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Comparability regarding two LC-MS/MS methods for the actual quantification of Twenty four,25-dihydroxyvitamin D3 throughout patients and exterior quality assurance trials.
In this paper, the relation between gain and resolution of an ideal analog optical differentiator in two different cases and their fundamental limits are investigated. Based on this relation, a figure of merit for comparison of the designed differentiators in recent papers is proposed. The differentiators are optimized using this figure of merit, and they are compared with each other to determine the best one. Also, a new differentiator is presented based on the dielectric slab waveguide in which the trade-off between its gain and resolution is easily controllable, and its best operating point is determined.Upconversion photoluminescence (UCPL) of rare-earth ions has attracted much attention due to its potential application in cell labeling, anti-fake printing, display, solar cell and so forth. In spite of high internal quantum yield, they suffer from very low external quantum yield due to poor absorption cross-section of rare-earth ions. In the present work, to increase the absorption by rare earth ions, we place the emitter layer on a diffractive array of Al nanocylinders. The array is designed to trap the near infrared light in the emitter layer via excitation of the plasmonic-photonic hybrid mode, a collective resonance of localized surface plasmons in nanocylinders via diffractive coupling. The trapped near-infrared light is absorbed by the emitter, and consequently the intensity of UCPL increases. In sharp contrast to the pure localized surface plasmons which are bound to the surface, the hybridization with diffraction allows the mode to extend into the layer, and the enhancement up to 9 times is achieved for the layer with 5.7 µm thick. Ruxotemitide solubility dmso This result explicitly demonstrates that coupling the excitation light to plasmonic-photonic hybrid modes is a sensible strategy to enhance UCPL from a thick layer.Thanks to the conductive thermal metamaterials, novel functionalities like thermal cloak, camouflage and illusion have been achieved, but conductive metamaterials can only control the in-plane heat conduction. The radiative thermal metamaterials can control the out-of-plane thermal emission, which are more promising and applicable but have not been studied as comprehensively as the conductive counterparts. In this paper, we theoretically investigate the surface emissivity of metal/insulator/metal (MIM, i.e., Au/Ge/Au here) microstructures, by the rigorous coupled-wave algorithm, and utilize the excitation of the magnetic polaritons to realize thermal camouflage through designing the grating width distribution by minimizing the temperature standard deviation of the overall plate. Through this strategy, the hot spot in the original temperature field is removed and a uniform temperature field is observed in the infrared camera instead, demonstrating the thermal camouflage functionality. Furthermore, thermal illusion and thermal messaging functionalities are also demonstrated by resorting to using such an emissivity-structured radiative metasurface. The present MIM-based radiative metasurface may open avenues for developing novel thermal functionalities via thermal metasurface and metamaterials.This paper presents modeling results of Mie-type GaAs nanopillar array resonant structures and the design of negative electron affinity photocathodes based on Spicer's three-step model. For direct-bandgap GaAs with high intrinsic absorption coefficient in the 500 ∼ 850 nm spectral range, photoelectrons were found to be highly localized inside the nanopillars near the top and side surfaces where electrons can be efficiently transported and emitted into vacuum, and the light reflectance can be reduced to ∼1% level at resonance wavelengths. Predictions of spectrally resolved photoemission indicate that these nanophotonics resonators, when properly optimized, can increase the photo-electron emission quantum efficiency at resonance wavelengths to levels limited only by the surface-electron escape probability, significantly outperforming traditional flat wafer photocathodes. Ultrafast photoelectric response is also expected from these nanostructured photocathodes due to the much shorter photoelectron transport distance in nanopillars compared to flat wafers. Given these unique optoelectronic properties, GaAs nanophotonic resonance structured photocathodes represent a very promising alternative to photocathodes with flat surfaces that are widely used in many applications today.A wide spectral asymmetry between the front and rear facets of a tapered chirped quantum dot multi-section superluminescent diode is reported. The spectral asymmetry between the two facet outputs was found to be tunable and highly dependent on the bias asymmetry between the two contact sections, with a spectral mismatch of up to 14 nm. Numerical simulations confirmed a relationship between this spectral asymmetry and the non-uniform filling of the quantum dots' confined states when different current densities are applied to the device electrodes. The results from this investigation open up an additional degree of freedom for multi-section superluminescent diodes, which could pave the way for optical bandwidth engineering via multiplexing the spectral output from both facets, using only a single device.The problem of X-ray diffraction from multilayer-coated blazed diffraction gratings is analyzed. Invalidity of the conventional condition of maximal diffraction efficiency observed in previous experiments is explained theoretically. This is attributed to two factors contribution of anti-blaze facets to diffraction efficiency and effect of strongly asymmetric diffraction. We demonstrate that a proper choice of the multilayer d-spacing allows