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Reevaluation in piling up along with lacking regarding dioxin-like ingredients throughout offspring associated with putting hen chickens: Quantification about eating threat coming from feed in order to egg.
Furthermore, earthworms significantly stimulated overall soil microbial activity and improved three microbial metabolic pathways, and xenobiotics biodegradation and metabolism, signal transduction, cell motility, particularly for the S-enantiomer treatment with earthworms, which alleviated the strong inhibition of S-enantiomer on microbial community functions. This study confirmed that earthworms accelerated the degradation of the highly toxic acetochlor S-enantiomer in soil, providing a potential approach in chloroacetamide herbicide-polluted soil remediation.Covalent organic polymers (COPs) are promising adsorbents for the removal and detection of various types of pollutants. However, the preparation of COPs that exhibit uniform dispersion and good appearance at room temperature is challenging. Herein, fluorinated covalent organic polymers (F-COPs) with different morphologies were synthesized through the Schiff base reaction of 4,4-diamino-p-terphenyl (DT) and 2,3,5,6-tetrafluoroterephthalaldehyde (TFA). The as-prepared F-COPs could selectively adsorb perfluorinated compounds (PFCs) owing to their fluoro-affinity, hydrophobicity, hydrogen bonding, and electrostatic attraction. The adsorption kinetics and isotherm simulation results showed that the adsorption process conformed to the second-order kinetics and the Langmuir model. The saturated adsorption capacity calculated by the Langmuir model was found to be 323-667 mg/g. The F-COPs were applied to the treatment of simulated fluorine industrial wastewater, and the PFC removal efficiencies of 92.3-100.0% were achieved. Moreover, ultra-high-performance liquid chromatography-mass spectrometry (UPLC-MS) was conducted for the detection of trace-level PFCs using F-COPs as dispersive solid-phase extraction (DSPE) adsorbents. The limits of detection were 0.05-0.13 ng/L and the limits of quantification were 0.17-0.43 ng/L. This study facilitates the synthesis of COPs at room temperature and extends the application of COPs as pretreated materials for environmental remediation and detection.Surface Enhanced Raman Spectroscopy (SERS) could be a powerful technique for detecting trace gaseous sulfur-mustard, but it is still challenging due to the difficulty in efficiently capturing sulfur-mustard molecules by normal SERS substrates. Here, a chemically trapping strategy is presented for such detection via coating an ultrathin metal-oxide sensing layer on a SERS substrate. In the strategy, a SERS substrate Au-wrapped Si nanocone array is designed and fabricated by Si wafer-based organic template-etching and appropriate Au deposition, and coated with an ultrathin CuO for chemically capturing sulfur-mustard molecules. The validity of such strategy has been demonstrated via taking the gaseous 2-chloroethyl ethyl sulfide (a simulant of sulfur-mustard, or 2-CEES for short) as the target molecules. The response of the CuO-coated SERS substrate to the gaseous 2-CEES is detectable within 10 min, and the lowest detectable concentration is 10 ppb or less. Further experiments have shown that there exists an optimal CuO coating thickness which is about 6 nm. The CuO coating-based capture of 2-CEES molecules is attributed to the surface hydroxyl-induced specific adsorption, which is subject to the pseudo-second-order kinetics and Freundlich-typed model. This study presents the practical SERS chips and new route for the trace detection of gaseous sulfur-mustard.Microplastics are ubiquitous environmental pollutants and a great threat to the aquatic environment. Due to their small size (ranging from 1 µm to 5 mm), microplastics be easily ingested by a wide range of organisms and can serve as a vector for various contaminants. In this study, additive or possible synergistic effects of microplastics and zinc were demonstrated through sex-specific alterations in behavior, redox status, and modulation of detoxification-related genes in Daphnia magna, with males being more sensitive than females with stronger modulations of antioxidant responses, particularly on glutathione S-transferases expressions. Furthermore, we demonstrated microplastics may act as vectors for metals (Zn2+) in the aquatic environment in D. magna, with reduced bio-concentration of the total Zn concentration, inducing greater toxicity. Our findings demonstrated synergistic toxicity of the heavy metal Zn and microplastics and could contribute to greater understanding of sex-specific effects of microplastics in aquatic organisms.This study investigates the regulation of the vertical gene transfer of quinolones' antibiotic resistance genes (ARGs) through a combination of source modification and process control. In source prevention, 29 Escherichia coli (E. coli) DNA gyrase subunit A mutant proteins were constructed, the B-G mutant protein displayed the greatest reduction in binding effect (-25.98%). AZD9291 Based on this, a 3D-QSAR model was constructed, and LEV-2 and LEV-9 QNs derivatives were designed based on Levofloxacin (LEV), and their binding effect with B-G mutant protein was found be increased by 13.24% and 19.40%. The drug resistance mechanism of E. coli was explored based on molecular docking technology and protein hydrophobic interaction theory. Most of the amino acid resistance mutations changed from hydrophilic to lipophilic, which inhibited the binding of QNs to mutant protein A subunit, and further reduced the bactericidal effect of QNs. In process control, Huoxiang-Zhengqi, stroke-physiological saline solution (SPSS), and Lycium barbarum (L. barbarum) was found to be 164.82% higher than that of the blank control group. The purpose of this study is to provide a theoretical support for the joint regulation of QNs' ARGs in organisms and the research and development on green alternatives to QNs compounds.Mercury (Hg) contaminated soil is a potential hazardous material especially under soil erosion and surface runoff. This work aims to use rice husk biochar to immobilize Hg and prevent