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ay have been the primary drivers in the Symbiodiniaceae-bacterial interactions (SBIs). Our study highlights the association between microbiome shift in distinct environmental regimes and holobiont acclimatisation, while providing insights into the impact of SBIs on holobiont health and acclimatisation during climate change.Contaminants of emerging concern (CECs), such as pharmaceuticals, personal care products, pesticides, synthetic and natural hormones and industrial chemicals, are frequently released into the environment because of the inability of conventional processes in municipal wastewater treatment plants to remove them. Some examples of alternative options to remove such pollutants are photo-Fenton and ozone-based processes, which are two techniques widely studied in Ibero-American countries. In fact, this region has been responsible for delivering frequently publications and conferences on advanced oxidation processes. This work is a critical review of recent developments in the intensification of the two aforementioned advanced oxidation techniques for CECs elimination in the Ibero-American region. Specifically for the photo-Fenton process (pF), this study analyses strategies such as iron-complexation with artificial substances (e.g., oxalic acid and ethylenediamine-N,N'-disuccinic acid) and natural compounds (such as humic-like substances, orange juice or polyphenols) and hybrid processes with ultrasound. Meanwhile, for ozonation, the enhancement of CECs degradation by adding hydrogen peroxide (i.e., peroxone), ultraviolet or solar light, and combining (i.e., photolytic ozonation) with catalysts (i.e., catalytic ozonation) was reviewed. Special attention was paid to how efficient these techniques are for removing contaminants from water matrices, and any potentialities and weak points of the intensified processes.Mechanisms for hematotoxicity and health effects from exposure to low doses of benzene (BZ) remain to be identified. selleck To address the information gap, our investigation was focused onto using appropriate populations and cell cultures to investigate novel BZ-induced effects such as disruption of DNA repair capacity (DRC). From our study, abnormal miRNAs were identified and validated using lymphocytes from 56 BZ-poisoned workers and 53 controls. In addition, 173 current BZ-exposed workers and 58 controls were investigated for key miRNA expression using RT-PCR and for cellular DRC using a challenge assay. Subsequently, the observed activities in lymphocytes were verified using human HL-60 (p53 null) and TK6 (p53 wild-type) cells via 1,4-benzoquinone (1,4-BQ) treatment and miR-222 interferences. The targeting of MDM2 by miR-222 was validated using a luciferase reporter. Our results indicate induction of genotoxicity in lymphocytes from workers with low exposure doses to BZ. In addition, miR-222 expression was up-regulated among both BZ-poisoned and BZ-exposed workers together with inverse association with DRC. Our in vitro validation studies using both cell lines indicate that 1,4-BQ exposure increased expression of miR-222 and Comet tail length but decreased DRC. Loss of miR-222 reduced DNA damage, but induced S-phase arrest and apoptosis. However, silencing of MDM2 failed to activate p53 in TK6 cells. In conclusion, our in vivo observations were confirmed by in vitro studies showing that BZ/1,4-BQ exposures caused genotoxicity and high expression of miR-222 which obstructed expression of the MDM2-p53 axis that led to failed activation of p53, abnormal DRC and serious biological consequences.A pilot-scale two-stage anaerobic digestion system, which includes a feed tank (0.4 m3), a hydrolysis reactor (1.2 m3) followed by a methane fermenter (4.0 m3) was set up and run at the municipal solid waste landfill located in Ho Chi Minh City (HCMC), Vietnam. The feed that was separated from urban organic solid waste was collected at households and restaurants in District 1, HCMC. This study aimed to investigate the resource recovery performance of the pilot two-stage anaerobic digestion system, in terms of carbon recovery via biogas production and nutrient recovery from digestate. The average organic loading rate (OLR) of the system was step increased from 1.6 kg volatile solids (VS)·m-3·d-1, 2.5 kg VS·m-3·d-1 and 3.8 kg VS·m-3·d-1 during 400 days of operation. During the long-term operation at three OLRs, pH values and alkalinity were stable at both hydrolysis and methanogenesis stages without any addition of alkalinity for the methanogenesis phase. High buildup of propanoic acid and total volatile fatty acid concentrations in the fermenter did not drop pH values and inhibit the methanogenic process at high OLRs (2.5-3.8 kg VS m-3·d-1). The obtained total chemical oxygen demand (tCOD) removal performance was 83-87% at the OLRs ranging from 2.5 kg VS·m-3·d-1 and 3.8 kg VS·m-3·d-1, respectively. The highest biogas yield of 263 ± 64 L·kg-1 tCOD removed obtained at OLR of 2.5 kg VS·m-3·d-1. It is expected that a full scale 2S-AD plant with capacity of 5200 tons day-1 of biowaste collected currently from municipal solid waste in HCMC may create daily electricity of 552 MWh, thermal energy of 630 MWh, and recovery of 16.1 tons of NH4+-N, 11.4 tons of organic-N, and 2.1 tons of TP as both organic liquid and solid fertilizers.A fair and effective carbon dioxide emissions allowances (CEA) allocation scheme is critical to balance regional development and alleviate social poverty. From the perspective of egalitarianism, this study aims to investigate the Chinese provincial CEA allocation in 2030, as well as the equality of allocation results. For this purpose, a total of 11 allocation schemes based upon a