to design grating with the diffraction efficiency close to the maximal possible one throughout the tender X-ray range (E∼1-5 keV). An optimization procedure is suggested for the first time to choose the optimal grating parameters and the operation diffraction order to obtain a high fix-focus constant and high diffraction efficiency simultaneously in a wide spectral range.In a previously published paper [Opt. Express26(17), 22182 (2018)], the performance of a LDPC coded OAM-based UCA FSO system exploring linear equalization with channel estimation over atmospheric turbulence has been analyzed. We find that some concepts and descriptions in [Opt. Express26(17), 22182 (2018)] are inconsistent and paradoxical. In this comment, we point out the referred inconsistency and paradox one by one and present the correct explanations.This joint issue of Optics Express and Optical Materials Express features 18 state-of-the art articles that witness actual developments in nonlinear optics, including those by authors who participated in the international conference Nonlinear Optics held in Waikoloa, Hawaii from July 15 to 19, 2019. As an introduction, the editors provide a summary of these articles that cover all aspects of nonlinear optics, from basic nonlinear effects and novel frequency windows to innovative nonlinear materials and devices, thereby paving the way for new nonlinear optical concepts and forthcoming applications.We use a simple photoalignment method to fabricate four reflective cholesteric liquid crystal (CLC) polymeric lenses with diameter D=2.45 cm and low f-numbers (f/2, f/0.9, f/0.45, f/0.33) at 550 nm. Such a flat CLC lens can be converging or diverging, depending on the handedness and direction of the incident light. Our CLC lenses can achieve ∼85% diffraction efficiency for a designated polarization state and manifest decent imaging ability.The influence of the pump scheme on the intensity noise of the single-frequency continuous-wave (CW) laser is investigated in this paper, which is implemented in a single-frequency CW NdYVO4 1064 nm laser by comparing the traditional 808 nm pumping scheme (TPS) to the direct 888 nm pumping scheme (DPS). Under the conditions that the lasers with TPS and DPS have the same cavity structure and the cavity mirrors, as well as the same operation state including the thermal lens of the laser crystals and the mode-matching between the pump laser mode and the laser cavity mode at the laser crystals, the output power of the laser with DPS is up-to 32.0 W, which is far higher than that of 21.1 W for the laser with TPS. However, the intensity noise of the DPS laser including resonant relaxation oscillation (RRO) frequency of 809 kHz, RRO peak amplitude of 31.6 dB/Hz above the shot noise level (SNL) and the SNL cutoff frequency of 4.2 MHz, respectively, is also higher than that of 606 kHz, 20.4 dB/Hz and 2.4 MHz for the TPS laser. After further analyses, we find that the laser crystal with high doping concentration and long optical length is employed for DPS laser in order to improve the pump laser absorption efficiency, which can simultaneously increase the dipole coupling between the active atoms and the laser cavity, and then results in a high RRO frequency with a large amplitude peak as well as a high SNL cutoff frequency of the laser.The beam fanning naturally occurring in a photorefractive crystal is shown to slow down a single light pulse at room temperature. Slow light is demonstrated for both visible and infrared wavelength light pulses as short as the response time of the photorefractive crystal and with fractional delay- i.e ratio of delay to output pulse duration- up to 0.4.Sub-wavelength aperture arrays featuring small gaps have an extraordinary significance in enhancing the interactions of terahertz (THz) waves with matters. But it is difficult to obtain large light-substance interaction enhancement and high optical response signal detection capabilities at the same time. Here, we propose a simple terahertz bow-tie aperture arrays structure with a large electric field enhancement factor and high transmittance at the same time. The field enhancement factor can reach a high value of 1.9×104 and the transmission coefficient of around 0.8 (the corresponding normalized-to-area transmittance is about 14.3) at 0.04 µm feature gap simultaneously. The systematic simulation results show that the designed structure can enhance the intensity of electromagnetic hotspot by continuously reducing the feature gap size without affecting the intensity of the transmittance. We also visually displayed the significant advantages of extremely strong electromagnetic hot spots in local terahertz refractive index detection, which provides a potential platform and simple strategy for enhanced THz spectral detection.Research has shown that the ignition characteristics of laser-induced plasmas in fuel-air mixtures are influenced by the gas dynamics effects induced during the gas breakdown stage. Here, we present the numerical modeling of the fluid mechanics induced by breakdown (plasma formation) from a nanosecond near-infrared (NIR) laser pulse in air. The simulations focus on the post-discharge kernel dynamics with the goal of developing a better understanding of how vorticity is generated during the kernel cooling phase. Initial conditions (ICs) of kernel shape, temperature, and pressure (corresponding to the end of the laser pulse) are found from experimental Rayleigh scattering data. It is shown that this method for determining ICs is preferred versus the use of the Taylor-Sedov blast wave theory as it provides a more accurate description of the starting field. Past experimental observations have revealed that the gas dynamics of nanosecond laser sparks typically lead to the formation of an asymmetric torus with a frontal lobe propagating towards the laser source.
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