erosion, and find the optimal production temperature and particle size of the biochar. The biochars were produced at 300, 500, and 700 °C and sieved to three particle sizes ~20, less then 2, and less then 0.15 mm. They were applied to a Hg contaminated loamy sand (20.2 mg/kg) and undergone simulated rainfall erosion representing 7 years of heavy rain events in Beijing. All biochar amendments reduced the runoff volume by 5.1-15.4%. Hg amount in runoff were significantly reduced by 36.7-48.8% after the amendments of biochar. The Hg concentration of infiltration was reduced by biochar treatments except that produced at 300 °C, while its amount was increased due to larger infiltration volume. All biochar amendments significantly reduced soil loss in runoff by 43.5-77.2%. Hg was enriched in the sediments (39.7-46.8 mg/kg) compared with the parent soil (20.2 mg/kg) regardless of biochar treatment, but its bioavailability was low. Higher pyrolysis temperature of the rice husk biochars resulted in less runoff, more infiltration, and better erosion prevention, while the effect of biochar particle size is less significant.MnO2 catalysts have been widely studied for catalytic gaseous ozone decomposition. However, their poor moisture resistance often leads to undesirable catalytic effects in the presence of high humidity. In this study, a novel catalyst with γ-like MnO2 was synthesized using the selective dissolution method on LaMnO3 perovskites. The as-prepared catalyst exhibited quite stable ozone conversion of ~90% within 12 h under 75% relative humidity (400-800 ppm of ozone, 30 °C, 150 000 mL·g-1·h-1 of WHSV). In contrast, traditional γ-MnO2 catalyst showed deficient resistance to H2O and sensitivity to space velocity. Detailed characterizations showed that the larger number of oxygen vacancies induced by structure reconstruction of the γ-like MnO2 and residual La3+ cations facilitated ozone decomposition in humid atmosphere. Finally, the reaction rate of ozone decomposition was proposed by a kinetic study, which further proved that the amount and hydrophilicity of oxygen vacancies are the determinants of the first-order reaction rate constant.To effectively address the serious human health challenges and ecological damage caused by organic dyes in wastewater, we developed a novel bionic adsorbent (LDH@PDA@MPNs) for the selective adsorption and removal of malachite green (MG) and crystalline violet (CV). The adsorbent was prepared using a facile two-step method based on mussel-inspired chemistry and metal complexation. The physicochemical structure, surface morphology, and composition of the LDH@PDA@MPNs were characterized by scanning electron microscopy, Fourier-transform infrared spectrometry, X-ray photoelectron spectroscopy, and thermogravimetric analysis. Adsorption of MG and CV with the LDH@PDA@MPNs was evaluated. Under optimal conditions, the maximum adsorption of MG and CV by the adsorbent was 89.608 and 40.481 mg/g, respectively. The adsorption kinetics showed that the experimental data were in good agreement with the pseudo-second-order kinetic model, and the equilibrium adsorption isotherm data fitted well with the Freundlich model. The thermodynamic results indicated that the adsorption of the dyes on LDH@PDA@MPNs was a spontaneous endothermic process. Importantly, the bionic adsorbent not only shows high removal efficiency by easy regeneration with low-cost reagents but also exhibits high selectivity for dyes in both single and binary systems. Therefore, LDH@PDA@MPNs have the potential to adsorb and remove dyes from complex wastewater solutions.Coagulation is well-established for controlling regulated disinfection by-products (DBPs), but its effectiveness for controlling unregulated DBPs remains unclear. The efficiency of coagulation in controlling unregulated DBPs requires clarification owing to their relatively high toxicity. In this study, three Al-based coagulants, aluminum sulfate (Alum), polyaluminum chloride (PAC), and a novel type of covalently bond hybrid coagulant (CBC, synthesized using AlCl3) were selected, and the coagulation performance of these Al-based coagulants in controlling DBPs and DBP-associated toxicity was compared over 5 classes of DBPs, including trihalomethanes, haloacetic acids, haloacetaldehydes, haloacetonitriles, and halonitromethanes. The results showed that Alum was the least efficient in removing DBP precursors among the three coagulants. The effectiveness of CBC and PAC for DBP control varied with the characteristics of source waters. CBC had an advantage in water with a low content of humic acids, and reduced DBP concentration and DBP-associated toxicity by 47% and 25%, respectively. For water rich in aromatic organics, CBC might serve as DBP precursors at a high-required dosage, suggesting that a trade-off between enhanced DBP control and serving as DBP precursors should be considered for CBC coagulation; PAC achieved the most reduction in DBP concentration and DBP-associated toxicity by 50% and 34%, respectively.This study investigated the impact of bench-scale ozonation on the inactivation of total cultivable and antibiotic-resistant bacteria (faecal coliforms, Escherichia coli, Pseudomonas aeruginosa, Enterococcus spp., and total heterotrophs), and the reduction of gene markers (16S rRNA and intl1) and antibiotic resistance genes (qacEΔ1, sul1, aadA1 and dfrA1) indigenously present in wastewater effluents treated by membrane bioreactor (MBR) or conventional activated sludge (CAS). The Chick-Watson model-predicted ozone exposure (CT) requirements, showed that higher CT values were needed for CAS- than MBR-treated effluents to achieve a 3-log reduction of each microbial group, i.e., ~30 and 10 gO3 min gDOC-1 respectively. Ozonation was efficient in inactivating the examined antibiotic-resistant bacteria, and no bacterial regrowth was observed after 72 h. The genes abundance decreased significantly by ozone, but an increase in their abundance was detected 72 h after storage of the treated samples. A very low removal of DOC was achieved and at the same time phyto- and eco-toxicity increased after the ozonation treatment in both wastewater matrices.
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