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Furthermore, the applied current played a selective role in the enrichment of microorganisms. Dissolved oxygen (DO) played a short board effect on nitrogen biotransformation and pollutant metabolism. This study for the first time explored the key role of different levels of DO (covering anaerobic, anoxic and aerobic) on hydrolyzed polyacrylamide (HPAM) bioconversion. HPAM was metabolized to intermediates with different chain length. Volatile fatty acid (VFA) production rose first and then descended with DO concentration (0-2 mg·L-1), and the maximum reached 92.5 mg·L-1 when DO was 0.5 mg·L-1. Total nitrogen (TN) removal increased first and then dropped with DO concentration, and the maximum (61.4%) occurred at 0.5 mg·L-1 DO. NH4+-N dipped from 42.8 to 0 mg·L-1 and NO3--N rose from 0 to 32.8 mg·L-1 with DO concentration. The changes of enzyme activities were consistent with those of VFA production and TN removal, which were related to HPAM metabolism and N bioconversion. Microbial function was correlated to HPAM metabolism, N bioconversion and key enzyme. Gas chromatography-ion mobility spectrometry (GC-IMS) and dynamic quantitative descriptive analysis (D-QDA) were combined to explore the aroma release and perception from the retronasal cavity during bread consumption. D-QDA results elucidated that the sweet, creamy, and roasty notes were the most active attributes during oral processing. The final stage of oral processing had the most complicated changing pattern, followed by the intermediate and initial stages. Thirteen aroma compounds were detected in the retronasal cavity, of which eight had odor activity values (OAVs) greater than 1. The total OAV changing pattern was consistent with the D-QDA results. Addition experiments further confirmed that acetoin, 2,3-butanedione, and 3-(methylthio)propanal were key aroma compounds contributing to retronasal olfaction. 2,3-Butanedione and 3-(methylthio)propanal were both identified as key odorants in the mouth cavity and retronasal cavity during oral processing, but they had 30% loss during the breath delivery from the mouth cavity to the retronasal cavity. This study is devoted to the development of a sensitive immunochromatographic analysis (ICA) for simultaneous determination of tylosin (TYL) and lincomycin (LIN) as antibiotics of the macrolide and lincosamide classes, widely used in animal husbandry and implicated in the contamination of foodstuffs. The ICA was implemented in an indirect competitive format, using antispecies antibodies conjugated with gold nanoparticles (GNPs) as a label. After the multistep optimization, the developed double ICA allowed for antibiotics detection with instrumental limits of detection/cutoff levels of 0.09/2 ng/mL and 0.008/0.8 ng/mL for TYL and LIN, respectively, within 10 min. The cross-reactivity was 40% to lincosamide clindamycin and negligible to other antibiotics tested. The test system allowed for the detection of TYL and LIN in milk, honey, and eggs. The recoveries of antibiotics from foodstuffs were 87.5-112.5%. The results demonstrate that the developed double ICA is an effective approach for the detection of other food contaminants. A novel procedure for the rapid isotope analysis of the carbon-bound non-exchangeable (CBNE) hydrogen in mono and disaccharides has been developed to demonstrate the feasibility of detecting undeclared addition of exogenous sugar products in foods and beverages susceptible to economically motivated adulteration. MSAB The procedure utilizes a simple one-step reaction, with the derivatising agent N-methyl-bis-trifluoroacetamide, to substitute the exchangeable hydroxyl-hydrogens with trifluoroacetate derivatives that are sufficiently volatile to be separated and measured by a gas chromatograph coupled to an isotope ratio mass spectrometer. The conversion of the derivatised sugars into the measuring gas is achieved using a high temperature chromium-silver reactor that retains carbon, oxygen and fluorine whilst releasing hydrogen gas for stable isotope measurement. The new procedure has advantages over existing methods in terms of ease of use, analysis time and compound-specific information. Sugars from fruit juice and honey have been measured to demonstrate the feasibility of using this technique. Sulfate related water quality and trophic status are crucial to operation of water diversion. Though the sulfur geochemistry in the lake sediment have been well studied, the effective indicator of surrounding environment conditions related to sulfur in river-lake systems are still unknown. In this study, Dongping Lake (DPH), Weishan Lake (WSH), and Hanzhuang trunk canal (HZQ) were selected as the typical river-lake systems in the eastern of China. Different spatial variations in sedimentary sulfate, total sulfur, and elemental composition of sediments were investigated in these areas. The relatively high sulfate in surface water and sediments appeared in portions of WSH. The biodiversity of HZQ and WSH surface sediments was much higher than that of DPH. Pseudomonas, Acinetobacter, and Thiobacillus were the dominant genera of the river-lake systems. Among the different genera in distribution, genera such as Malikia, Sulfurovum and Lysinibacillus were significantly negatively correlated with sulfur related environmental factors. While the genera such as Pseudomonas, Vogesella and Acinetobacter were significantly positively correlated with these factors. Compared with connectivity in the largest interaction network, bacteria such as Proteus, Acidobacter and Chlorobacteria were identified as indicatory taxa to infer sulfate related conditions in the river-lake systems. Underwater sound plays an important role in some critical life functions of many