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Theoretical examine in the compound reactivity of your class of trivalent phosphorus types in direction of polyhaloalkanes: DFT study.
This flat part corresponds to the mixture of the displacements of the lead and oxygen ions and can be an explanation of the extinction rules contradiction. Moreover, a flat dispersion surface is a typical prerequisite for the incommensurate phase transition.The present study evaluates the fracture surface response of fatigued 34CrNiMo6 steel bars with transverse blind holes subjected to bending with torsion loading. The analysis of the geometric product specification was performed by means of height parameters Sx, functional volume parameters Vx, and fractal dimension Df. Surface topography measurements were carried out using an optical profilometer with focus variation technology. The experimental results show that the doubling the bending to torsion moment ratio B/T from B/T = 1 to B/T = 2, maintaining the same normal stress amplitude, greatly reduces both Sa, Vv as well as the fractal dimension Df of the analyzed specimen fractures by 32.1%, 29.8%, and 16.0%, respectively. However, as expected, a two-fold increase in the B/T ratio, maintaining the same normal stress amplitude, resulted in a larger number of cycles to fatigue crack initiation, Ni, which can be explained by the lower shear stress level. https://www.selleckchem.com/products/ten-010.html These experiments prove that parameters Sx, Vx, Df are smaller for larger Ni values, which is an important finding. In addition, it was found a high consistency of surface topography measurements for the two sides of the broken specimens. The proposed methodology is both reliable and applicable for other engineering applications involving different geometries and loading conditions.In this paper, the application of a fiber Bragg grating written in a highly birefringent side-hole elliptical core optical fiber for two-axial strain measurement is presented. Hybrid optical fiber structures achieved by combining large side-holes and elliptical core result in a very high birefringence of 1 × 10-3 and thus high initial Bragg peak spectral separation of 1.16 nm, as well as a very high transverse force sensitivity, of up to 650 pm/(N/mm) or even -1150 pm/(N/mm), depending on the fiber orientation with respect to the applied force. Due to the ~22 %m/m GeO2 concentration in the core the fiber being highly photosensitive, which significantly simplifies FBG fabrication by UV illumination without the need for prior hydrogen loading, which worsens thermal stability. Finally, the developed FBGs written in the highly birefringent side-hole elliptical core optical fiber were embedded in the square composite plates and applied for strain measurements. Tests of two-directional four-point bending have shown usability of such FBG for two-axial in-plane strain measurement with a single FBG in iso-thermal conditions.The inevitable destructive effects of moisture and temperature are obvious in cellulosic and nanocellulosic substrates. These materials are the main foundations of interdependent industries that produce products such as currency notes or high-quality packaging for sanitary, cosmetics, or ammunition in the defense industry. Therefore, it is essential to develop procedures to eliminate problems arising from humidity and fire to improve the quality of these green and sustainable materials. The production of waterproof and flame-resistant cellulose-based substrates has drawn increasing attention to resolve these drawbacks. In this review paper, we have initially summarized the most accessible cellulosic substrates, different kinds of nanocellulose, and the general information about water repellents and intumescent fireproof surfaces. Then, the potential and necessity of using cellulosic biobased substrates are addressed for use in modified shapes as waterproof and fire inhibitor coatings. Cost-effective, eco-friendly, and durable, dual-function coatings are also introduced as future challenges, which are exploited as water-repellents and flame-retardant cellulose-based surfaces for pulp and paper applications.The aim of this work is to propose a numerical methodology based on the finite element (FE) method to investigate the dispersive behavior of guided waves transmitted, converted, and reflected by reinforced aluminum and composite structures, highlighting their differences. The dispersion curves of such modes can help designers in improving the damage detection sensitivity of Lamb wave based structural health monitoring (SHM) systems. A preliminary phase has been carried out to assess the reliability of the modelling technique. The accuracy of the results has been demonstrated for aluminum and composite flat panels by comparing them against experimental tests and semi-analytical data, respectively. Since the good agreement, the FE method has been used to analyze the phenomena of dispersion, scattering, and mode conversion in aluminum and composite panels characterized by a structural discontinuity, as a stiffener. The research activity allowed emphasizing modes conversion at the stiffener, offering new observations with respect to state of the art. Converted modes propagate with a slightly slower speed than the incident ones. Reflected waves, instead, have been found to travel with the same velocity of the incident ones. Moreover, waves reflected in the composite stiffened plate appeared different from those that occurred in the aluminum one for the aspects herein discussed.Conventionally, in a linear economy, C&D (Construction and Demolition) waste was considered as zero value materials, and, as a result of that, most C&D waste materials ended up in landfills. In recent years, with the increase in the awareness around sustainability and resource