composite indicator method are developed, which consider different combinations of four allocation criteria, namely, egalitarian, responsibility, capability and efficiency. Then, an environmental Gini coefficient derived from Lorenz curves of allocation results is proposed to examine the equality of the results. The main findings show that the egalitarian criterion plays a crucial role in constructing allocation schemes, and different schemes often give rise to diversified allocation results. Although all the 11 allocation schemes, with the environmental Gini coefficients ranging from 0.0642 to 0.4019, better ensure the equality of allocation results, the schemes considering egalitarian criterion present higher equality over the schemes without this criterion. link2 Furthermore, the schemes are likely to present higher equality, when the efficiency criterion is measured by the reciprocal of emission intensity, rather than the indicator derived from a data envelopment analysis method. Emission intensity is a better proxy for efficiency criterion in improving the equality of allocation results.In recent years, magnetic biochar (MBC) has been greatly concerned because of its magnetic separation characteristics, and has been successfully used as a catalyst in the catalytic degradation of organic pollutants. However, there is currently a lack of a more systematic summary of MBC preparation methods, and no detailed overview of the catalytic mechanism of MBC catalysts for the degradation of organic pollutants. Therefore, we carry out this work to fill the above gaps. At first, we summarize the raw materials, preparation methods, and types of MBC in detail, and emphasize the MBC prepared by iron-containing sludge. Then, the catalytic mechanisms of MBC in peroxydisulfate, peroxymonosulfate, Fenton-like, photocatalysis, and NaBH4 systems are carefully summarized, highlighting the contribution of various parts of MBC in catalysis. The degradation efficiency of organic pollutants in the above systems is evaluated. Finally, the stability and reusability of MBC catalysts are evaluated. In conclusion, this review contributes a meager force to the future development of MBC.In this study, the removal of ibuprofen and gemfibrozil by chlorination, ozonation and a combination of ozone/hydrogen peroxide (O3/H2O2) advanced oxidation process (AOP) from treated sewage effluent (TSE) has been investigated. The removals were evaluated as single components and in binary systems at different oxidant dosages. Chlorination showed insignificant removal for both pharmaceuticals, while ozonation and O3/H2O2 achieved significant removals for both ibuprofen and gemfibrozil. link3 The highest removal efficiency of ibuprofen achieved with ozonation and O3/H2O2 in TSE was 80% at 1.5 mg/L ozone dosage (0.27 mg O3/mg DOC) within 5 min contact time and was not increased at extended times as the ozone residual approached zero in 5 min. For gemfibrozil, complete removals were achieved at ozone dosages of 1 and 1.5 mg/L by both ozonation and O3/H2O2 within 30 s. The rate constants obtained from the second order kinetics study were almost similar for the binary and single component tests, however, the degradation of ibuprofen was around four times faster by O3/H2O2 with a rate constant of 9 × 104 M-1 s-1 in comparison to ozone alone. The results in the single component and binary systems were almost similar for gemfibrozil, but noticeably lower removals of ibuprofen were obtained in the binary system showing the higher selectivity and oxidation demand of gemfibrozil. Although O3/H2O2 has a higher operation cost, but its capability for faster degradation makes it preferable over ozonation only, as more water can be treated on a daily basis or a smaller treatment plant can be used with lower capital cost, which practically becomes more cost efficient.Knowledge of how temperature influences animal behavior is critical to understanding and predicting impacts of changing climate on individual species and biotic interactions. However, the effects of climate change, especially winter warming in freshwater systems, on fish behaviors and the use of chemical information have been largely unexplored. Qinling lenok Brachymystax lenok tsinlingensis, an endangered salmonid species endemic to the Qinling Mountain Range, China, is currently experiencing population decline and is a potential biological indicator of warming winter climate effects on freshwater fishes due to its temperature sensitivity and required habitat of small, cold-water streams. Our objective was to determine if transient winter warming (increases of ~4 °C) consistent with seasonal maxima in line with near-future climate projections will affect antipredator responses to damage-released chemical alarm cues in B. lenok tsinlingensis. Wild fish were collected during winter and held in captivity under food deprivation for four days, during which half were acclimated to a warmer temperature (6 °C) while the other half were maintained at ambient levels (2 °C). Individual acclimated fish were then exposed to injections of either conspecific alarm cues to simulate elevated predation risk or stream water as a control treatment. Focal fish demonstrated responses consistent with antipredator behaviors to alarm cues at ambient temperature, but no significant behavioral responses to alarm cues were found relative to controls at the warmer temperature. These results support our hypothesis that winter warming will negatively influence antipredator responses and indicate that projected warmer temperature patterns in winter may have significant impacts on chemically mediated predator-prey interactions in cold-water streams.
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