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Molecular Positioning regarding Homoleptic Iridium Phosphors within Natural Light-Emitting Diodes.
As a result, the production of lipid, carbohydrate, and protein was enhanced by 61%, 122%, and 34%, respectively. This study provides new insights for using microalgae to recover bioresources from toxic wastewater and reveals the critical underlying mechanisms.A membrane bioreactor with humic acid substrate (MBR-H) was operated to investigate organic removal and membrane performance. Approximately, 60% of chemical oxygen demand removal was observed in MBR-H. The biosorption capacity reached to the maximum value of 29.2 mg g-1 in the experiments with various activated sludge concentrations and the amount adsorbed on the newly produced microbes was limited. To understand key functions of microorganisms in the biodegradation of humic acid, the microbial community was examined. The dominant phylum was changed from Actinobacteria at the raw sludge to Proteobacteria at the MBR-H. Especially, great increases of β-, γ-, and δ-Proteobacteria in the MBR-H indicated that those class of Proteobacteria played a vital role in humic acid removal. Investigation at the genus level showed enrichment of Stenotrophobacter in the MBR-H, which indicated the presence of metabolites in the proposed humic substance degradation pathway. In addition, the bacteria producing extracellular polymeric substances were increased in the MBR-H. check details Substantial variation of microbial community function was occurred in the MBR to degrade humic acid. Operational parameters in MBRs might be sought to maintain water permeability and to obtain preferable condition to evolution of microbial consortia for degradation of the refractory organic matter.In this work, a temperature-sensitive block polymer PDEA-b-P(DEA-co-AM) was synthesized and then introduced into the preparation of a smart Ru(Ⅲ) imprinted polymer (Ru-IIP) to selectively adsorption Ru(Ⅲ) first. Then the waste Ru-IIP was converted into a catalyst in-situ for recycle. The structure and morphology of the prepared polymer were characterized by Fourier transform infrared spectrometer, Scanning electron microscope, BET surface area and Thermogravimetric analysis. The adsorption properties of the synthesized smart material were investigated in terms of adsorption pH, adsorption kinetics and adsorption isotherm. Results documented that the optimal adsorption temperature and pH were 35 °C and 1.5 respectively, the maximum adsorption capacity was 0.153 mmol/g, and the adsorption processes of Ru-IIP were more suitable to be expressed by pseudo-first-order kinetic and Langmuir model. The selectivity studied in different binary mixed solutions showed that Ru-IIP has good selectivity, and reusability results showed that Ru-IIP still maintains a good adsorption effect after 8 cycles. In addition, the waste Ru-IIP, a Ru(Ⅲ) remained waste sample was employed as the catalyst for the synthesis of imines, and result showed the mass of adsorbent would reduce after the completion of catalysis, which could not only catalyze the reaction but also reduce pollution.The migration risk of antibiotic and antibiotic resistance genes (ARGs) have attracted lots of attentions due to their potential threaten to public health. Strategies to reduce their vertical mobilization risk are urgently required for groundwater safety and human health. Biochar enjoys numerous interests due to its excellent sorption affinity. However, little was known about the efficacy of biochar amendment in impeding the vertical mobilization of antibiotic and ARGs. To fill this gap, a column study was carried out to investigate biochar-induced variations in the leaching behavior of dissolved organic matter (DOM), sulfamethazine (SMZ) and ARGs. Results showed that biochar addition enhanced DOM export from soil, changed its composition and impeded the vertical transport of SMZ. Biochar amendment could effectively decrease the occurrence of extracellular and intracellular sul2 in soil and impede its vertical transportation, however, it did not work out with sul1 gene. Structural equation modeling analysis demonstrated that the abundance of sul2 was significantly controlled by SMZ concentration, while the primary drivers of sul1 were SMZ concentration and DOM content. These results indicated the failure in inhibiting the vertical transfer of sul1 under biochar amendment and highlighted the important role of DOM in the leaching of soil ARGs.Arsenic is the leading toxicant of hazardous environmental chemicals, which is linked with neurotoxicity including cognitive dysfunction, neurodevelopmental alterations and neurodegenerative disorders. It has been suggested that sustained pro-inflammatory response is one of the triggering factors of arsenic-induced neurotoxicity. Microglia, the immune cells in the central nervous system, response to physiological and pathological stress, and release a large array of pro-inflammatory cytokines if activated excessively. Several studies indicated that arsenic was capable of inducing microglia activation, however, the role of the subsequently released pro-inflammatory cytokines in arsenic-induced neurotoxicity remains to be elucidated. Our findings demonstrated that arsenic-induced cognitive dysfunction, microglia activation, up-regulation and release of IL-1β and ER stress-mediated apoptosis could be attenuated by minocycline, a recognized inhibitor of microglia activation. In addition, the IL-1 receptor antagonist IL-1ra diminished arsenic-induced activation of ER stress-mediated apoptotic pathway PERK/eIF2α/ATF4/CHOP and neuronal apoptosis. Our findings provided evidences that arsenic-induced microglia activation