management, various countries have started to explore new models to minimize the use of limited resources which are currently overused, mismanaged, or quickly depleting. In this regard, the implementation of CE (Circular Economy) has emerged as a potential model to minimize the negative impact of C&D wastes on the environment. However, there are some challenges hindering a full transition to CE in the construction and demolition sectors. Therefore, this review paper aims to critically scrutinize different aspects of C&D waste and how CE can be integrated into construction projects. Reviewing of the literature revealed that the barriers in the implementation of CE in C&D waste sectors fall in five main domains, namely legal, technical, s effective model approach, the future direction should be more focused on dismantling practices, hazardous material handling, quality control on waste acceptance, and material recovery processes, as well as a incentivization mechanism to promote ecological, economic, and social benefits of the CE for C&D sectors.Honing processes are currently employed to obtain a cross-hatched pattern on the internal surfaces of cylinders that favors oil flow in combustion engines or hydraulic cylinders. The main aim of the present paper is to optimize the machining conditions in honing processes with respect to surface roughness, material removal rate and tool wear by means of the desirability function. Five process variables are considered grain size, density, pressure, linear speed and tangential speed. Later, a sensitivity analysis is performed to determine the effect of the variation of the importance given to each response on the results of the optimization process. In the rough and semi-finish honing steps, variations of less than 5% of the importance value do not cause substantial changes in the optimization process. On the contrary, in the finish honing step, small changes in the importance values lead to modifications in the optimization process, mainly regarding pressure. Thus, the finish honing phase is more sensitive to changes in the optimization process than the rough and the semi-finish honing phases. The present paper will help users of honing machines to select proper values for the process variables.
The objective of this micro-computed tomography (micro-CT)-based study was to compare the filling quality of endodontic treatment and endodontic Re-treatment between two sealers with matched obturation techniques calcium silicate-based sealer (Endoseal TCS) with a single-cone technique (SCT) and resin-based sealer (AH Plus) with a continuous wave technique (CWT).

Forty maxillary premolars were selected and assigned into four groups, according to the obturation methods of the first endodontic treatment and Re-treatment (
= 10). The AP/AP group was first treated with AH Plus/CWT, then re-treated with AH Plus/CWT. The AP/ET group was first treated with AH Plus/CWT, then re-treated with Endoseal TCS/SCT. The ET/AP group was first treated with Endoseal TCS/SCT, then re-treated with AH Plus/CWT, and the ET/ET group was first treated with Endoseal TCS/SCT, then re-treated with Endoseal TCS/SCT. The specimens were scanned using micro-CT at three time points after the first endodontic treatment, after gutta-percrdless of which sealer was used in the previous treatment.Platinum-based materials are widely known as the most utilized and advanced catalysts for hydrogen evolution reaction. For this reason, several studies have reported alternative methods of incorporating this metal into more economical electrodes with a carbon-based support material. Herein, we report on the performance of pencil graphite electrodes decorated with electrochemically deposited platinum nanoparticles as efficient electrocatalysts for hydrogen evolution reaction. The electrodeposition of platinum was performed via pulsed current electrodeposition and the effect of current density on the electrocatalytic activity was investigated. The obtained electrodes were characterized using cyclic voltammetry, while the electrocatalytic activity was assessed through linear sweep voltammetry. Field emission scanning electron microscopy and energy-dispersive X-ray spectroscopy were utilised to gain an insight into surface morphology and chemical analysis of platinum nanoparticles. The best performing electrocatalyst, at both low and high current densities, was characterized by the highest exchange current density of 1.98 mA cm-2 and an ultralow overpotential of 43 mV at a current density of 10 mA cm-2. The results show that, at low current densities, performances closest to that of platinum can be achieved even with an ultralow loading of 50 µg cm-2 Pt.Fiber-reinforced concrete (FRC) has become an alternative for structural applications due its outstanding mechanical properties. The appearance of new types of fibres and the fibre cocktails that can be configured by mixing them has created FRC that clearly exceeds the minimum mechanical properties required in the standards. Consequently, in order to take full advantage of the contribution of the fibres in construction projects, it is of interest to have constitutive models that simulate the behaviour of the materials. This study aimed to simulate the fracture behaviour of five types of FRC, three with steel fibres, one with a combination of two types of steel fibers, and one with a combination of polyolefin fibres and two types of steel fibres, by means of an inverse analysis based on the cohesive crack approach. The results of the numerical simulations defined the softening functions of each FRC formulation and have pointed out the synergies that are created through use of fibre cocktails. The information supplied can be of help to engineers in designing structures with high-performance FRC.
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