack initiation life was calculated. Through finite element modeling, the stress field evolution during the interface debonding was traced by simulation. Finally, the effect of the position and shape size of inclusions on interface debonding was explored.New ceramic materials based on two copper borates, CuB2O4 and Cu3B2O6, were prepared via solid state synthesis and sintering, and characterized as promising candidates for low dielectric permittivity substrates for very high frequency circuits. The sintering behavior, composition, microstructure, and dielectric properties of the ceramics were investigated using a heating microscope, X-ray diffractometry, scanning electron microscopy, energy dispersive spectroscopy, and terahertz time domain spectroscopy. The studies revealed a low dielectric permittivity of 5.1-6.7 and low dielectric loss in the frequency range 0.14-0.7 THz. The copper borate-based materials, owing to a low sintering temperature of 900-960 °C, are suitable for LTCC (low temperature cofired ceramics) applications.When designing embankments on a soft ground improved with columns (rigid inclusions) and with a geosynthetically reinforced load transfer platform (LTP), the methods of determining strains in reinforcement reduce the spatial problem to a two-dimensional one, and analytical calculations are carried out for reinforcement strips in the directions along and across the embankment. In addition, the two-dimensional FEM models do not allow for a complete analysis of the behavior of the reinforcement material. The aim of this research was to analyze the work of the membrane in the 3D space modeling of the LTP reinforcement, depending on the interaction with the column, the shape of the column's cap, the value of the Poisson's ratio, the value of the stiffness of the elastic foundation (subgrade reaction k) modeling of the soft soil resistance between the columns and the load distribution over membranes that model the reinforcement. The membranes were modeled in the framework of the theory of large deformations using the finite element method and slender shell elements as three-dimensional objects.
Website: https://www.selleckchem.com/products/shp099-dihydrochloride.html
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