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006, -0.001) and the inverse relation was more pronounced in male infants. In addition, PM2.5 level in the 2nd trimester was negatively related to activetone score (β, -0.012; 95% CI, -0.021, -0.002) in a dose-dependent manner for both genders. click here Collectively, our results demonstrated that prenatal exposure to PM2.5 was linked to poor neurobehavioral performance of newborns. The second trimester was the most sensitive time window for the developments of behavior and activetone, and male subject was more vulnerable as compared to females. Anaerobic co-digestion (AcoD) can increase methane production of anaerobic digesters in plants treating wastewater sludge by improving the nutrient balance needed for the microorganisms to grow in the digesters, resulting in a faster process stabilization. Substrate mixture proportions are usually optimized in terms of biogas production, while the metabolic biodegradability of the whole mixture is neglected in this optimisation. In this aim, we developed a strategy to assess AcoD using metabolomics data. This strategy was explored in two different systems. Specifically, we investigated the co-digestion of wastewater sludge with different proportions of either grass or fish waste using untargeted High Performance Liquid Chromatography coupled to Mass Spectrometry (HPLC-MS) metabolomics and chemometrics methods. The analysis of these data revealed that adding grass waste did not improve the metabolic biodegradability of wastewater sludge. Conversely, a synergistic effect in the metabolic biodegradability was observed when fish waste was used, this effect being the highest for 25% of fish waste. In conclusion, metabolomics can be regarded as a promising tool both for characterizing the biochemical processes occurring during anaerobic digestion, and for providing a better understanding of the anaerobic digestion processes. Chlorine-containing organic compounds were discharged informally as a result of untreated industrial wastewater, which caused groundwater pollution. In this study, titanium dioxide nanotube arrays (TNAs) were modified with copper oxide to photoelectrochemical (PEC) active persulfate to degrade trichloroethylene (TCE). The SEM results show copper nano-particles with a cubic shape were successfully deposited on the surface of TNAs. The results of UV-vis analysis indicate the absorption wavelengths red-shift to 550-600 nm for better light utilization. CuO/TNAs were dominated by the anatase phase after sintering at 450 °C with significant visible light response. The chemical contents for the surface of CuO/TNAs are 23.7, 53.4, 18.4 and 4.4% for C, O, Ti and Cu, respectively. The photocurrent of CuO/TNAs is 1.89 times higher than that of TNAs-93 cm^2-1hr under 100 W Hg-lamp illuminations. This demonstrates the efficiency of light utilization of TNAs was improved by the modification with copper nanoparticles. The degradation rate of TCE in the anodic chamber is more effective than that in the cathodic chamber because of the synergistic effect of hydroxyl and sulfate radicals. The mechanism of TCE degradation via persulfate in the PEC system was proposed and discussed in detail. The growth of microplastic (MP) pollution is of increasing concern and represents a global challenge. In situ detection of these small particles is difficult because of their sizes, shapes, transparency or translucency, surface texture and ambient conditions. We propose and demonstrate the use of a prototype optical sensor to detect flat, nearly flat, curved and rough MPs prepared from commercial polyethylene terephthalate (PET) plastics and PET bottles in water. The prototype measures the specular reflection of a laser radiation incident on MPs, with a photodiode, and the transmitted laser speckle pattern, with a charge-coupled device (CCD) camera. The presence of the MPs as well as the optical surface roughness are determined from the specular reflection. Additionally, the so-called speckle contrast calculated from the speckle pattern, as a promising tool, is used to rank the rough MPs according to the different average surface roughness, to approximately twice the wavelength of the probing light. The novel application of laser speckle contrast and the optical roughness estimation allows the description of MP surface roughness in water. Moreover, in combination with earlier studies, these results, therefore, pave a way for the complete and a relatively easier description of MPs properties optical and also advances our step towards the development of simple and robust optical monitoring techniques for micro and nanoplastics in open and wastewater. Barium ferrite nanoparticles (BaFeNPs) are a permanent magnetic nanomaterial widely used in electrical energy storage, recording media or in the improvement of the magnetic properties of other nanoparticles (NPs). However, the information about the toxicity of BaFeNPs is almost non-existent. Thus, in the present work, the antimicrobial effect of BaFeNPs was evaluated for the first time in gram-negative and gram-positive bacteria and yeast showing neither antibacterial nor antifungal activity at moderate concentrations. On the other hand, in order to assess the in vivo toxicity of BaFeNPs the model organism Caenorhabditis elegans was used and ingestion, survival, reproduction and ROS production were evaluated in worms treated with different concentrations of BaFeNPs. Our results show that worms ingest these NPs through the digestive system affecting survival, reproduction and ROS production. In this work acid-treated activated carbon was developed from rice husk, and it was used as raw material for Capacitive deionization (CDI) electrodes. The prepared acid treated rice husk waste biomass activated carbon (RHWBAC) electrode was used for the electrosorption of Cr(VI) from the aqueous medium. This RHWBAC electrode shows maximum electrosorption capacity was 2.8316 mg g-1 of initial feed concentration 100 mg L-1 at 1.2 V. The result shows that the electrosorption method follows Redlich Peterson isotherm, Langmuir isotherm model, and Pseudo first order kinetic model. The computational fluid dynamics (CFD) analysis of square CDI cell design shows that the stagnant regions decreases by increasing the flow rate of feed. The present work concluded that the RHWBAC could be capable electrode material for Cr(VI) sorption from low concentrated aqueous feed.
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