aquatic animals. Underwater noise pollution has received relatively more attention in ocean systems. However, little attention has been paid to freshwater systems, such as the Yangtze River which is the habitat of critically endangered Yangtze finless porpoises (Neophocaena asiaeorientalis asiaeorientalis). In 2012, the underwater noise levels in 25 sites along the middle and lower sections of the Yangtze River were measured. The root mean square sound pressure level (SPL) and unweighted sound exposure level (SEL) at each site ranged between 105 ± 2.4 (median ± quartile deviation) and 150 ± 5.5 dB. Obvious spatial and temporal variations in the SPL were detected among the 25 sites. The SPL and SEL in the middle section of the Yangtze River were smaller (approximately 15 dB) and fluctuated more compared to those in the lower section. The power spectrum in the mainstem was site specific. However, all the spectra levels were higher than the audiogram of Yangtze finless porpoises. Majority of the sites had an averaged cumulative unweighted SEL (72%) and cumulative weighted SEL (68%) that surpassed the underwater acoustic thresholds for onset of hearing temporal threshold shifts for finless porpoise. Porpoise bio-sonars were detected in 89% of sonar monitoring sites indicating that noise pollution in the Yangtze River greatly threatened porpoise survival. In 8% of the sites, the averaged cumulative weighted SEL exceeded that of underwater acoustic thresholds causing non-recoverable permanent threshold shifts of finless porpoises auditory system whereas it was less than 1 dB below the underwater acoustic thresholds in other 8% of the sites. These sites urgently needed noise mitigation and management strategies. These results will facilitate the evaluation of the impacts of anthropogenic noise pollution on local finless porpoises and give further guidelines on its effective conservation. Stibnite (Sb2S3) dissolution and transformation on mineral surfaces are the fundamental steps controlling the fate of antimony (Sb) in the environment. The molecular-level understanding of Sb2S3-mineral-water interfacial reactions is of great importance. Herein, Sb2S3 oxidative dissolution and sequestration on pyrite (FeS2) were explored. The results show that FeS2 accelerated the rate of Sb2S3 oxidative dissolution by a factor of 11.4-fold under sunlight due to heterogeneous electron transfer. The electron transfer from Sb2S3 to FeS2 separated photogenerated hole (h+) and electron (e-) pairs, facilitating the generation of hydroxyl radicals (OH) on Sb2S3 and FeS2, and superoxide radicals (O2-) on FeS2. Surface O2- was the dominant oxidant for Sb(III) oxidation with 91% contribution, as evidenced by radical trapping experiments. OH was preferentially adsorbed on Sb2S3, but was released with Sb2S3 dissolution, and subsequently contributable to Sb(III) oxidation in solution. The Sb(III) oxidation and sequestration on FeS2 surface coupled Fe2+/Fe3+ cycling and inhibited FeS2 dissolution, as evidenced by X-ray absorption near edge structure and X-ray photoelectron spectroscopy. The insights gained from this study further our understanding of Sb2S3 transformation and transport at the environmental mineral-water interfaces. The prediction and identification of the factors controlling heavy metal transfer in soil-crop ecosystems are of critical importance. In this study, random forest (RF), gradient boosted machine (GBM), and generalised linear (GLM) models were compared after being used to model and identify prior factors that affect the transfer of heavy metals (HMs) in soil-crop systems in the Yangtze River Delta, China, based on 13 covariates with 1822 pairs of soil-crop samples. The mean bioaccumulation factors (BAFs) for all crops followed the order Cd > Zn > As > Cu > Ni > Hg > Cr > Pb. The RF model showed the best prediction ability for the BAFs of HMs in soil-crop ecosystems, followed by GBM and GLM. The R2 values of the RF models for the BAFs of Zn, Cu, Cr, Ni, Hg, Cd, As, and Pb were 0.84, 0.66, 0.59, 0.58, 0.58, 0.51, 0.30, and 0.17, respectively. The primary controlling factor in soil-to-crop transfer of all HMs under study was plant type, followed by soil heavy metal content and soil organic materials. The model used herein could be used to assist the prediction of heavy metal contents in crops based on heavy metal contents in soil and other covariates, and can significantly reduce the cost, labour, and time requirements involved with laboratory analysis. It can also be used to quantify the importance of variables and identify potential control factors in heavy metal bioaccumulation in soil-crop ecosystems. Low pH and aluminum (Al)-toxicity often coexist in acidic soils. Citrus sinensis seedlings were treated with nutrient solution at a pH of 2.5, 3.0, 3.5 or 4.0 and an Al concentration of 0 or 1 mM for 18 weeks. Thereafter, malate, citrate, isocitrate, acid-metabolizing enzymes, and nonstructural carbohydrates in roots and leaves, and release of malate and citrate from roots were measured. Al concentration in roots and leaves increased under Al-toxicity, but it declined with elevating nutrient solution pH. Al-toxicity increased the levels of glucose, fructose, sucrose and total soluble sugars in leaves and roots at each given pH except for a similar sucrose level at pH 2.5-3.0, but it reduced or did not alter the levels of starch and total nonstructural carbohydrates (TNC) in leaves and roots with the exception that Al improved TNC level in roots at pH 4.0. Levels of nonstructural carbohydrates in roots and leaves rose with reducing pH with a few exceptions with or without Al-toxicity. A potential model for the possible role of root organic acid (OA) metabolism (anions) in C.
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