also contributed to neuronal apoptosis through pro-inflammatory cytokine. Microglia-derived IL-1β promoted hippocampal neuronal apoptosis through ER stress-mediated PERK/eIF2α/ATF4/CHOP apoptotic pathway. Neuronal apoptosis induced by prolonged activation of microglia was partially involved in the arsenic-induced cognitive dysfunction.The pollution of aquatic systems with noxious organic and inorganic contaminants is a challenging problem faced by most countries. Water bodies are contaminated with diverse inorganic and organic pollutants originating from various diffuse and point sources, including industrial sectors, agricultural practices, and domestic wastes. Such hazardous water pollutants tend to accumulate in the environmental media including living organisms, thereby posing significant environmental health risks. Therefore, the remediation of wastewater pollutants is a priority. Adsorption is considered as the most efficient technique for the removal of pollutants in aqueous systems, and the deployment of suitable adsorbents plays a vital role for the sustainable application of the technique. The present review gives an overview of polyurethane foam (PUF) as an adsorbent, the synthesis approaches of polyurethane, and characterization aspects. Further emphasis is on the preparation of the various forms of polyurethane adsorbents, and their potential application in the removal of various challenging water pollutants. The removal mechanisms, including adsorption kinetics, isotherms, thermodynamics, and electrostatic and hydrophobic interactions between polyurethane adsorbents and pollutants are discussed. In addition, regeneration, recycling and disposal of spent polyurethane adsorbents are reported. Finally, key knowledge gaps on synthesis, characterization, industrial applications, life cycle analysis, and potential health risks of polyurethane adsorbents are discussed.We evaluate the isolated and combined effects of glyphosate and its by-product aminomethylphosphonic acid (AMPA) and the potential of the aquatic macrophyte Salvinia molesta to remove these chemicals from contaminated water. Plants were exposed to environmentally relevant concentrations of glyphosate (0, 20, 40, 60, 80 and 100 µg l-1) or AMPA (0, 10, 20, 30, 40 and 50 µg l-1) for seven days. Then, based on the effective concentrations of glyphosate found to reduce photosynthetic rates by 10% (EC10) and 50% (EC50), the plants were exposed to combinations of 0, 16 and 63.5 µg glyphosate l-1 and 0, 5, 15, 25 µg AMPA l-1. The EC(10) and EC(50) were lower for AMPA (6.1 µg l-1 and 28.4 µg l-1 respectively) than for glyphosate (16 and 63.5 µg glyphosate l-1 respectively). When occurring together, the deleterious effects of those chemicals to plants increased. S. molesta plants removed up to 74.15% of glyphosate and 71.34% of AMPA from culture water. Due to its high removal efficiency, S. molesta can be used in phytoremediation programs. It will be important to evaluate the combined effects of glyphosate and AMPA in any toxicological studies of the herbicide.The deep removal of quinoline from coking wastewater is a prerequisite for reducing its potential threat to environmental safety. Therefore, it is urgent to develop advanced materials for efficient removal of quinoline in wastewater. In this work, a nitrogen-doped hollow carbon nanosphere/graphene composite aerogel (HCNS/NGA) was prepared by in-situ reduction self-assembly strategy, in which HCNS prevents the agglomeration of graphene oxide (GO) nanosheets, and a special sphere-sheet mutual support structure is formed to ensure the structural stability. As-prepared HCNS/NGA exhibits large specific surface area, hierarchical pore structure, and excellent conductivity. Large cavity inside and hierarchically porous structure that primarily consists of micropores, resulting in high quinoline adsorption performance (138.37 ± 2.58 mg g-1 at 298 K). Furthermore, in a fixed-bed column adsorption system, the partition coefficient at 10% breakthrough reaches up to 35.19 mg g-1 μM-1. More importantly, HCNS/NGA, as a conductive monolithic sorbent, can realize easy solid-liquid separation, as well as efficient regeneration in situ by electrochemically assisted regeneration. After ten regeneration cycles, the adsorption capacity retention is 91.54%. In short, as an efficient adsorbent, HCNS/NGA has an enormous application potential in wastewater treatment.Removal of toxic Cr (VI) from aqueous solutions using silicon-based adsorbents has been widely investigated. Meanwhile, contradictory between highly dispersed active Cr species and high Cr loading over commercial Cr-based catalyst was inevitable. In this work, amino-assisted electrostatic adsorption from toxic Cr (VI) treatment was developed to prepare highly dispersed Cr oxides catalysts supported on MCM-41. The Cr loading was as high as 15 wt%, and structure characters of the catalysts were well-reserved. As a result, electrostatic adsorption and subsequent complexation from negatively charged Cr (VI) species and positively charged ammonium groups made a positive contribution to the appearance of highly dispersed mono Cr species, which gave rise to improved non-oxidative propane dehydrogenation (PDH) activity. In contrast, the agglomeration of Cr species and lower PDH activity were observed on the sample synthesized using the traditional wet impregnation method. Besides, the transformation of Cr (VI) to active Cr (III) sites over the catalyst was proved by the designed in-situ H2-TPR, ex-situ UV-vis and Raman spectra results. This procedure reflects a new avenue of green chemistry, which can recycle waste Cr adsorbents as efficient PDH catalysts.
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