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Selenium has a similar pyritic origin but after alteration, it is predominantly associated with organic matter. Despite different distributions, the leaching experiment as a function of pH showed that the mobilization of arsenic and selenium overlapped below pH 2 and above pH 8. The main differences were observed between pH 2 and 8 with a plateau at 5% of released selenium, whereas the amount of mobilized arsenic continuously decreased. The pH-dependence of both elements is attributed to the partial dissolution of pyrite in acidic conditions combined with desorption processes at higher pH values.Lithobates catesbeianus tadpoles were exposed for 96 h to water from two sites of the Sorocaba River (summer and winter), Ibiúna (PI) and Itupararanga reservoir (PIR) that contained metals. In the liver, in PI, the glutathione peroxidase (GPx) decreased, and the glutathione S-transferase (GST) and carbonyl proteins (PCO) increased. In PIR, the glutathione reduced (GSH) increased, while there was a decrease in catalase (CAT), GPx, GST, PCO, and superoxide dismutase (SOD). In winter, GPx and GST increased in both points. Regarding the kidneys, lipoperoxidation (LPO) levels and GST decreased, while GSH increased in the summer. In the winter, LPO increased in PI. In the muscle, in the summer, there was an increase in GSH and GST and change in PCO. In the winter, the levels of PCO increased and CAT decreased in PIR. The area and volume of the hepatocyte and nucleus area increased in the summer and decreased in the winter. Hepatic melanin decreased in the summer after exposure to PIR water. There were the systemic effects of Sorocaba River water exposure at different times of the year with alterations in biomarkers at different levels, in which kidney shows highest Integrated Response of Biomarkers (IBR) value followed by liver and muscle. Biochemical biomarkers were more sensitive than morphological ones. The more sensitive biochemical markers were MT, PCO, GST and LPO. These effects confirm the hypothesis of metabolic alteration in bullfrog tadpoles by the Sorocaba River water.Soil petroleum contamination has become a global environmental problem. In order to develop a new soil remediation technology, this study established bacteria isolation, surfactant toxicity matching and petroleum contaminated soil remediation practice. The simulated field remediation showed that inoculating the soil with Bacillus methylotrophicus and adding 500 mg kg-1 rhamnolipid (N + RL) to soil can remove 80.24% of aged total petroleum hydrocarbons (TPHs) within 30 days. In particular, although the remediated soil has inoculated sufficient bacterial suspension, the microbial abundance of Bacillus was not a significantly dominant genus after remediation, especially in N + RL (0.73% of the total), but the colonies of indigenous petroleum-degrading bacteria (such as Massilia and Streptomyces) increased significantly. The interaction among genera has been further proved to drive soil non-specific oxidases (such as polyphenol oxidase, laccase and catalase) to remove TPHs. β-Aminopropionitrile datasheet This indicates that the interaction among microorganisms, rather than the degradability of exogenous degrading bacteria, plays more critical role in the degradation of organic pollutants, which enriches the traditional understanding of micro-remediation of contaminated soil. It can be concluded from the obtained results that the remediation of pollutants can be achieved by adjusting the purification capacity of the microbial community and the natural environment.An increasing amount of industrial chemicals are being released into wastewater collection systems and indigenous microbial communities in treatment plants are not always effective for their removal. In this work, extracellular polymeric substances (EPS) recovered from aerobic granular sludge (AGS) were used as a natural carrier to immobilize a specific microbial strain, Rhodococcus sp. FP1, able to degrade 2-fluorophenol (2-FP). The produced EPS granules exhibited a 2-FP degrading ability of 100% in batch assays, retaining their original activity after up to 2-months storage. Furthermore, EPS granules were added to an AGS reactor intermittently fed with saline wastewater containing 2-FP. Degradation of 2-FP and stoichiometric fluorine release occurred 8 and 35 days after bioaugmentation, respectively. Chemical oxygen demand removal was not significantly impaired by 2-FP or salinity loads. Nutrients removal was impaired by 2-FP load, but after bioaugmentation, the phosphate and ammonium removal efficiency improved from 14 to 46% and from 25 to 42%, respectively. After 2-FP feeding ceased, at low/moderate salinity (0.6-6.0 g L-1 NaCl), ammonium removal was completely restored, and phosphate removal efficiency increased. After bioaugmentation, 11 bacteria isolated from AGS were able to degrade 2-FP, indicating that horizontal gene transfer could have occurred in the reactor. The improvement of bioreactor performance after bioaugmentation with EPS immobilized bacteria and the maintenance of cell viability through storage are the main advantages of the use of this natural microbial carrier for bioaugmentation, which can benefit wastewater treatment processes.Selenium (Se) species can deposit in selective catalytic reduction (SCR) system during the denitrification process, which is harmful to the catalyst. To improve the Se-poisoning resistance of SCR catalysts, the influence mechanism of Se species on vanadium-titanium-based catalysts should be elucidated from an atomic scale. In this paper, theoretical calculations were conducted to reveal the adsorption and interaction mechanism of Se species on V2O5-WO3(MoO3)/TiO2 surface based on the first-principles. The impact of Se species on the electronic structure of the catalyst was investigated from electron transfer, bond formation, and VO site activity. The results show that the adsorption of elementary Se (Se0) belongs to chemisorption, while SeO2 can undergo both physisorption and chemisorption. For the chemisorption of Se species, obvious charge transfer with the catalyst is observed and Se-O bond is formed, which enhances the oxidation activity of the catalyst, triggers the reaction of Se0 and SeO2 with the catalyst components to generate SeVOx and SeW(Mo)Ox.
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