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Precisely how Efficient Could be the Green Growth Policy associated with China's Yangtze River Economic Gear? Any Quantitative Analysis In line with the PMC-Index Design.
An analysis is presented in this paper.As the most important paper packaging materials, corrugated cartons with a tremendous amount of production demonstrate several advantages and have been widely used in daily life. However, waste corrugated cartons (WCCs) are usually recycled and reused to produce new corrugated cartons, and their properties are decreased dramatically after several cycles. Therefore, recycling and converting WCCs into cellulose-based film with high value is attractive and significant. Herein, without any pretreatment, the waste old corrugated cartons were directly dissolved in ionic liquid 1-allyl-3-methylimidazolium chloride, and semitransparent cellulose-based films were successfully fabricated. It was indicated that cellulose-based films displayed better UV-shielding property and hydrophobicity than traditional cellulose films. Interestingly, the cellulose-based films regenerated from deionized water displayed higher tensile strength, elongation at break, and toughness. Their tensile strength could reach 23.16 MPa, exhibiting enormous superiority as wrapping and packaging materials to replace the petrochemical polyethylene membrane (8.95 MPa). Consequently, these renewable, biodegradable, and high-valued cellulose-based films were successfully fabricated to simultaneously realize the valorization of old corrugated cartons and supplement the petrochemical plastics.Sustainable composite brake pads were processed by employing recycled end-of-life tire (ELT) rubber particles obtained by means of cryogenic grinding and ambient grinding. The effect of the grinding mechanism and concentration of ELT rubber particles was then reported. From the friction result test, better behavior in terms of coefficient of friction (COF) was obtained when 3% of ELT rubber particles were introduced into the composite. It was demonstrated that the size of the particles is not as determinant as the friction mechanism in the wear properties of the sustainable brake pads. Whereas, while increasing the ELT rubber particle size acts as detrimental to the COF either in the ambient or cryogenic grinding, at high friction distances, the better adhesion of the particles because of the rough surface of the particles subjected to ambient grinding enhances the long-life behavior of the composite brake pads.A novel nanomaterial, bacterial cellulose (BC), has become noteworthy recently due to its better physicochemical properties and biodegradability, which are desirable for various applications. Since cost is a significant limitation in the production of cellulose, current efforts are focused on the use of industrial waste as a cost-effective substrate for the synthesis of BC or microbial cellulose. The utilization of industrial wastes and byproduct streams as fermentation media could improve the cost-competitiveness of BC production. This paper examines the feasibility of using typical wastes generated by industry sectors as sources of nutrients (carbon and nitrogen) for the commercial-scale production of BC. Numerous preliminary findings in the literature data have revealed the potential to yield a high concentration of BC from various industrial wastes. These findings indicated the need to optimize culture conditions, aiming for improved large-scale production of BC from waste streams.Additive manufacturing (AM) is a sustainable and innovative manufacturing technology to fabricate products with specific properties and complex shapes for additive manufacturable materials including polymers, steels, titanium, copper, ceramics, composites, etc. This technology can well facilitate consumer needs on products with complex geometry and shape, high strength and lightweight. It is sustainable with having a layer-by-layer manufacturing process contrary to the traditional material removal technology-subtractive manufacturing. However, there are still challenges on the AM technologies, which created barriers for their further applications in engineering fields. For example, materials properties including mechanical, electrical, and thermal properties of the additively manufactured products are greatly affected by using different ways of AM methods and it was found as the material anisotropy phenomenon. In this study, a detailed literature review is conducted to investigate research work conducted on the material anisotropy phenomenon of additively manufactured materials. Based on research findings on material anisotropy phenomenon reported in the literature, this review paper aims to understand the nature of this phenomenon, address main factors and parameters influencing its severity on thermal, electrical and mechanical properties of 3D printed parts, and also, explore potential methods to minimise or mitigate this unwanted anisotropy. The outcomes of this study would be able to shed a light on improving additive manufacturing technologies and material properties of additively manufactured materials.The limitations and difficulties that nerve autografts create in normal nerve function recovery after injury is driving research towards using smart materials for next generation nerve conduits (NCs) setup. Here, the new polymer partially oxidized polyvinyl alcohol (OxPVA) was assayed to verify its future potential as a bioactivated platform for advanced/effective NCs. Sodium Bicarbonate mw OxPVA-patterned scaffolds (obtained by a 3D-printed mold) with/without biochemical cues (peptide IKVAV covalently bound (OxPVA-IKVAV) or self-assembling peptide EAK (sequence AEAEAKAKAEAEAKAK), mechanically incorporated (OxPVA+EAK) versus non-bioactivated scaffold (peptide-free OxPVA (PF-OxPVA) supports, OxPVA without IKVAV and OxPVA without EAK control scaffolds) were compared for their biological effect on neuronal SH-SY5Y cells. After cell seeding, adhesion/proliferation, mediated by (a) precise control over scaffolds surface ultrastructure; (b) functionalization efficacy guaranteed by bioactive cues (IKVAV/EAK), was investigated by MTT assay at 3, 7, 14 and 21 days. As shown by the