Notes

Prophylactic fasciotomy of the anterolateral upper leg contributor internet site in neck and head renovation.
Native plants in metal pollution sites have great potentials for mine rehabilitation. In the presented work, we investigated Vanadium (V) concentrations of soils and plants (Heteropogon contortus) in Majiatian V-Ti magnetite tailing reservoir in Panzhihua, Southwestern China. The objectives were to explore the V accumulation mode of H. contortus and its driving factors, as well as the phytoremediation potential of H. contortus. As the results, H. contortus accumulated 37.53 mg/kg and 8.69 mg/kg of V in root and aerial part, respectively. With the increase of rehabilitation age, root V concentrations decreased, while aerial part V concentrations remained constant. The significant negative correlations between root V and soil V, acid-soluble V (VHAc) (P less then 0.05) indicated that increasing soil V and VHAc concentrations drove the V accumulation mode of H. contortus. Soil properties had a little influence on the V accumulation mode of H. contortus. Therefore, H. contortus might be not the suitable plant extractant to remove V from mine tailing for its lower V accumulation capacity. On the other hand, it can tolerate high V stress through elimination and detoxification/isolation V. Furthermore, the settlement of H. contortus increased the content of soil organic matter and might thus improve the soil quality. The cover of H. contortus is also beneficial to reduce the dispersion of the tailings and prevent contaminating surrounding soil. Therefor it showed a great potential to serve as a pioneer plant in the remediation of V-rich tailing reservoirs and other V-contaminated sites with similar poor soil condition.In this work, the primary focus is given on a mixture of 27 micropollutants (pharmaceuticals, pesticides, herbicides, fungicides and others) and its removal from aqueous solution by phytoremediation. Phytoremediation belongs to technologies, which are contributing on removal of micropollutants from wastewater in constructed wetlands. Constructed wetlands can be used as an additional step for elimination of micropollutants from municipal medium-sized wastewater treatment plants. To our knowledge, such a broad variety of micropollutants was never targeted for removal by phytoremediation before. In this work, we carry out experiments with 3 emergent macrophytes Phragmites australis, Iris pseudacorus and Lythrum salicaria in hydroponic conditions. The selected plants are exposed to mixture of micropollutants in concentrations 1-14 mg/l for a time period of 30 days. The highest affinity for phytoremediation is detected at groups of fluorosurfactants (removal rate up to 30%), beta-blockers (removal rate up to 50%) and antibiotics (removal rate up to 90%). The leading capability for micropollutant uptake is detected at Lythrum salicaria, where 25 out of 27 compounds are removed with more than 20% efficiency. The results demonstrate well usefulness of this technology e.g. in an additional treatment step, because the mentioned groups of micropollutants are removed with comparable or even higher effectivity, than it is in case of conventional wastewater treatment plants.Per-, Poly-fluoroalkyl substances (PFASs) accumulation in benthic environments is mainly determined by material mixing and represents a significant challenge to river remediation. However, less attention has been paid to the effects of sediment distribution on PFASs accumulation, and how PFASs influence microbial community coalescence and biogeochemical processes. In order to identify correlations between PFASs distribution and benthic microbial community functions, we conducted a field study and quantified the ecological constrains of material transportation on benthic microorganisms. Perfluorohexanoic acid (PFHxA) contributed most to the taxonomic heterogeneity of both archaeal (12.199%) and bacterial (13.675%) communities. Genera Methanoregula (R2 = 0.292) and Bacillus (R2 = 0.791) were identified as indicators that respond to PFASs. Phylogenetic null modeling indicated that deterministic processes (50.0-82.2%) dominated in spatial assembly of archaea, while stochasticity (94.4-97.8%) dominated in bacteria. Furthermore, spatial mixing of PFASs influenced broadly in nitrogen cycling of archaeal genomes, and phosphorus mineralization of bacterial genomes (p less then 0.05). Overall, we quantified the effect of PFASs on community assembly and highlighted the constrains of PFASs influence on benthic geochemical potentials, which may provide new insights into riverine remediation.A novel strategy was described to fabricate hematite-MOF materials with morphologies (core-shell) and (composite) as an efficient peroxymonosulfate (PMS) activator for degrading ciprofloxacin (CIP) antibiotics. First, α-Fe2O3 nanoparticles (NPs) with a size distribution range of 80 nm were prepared by surfactant-assisted reflux method. Then, cobalt-based metal-organic framework (ZIF-67) was grown onto the α-Fe2O3 NPs with ultrasonic and solvothermal method, which can control the nanostructures morphology. The physicochemical properties of these nanostructures were probed by ATR-IR, WA-XRD, FESEM, VSM, TEM, and EDS spectroscopy. The results showed that all the added CIP (20 ppm) antibiotics were completely degraded in 30 min in the α-Fe2O3/ZIF-67 (0.10 g/L) and PMS (0.20 g/L) system with rate constant of 0.130 min-1. To validate the merits of the α-Fe2O3/ZIF-67, α-Fe2O3@ZIF-67 core-shell nanostructures were also applied under similar conditions. The findings demonstrated that Co/Fe species within α-Fe2O3/ZIF-67 composite catalyzed PMS synergistically to the formation of the OH and SO4- and 1O2 for CIP degradation. Furthermore, α-Fe2O3/ZIF-67 showed good recyclability enabling facile separation of the catalyst from reaction mixtures using an external magnet. The current protocol can be a useful criterion in designing various Magnetic-MOF composites with controlled morphologies for environmental remediation.Lignin is a low-cost and environmental-friendly material and could increase the solubility of phosphorus (P) in soils. Meanwhile, application of P compounds to soils decreases the bioavailability of heavy metals. However, there are few reports on whether lignin-induced P release immobilizes heavy metals in soil. see more This study investigated this possibility by adding alkaline lignin to forest, paddy and upland soils differing in pH and available P. The amendment of alkaline lignin increased soil P availability and enhanced the adsorption and decreased the desorption percentages of Cd in acid forest and paddy soils. The P released from the soil could immobilize Pb and Cd but the presence of Pb decreased the adsorption capacity of Cd on the acid soils. In comparison, the alkaline lignin decreased Cd adsorption and raised Cd desorption in the alkaline upland soil, due to the formation of soluble complex of hydrophilic organic matter with Cd. In addition, precipitation, complexion, and competition effect among Cd, P and lignin in different soils led to various P concentrations in the experiment.
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