Notes

Enhanced debromination of 4-bromophenol by the UV/sulfite process: Efficiency Halogenated aromatic compounds have attracted increasing concerns due to their toxicity and persistency in the environment, and dehalogenation is one of the promising treatment and detoxification methods
Herein, we systematically studied the debromination efficiency and mechanism of para-bromophenol (4-BP) by a recently developed UV/sulfite process. 4-BP underwent rapid degradation with the kinetics accelerated with the increasing sulfite concentration, pH (6-10) and temperature, whereas inhibited by dissolved oxygen and organic solvents. The apparent activation energy was estimated to be 27kJ/mol. The degradation mechanism and pathways of 4-BP were explored by employing N2O and nitrate as the electron scavengers and liquid chromatography/mass spectrometry to identify the intermediates. 4-BP degradation proceeded via at least two pathways including direct photolysis and hydrated electron-induced debromination. The contributions of both pathways were distinguished by quantifying the quantum yields of 4-BP via direct photolysis and hydrated electron production in the system.

4-BP could be readily completely debrominated with all the substituted Br released as Br-, and the degradation pathways were also proposed. This study would shed new light on the efficient dehalogenation of brominated aromatics by using the UV/sulfite A high-precision and wide-range pH monitoring system based on broadband Research Center for Optical Instruments, Zhejiang Provincial Key Laboratory for Interdisciplinary Student Training Platform for Marine Areas, Zhejiang Research Center for Optical Instruments, Zhejiang Provincial Key Laboratory for Research Center for Optical Instruments, Zhejiang Provincial Key Laboratory for A high-precision pH monitoring system over a wide pH range is introduced. The system comprises a cavity-enhancement module constructed by two high-reflectivity mirrors, a microfluidic pH sensing chip based on a binary-indicator membrane of Congo red and m-cresol purple, and a hyperspectral transmission module. This structure extends the effective absorption optical path of the sensing chip, significantly amplifying the spectral differences at various pH values. The spectrum of the transmitted light is recorded by a self-developed hyperspectral module and then converted to broadband cavity-enhanced absorption spectrum (BBCEAS) via the Beer-Lambert law. An artificial neural network (ANN) is employed to predict pH values of the solution. With such Seebio Light-Activated Acid Producer , this system exhibits a wide detecting range of 2 M [H+] - 2 M [OH-] (corresponding to pH -0-14) with a response time of about 120 s.

The system can achieve a higher detection accuracy with root mean square error (RMSE) of 073, as compared to 037 without the cavity enhancement. The system also possesses good properties of repeatability, long-term stability, ion resistance, and organic corrosion resistance. These excellent properties make the proposed system a promising candidate technology for harsh environments, such as seawater acidification warning, chemical plant sewage monitoring, and declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this Evaluating the pH-dependence of DOM absorbance, fluorescence, and photochemical The protonation state of dissolved organic matter (DOM) impacts its structure and function in natural and engineered environmental systems, including DOM's ability to absorb light and form photochemically produced reactive intermediates (PPRI). However, the impacts of pH on DOM optical properties and PPRI formation have largely been evaluated separately, with less information being available on their interrelationship as a function of pH for the same set of samples. It is also unclear whether the impact of pH on optical spectra and associated optical surrogates for molecular size (e.g., E2 : E3) of DOM isolates is representative of the behavior of whole water samples.

To address these knowledge gaps, spectral pH titrations were performed for seven humic substance and natural organic matter isolates, three whole water samples, and three model compounds. Comparison of the fractional and differential absorption and fluorescence spectra between DOM isolates, whole water samples, and model compounds revealed similar spectral features between all samples. The results show that spectral features observed for DOM isolates also occur for whole water samples, which suggests that there is overlap in the types of chromophores present in DOM isolates and whole waters. Although results from model compounds overlapped with DOM, especially in the ultraviolet region of the spectrum, no model compound replicated DOM's pH dependence perfectly. By measuring apparent quantum yields of singlet oxygen (ΦΔ), we show that aquatic DOM isolates exhibit a different pH-dependence (ΦΔ ∝ pH-1) than soil-derived humic acid isolates (ΦΔ ∝ pH). For aquatic DOM isolates, ΦΔ values measured at different pH were not correlated to apparent fluorescence quantum yields (Φf), suggesting that pH impacts singlet and triplet excited state DOM dynamics in different ways. In contrast, the proportional relationship between Φf and ΦΔ with increasing pH for soil humic acid isolates suggests that pH impacts singlet and triplet excited DOM in these Carbenes from cyclopropanated aromatics.
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