results, the patterned groove alone stimulates colonization by cells; however, differences were observed when comparing the scaffold types over time. In the long period (21 days), patterned OxPVA+EAK scaffolds distinguished in bioactivity, assuring a significantly higher total cell amount than the other groups. Experimental evidence suggests patterned OxPVA-EAK potential for NCs device fabrication.Finding a simple and eco-friendly production technique that matches to the natural agent and results in a truly valuable natural scaffold production is still limited amongst the intensively competitive natural scaffold development. Therefore, the purpose of this study was to develop natural scaffolds that were environmentally friendly, low cost, and easily produced, using natural agents and a physical crosslinking technique. These scaffolds were prepared from agarose and sericin using the freeze-drying method (D) or freeze-thawing together with the freeze-drying method (TD). Moreover, plasticizers were added into the scaffold to improve their properties. Their physical, mechanical, and biological properties were investigated. The results showed that scaffolds that were prepared using the TD method had stronger bonding between sericin and other compounds, leading to a low swelling ratio and low protein release of the scaffolds. This property may be applied in the development of further material as a controlled drug release scaffold. Adding plasticizers, especially glycerin, into the scaffolds significantly increased elongation properties, leading to an increase in elasticity of the scaffold. Moreover, all scaffolds could activate cell migration, which had an advantage on wound healing acceleration. Accordingly, this study was successful in developing natural scaffolds using natural agents and simple and green crosslinking methods.In this paper, in order to improve the electrical and thermal properties of SiC/EP composites, the methods of compounding different crystalline SiC and micro-nano SiC particles are used to optimize them. Under different compound ratios, the thermal conductivity and breakdown voltage parameters of the composite material were investigated. It was found that for the SiC/EP composite materials of different crystal types of SiC, when the ratio of α and β silicon carbide is 11, the electrical performance of the composite material is the best, and the breakdown strength can be increased by more than 10% compared with the composite material filled with single crystal particles. For micro-nano compound SiC/EP composites, different total filling amounts of SiC correspond to different optimal ratios of micro/nano particles. At the optimal ratio, the introduction of nanoparticles can increase the breakdown strength of the composite material by more than 10%. Compared with the compound of different crystalline SiC, the advantage is that the introduction of a small amount of nanoparticles can play a strong role in enhancing the break-down field strength. For the filled composite materials, the thermal conductivity mainly depends on whether an effective heat conduction channel can be constructed. Through experiments and finite element simulation calculations, it is found that the filler shape and particle size have a greater impact on the thermal conductivity of the composite material, when the filler shape is rounder, the composite material can more effectively construct the heat conduction channel.This study reports the feasible use of chitosan as a thin film biosensor on the very sensitive quartz crystal micro balance system for detection of blends of multiple templates within a single matrix. The development of chitosan-based thin film materials with selectivity for nicotine derivatives is described. The molecular imprinting of a combination of nicotine derivatives in N-diacryloyl pipiradine-chitosan-methacrylic acid copolymer films on quartz crystal resonators was used to generate thin films with selectivity for nicotine and a range of nicotine analogues, particularly 3-phenylpyridine. The polymers were characterized by spectroscopic and microscopic evaluations; surface area, pore size, pore volume using Breuner-Emmet-Teller method. Temperature characteristics were also studied. The swelling and structure consistency of the Chitosan was achieved by grafting with methylmethacrylic acid and cross-linking with N-diacrylol pipiradine. A blend of 0.002 g (0.04 mmol) of Chitosan, 8.5 μL Methylmethacrylic Acid and 1.0 mg N-diacrylol pipradine (BAP) presented the best blend formulation. Detections were made within a time interval of 99 s, and blend templates were detected at a concentration of 0.5 mM from the Quartz crystal microbalance resonator analysis. The successful crosslinking of the biopolymers ensured successful control of the swelling and agglomeration of the chitosan, giving it the utility potential for use as thin film sensor. This successful crosslinking also created successful dual multiple templating on the chitosan matrix, even for aerosolized templates. The products can be used in environments with temperature ranges between 60 °C and 250 °C.A facile method for the preparation of hierarchically porous spherical particles using high internal phase water-in-oil-in-water (w/o/w) double emulsions via the photopolymerization of the water-in-oil high internal phase emulsion (w/o HIPE) was developed. Visible-light photopolymerization was used for the synthesis of microspherical particles. The HIP emulsion had an internal phase volume of 80% and an oil phase containing either thiol pentaerythritol tetrakis(3-mercaptopropionate) (PETMP) or trimethylolpropane tris(3-mercaptopropionate) (TMPTMP) and acrylate trimethylolpropane triacrylate (TMPTA). This enabled the preparation of microspheres with an open porous morphology, on both the surface and within the microsphere, with high yields in a batch manner. The effect of the thiol-to-acrylate ratio on the microsphere diameter, pore and window diameter, and degradation was investigated. It is shown that thiol has a minor effect on the microsphere and pore diameter, while the acrylate ratio affects the degradation speed, which decreases with increasing acrylate content.
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