Notes

Childhood maltreatment, pubertal growth, HPA axis performing, as well as psychosocial benefits: A great integrative biopsychosocial design.
Nowadays, environment-friendly and sustainable polymers have aroused great research attention, due to serious pollution caused by nondegradable and nonrenewable polymer waste. In this paper, chitosan (CS) grafted polyethylene glycol monomethyl ether (mPEG) (CS-g-mPEG) fiber, with solid-solid phase change (SSPC) behavior and improved mechanical performance, were prepared successfully by in-situ wet spinning process. The tensile strength of CS-g-mPEG fiber reached 1.36 cN/dtex, increased by more than 50 % contrasted with CS fiber, due to the enhancement of molecular entanglement and hydrogen bonding interactions. Particularly, CS-g-mPEG fiber with stable shape could actively absorb heat as ambient temperature above 46 °C, then would release heat as ambient temperature below 26 °C. So, the human body will not feel too cold or heat. Thus, this work do not only give a continuous process of fabricating SSPC CS-g-mPEG fiber for industry, but also provides an important choice for smart textiles.Nanocomposite film of pullulan (PULL), tempo cellulose nanofibrils (TOCNs) and, montmorillonite clay (MMT) were prepared using a solution casting method with aqueous solutions. X-ray diffraction data revealed that exfoliated MMT nanoplatelets are distributed within the PULL/TOCNs/MMT film structure. Fourier-transform infrared results revealed that there might be interactions among the TOCNs, MMT and PULL matrix led to improved tensile strength, thermal stability, water barrier properties, and decrease moisture susceptibility while maintained reasonable transparency and biodegradability of the ternary PULL nanocomposites. BMS-794833 price These excellent properties of the nanocomposites clearly indicate towards a new strategy for developing high-performance PULL-based nanocomposites by using two different types of fillers with various geometric shapes and aspect ratio. This kind of ternary nanocomposite film can be broadly used in food packaging and protection as a green and biodegradable film.An active ink composed of cellulose nanofibrils and silver nanowires was deposited on flexible and transparent polymer films using the bar coating process, achieving controlled thicknesses ranging from 200 nm up to 2 μm. For 350 nm thick coating on polyethylene terephthalate films, high transparency (75.6% transmittance) and strong reduction of bacterial growth equal to 89.3% and 100% was noted respectively against Gram-negative Escherichia Coli and Gram-positive Staphylococcus Aureus bacteria using AATCC contact active standard test. Retained antibacterial activity was found with films produced by reverse gravure roll-to-roll process, showing the promising capability of this antibacterial solution to be deployed industrially. Finally, the same ink was also deposited on polylactic acid substrate to investigate barrier properties for 350 nm thick coating, a reduction of 49% of oxygen transmission rate (dry conditions) and 47% reduction of water vapor transmission rate was noted, proving the enhanced barrier properties of the coatings.Polypyrrole (PPy) and cellulose nanofiber (CNF) based conducting composite films were synthesized using two new approaches, in-situ polymerization of pyrrole onto cellulose nanopaper (PPy/CNP) and polyvinyl alcohol coated cellulose nanopaper (PPy/PVA-CNP). Significant improvement in the conductivity, tensile strength, water resistance, and electromagnetic shielding effectiveness (SE) was observed for these composite films compared to commonly used in-situ nanofiber (ISF) approach, where PPy is coated on nanofibers prior to film preparation. Maximum improvement in conductivity, SE and tensile strength of PPy/PVA-CNP compared to ISF films was attributed to highly uniform and compact PPy coating and reduced porosity. SE of -23 dB (thickness upto 138.4 μm) and tensile strength of 103.8 MPa for PPy/PVA-CNP films are the highest values found in the literature for PPy and CNF based composite films at a comparable thickness. These new approaches could enable a scalable preparation of flexible conducting composite films with superior physical and electrical properties for EMI shielding applications.The process optimization and biological characterization of marshmallow root polysaccharides (MRPs) obtained from the microwave-assisted extraction (MAE) were studied. The highest MAE-yield (14.47%) was optimized at 457.32 W and 75 °C for 26 min. The extracted crude polysaccharides were purified using ion-exchange and gel-filtration chromatographies and eluted a single symmetrical narrow peak, showing a homogenous fraction (MRP-P1) with a molecular weight of 4.87 × 104 Da. The surface morphology of polysaccharides and functional groups of MRP-P1 were determined by employing scanning electron microscopy and Fourier-transform infrared spectroscopy, respectively. The major monosaccharide composition of MRPs were the three monomers of rhamnose, galactose, and glucose. The antioxidant, antimicrobial, and antitumor activities were increased in a concentration-dependent manner (1.0-10.0 mg/mL). MRP-P1 exhibited a strong in vitro antiproliferative activity against lung (A549), liver (HepG2), and breast (MCF-7) cancer cells. The anticancer activity of polysaccharides extracted under optimal MAE conditions was highly associated with their antioxidant and antibacterial functions.Starch has received research focus due to its low cost, excellent film-forming ability, bio-compatibility, extensive sources, renewability and biodegradability. However, native starch with relatively strong hydrophilicity greatly limits its application in industries. Therefore, in this paper, the recent research advances in chemical modifications of starch for hydrophobicity, e.g., esterification, etherification, crosslinking, grafting and condensing reaction etc., were discussed. The changes of hydrophobicity and other properties due to chemical modifications were described, as well. Different applications of modified starch with better hydrophobicity, i.e., packaging industries, Pickering emulsion and pharmaceutical, are presented, too. Finally, the future research and prospects on chemical modifications of starch for hydrophobicity and their applications are proposed.The effect of modification with phenolic extracts from grape pomace (GPE) and sorghum bran (SBE) under alkaline conditions for 6 and 12 h, with and without washing with aqueous ethanol (post modification) on the enzymatic hydrolysis as measured by viscosity decrease and antioxidant activity of maize starch was studied. Phenolic-modified starches showed lower rate of starch hydrolysis. The DSC of residues after enzyme hydrolysis showed the conversion of type I inclusion complexes in the unwashed to type II inclusion complexes in the washed phenolic-modified starches. FTIR suggests the presence of covalent bonds in the residues of the phenolic-modified starches due to the retention of starch-bound phenolics. Phenolic-modified starches showed ABTS radical scavenging activity. Ultra-fast liquid chromatography showed polymerisation of monomeric and dimeric procyanidins to oligomeric procyanidins in GPE and SBE-modified starches. It can be concluded that phenolic-modified starches with relatively low hydrolysis and antioxidant activity can be produced under alkaline conditions.Lignocellulosic fibers and microcellulose have been obtained by simple alkaline treatment from softwood almond shells. In particular, the Prunus dulcis Miller (D.A.) Webb. was considered as a agro industrial waste largely available in southern Italy. The materials before and after purification have been characterized by 13C CPMAS NMR spectroscopy methodology. A proper data analysis provided the relative composition of lignin and holocellulose at each purification step and the results were compared with thermogravimetric analysis and FT-IR. To value the possibility of using this material in a circular economy framework, the fibrous cellulosic material was used to manufacture a handmade cardboard. The tensile performances on the prepared cardboard proved its suitability for packaging purposes as a sustainable material. These fibers along with the obtained microcellulose can represent a new use for the almond shells that are mainly used as firewood.High strength and self-healing properties of hydrogels are of great interest in tissue engineering and biomedical fields. In this paper, nanocomposite hydrogels were prepared by freeze-thaw cycle method via fabricating physical cross-links into chemical-crosslinked formed polymer network. The properties of nanocomposite hydrogels were characterized by FTIR, XRD, SEM, rheological analysis, swelling analysis and mechanical test. The results showed that the electrostatic interaction between CNC and QAX and the high amount of PVA (20 wt%) were favorable to improve the mechanical properties of nanocomposite hydrogels, in which the maximum compressive strength and elongation at break of nanocomposite hydrogels were 1.56 MPa and 771 %, respectively. Prepared hydrogels achieved self-healing without any external stimuli at room temperature with the help of hydrogen bonds and the entanglement of long polymer chains, the healing efficiency was 37.03 % within 48 h. These hydrogels with high strength and self-healing properties will offer new insights for xylan application.Global increase of antibiotic-resistant pathogens as well as elevated content of drug residues in the foodstuffs and the environment urgently calls for new biocompatible antimicrobial biomaterials. Yeast mannans represent readily available source of biodegradable materials for tailor-made derivatives that could be effective in biomedical applications. Here, antimicrobial properties of quaternized mannans (DSQ 0.12, 0.24, 0.30, 0.62) from Candida albicans against clinical multi-resistant strains of Staphylococcus aureus are confronted with possible cytotoxicity against human cells. As expected, both effects increase with increasing degree of quaternization. However, it is possible to define the "window", at quaternized mannan with DSQ 0.30 with good anti-microbial effectiveness and low cytotoxicity. This derivative exhibit minimum inhibitory (MIC) and minimum bactericidal (MBC) concentration from 62.5 to 250 μg/mL and demonstrate good biofilm inhibition effect. Also acceptable values were obtained in hemagglutination and hemolytic activity assays and also in cytotoxicity tests on human fibroblasts.Transparent film with high thermal resistance and antimicrobial properties has many applications in the food packaging industry particularly packaging for reheatable food. This work investigates the effects of heat treatment on the thermal resistance, stability of transparency and antimicrobial activity of transparent cellulose film. The film from ginger nanocellulose fibers was prepared with chemicals and ultrasonication. The dried film was heated at 150 °C for 30, 60, 90, or 120 min. The unheated and sonicated film had the lowest crystallinity index and the lowest thermal properties. After heating, the film became brownish-yellow resulting from thermal oxidation. The reheated film had higher thermal resistance than unheated film. Heating led to further relaxation of cellulose network evidenced by shifting of the XRD peak positions toward lower values. The antimicrobial activity decreased due to heating. Average opacity value increases after short heating durations. It was relatively stable for further heating.
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