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Genome evaluation associated with Salmonella enterica serovar Typhimurium bacteriophage T, sign pertaining to StySA (StyLT2III) restriction-modification program action.
Neutral titanium oxide clusters of up to 1 nm in diameter (TiO2)n, with n less then 10, are produced in a laser vaporization source and subsequently ionized by a sequence of femtosecond laser pulses. Using a 400 nm pump and 800 nm probe lasers, the excited state lifetimes of neutral (TiO2)n clusters are measured. All clusters exhibit a rapid relaxation lifetime of ∼35 fs, followed by a sub-picosecond lifetime that we attribute to carrier recombination. The excited state lifetimes oscillate with size, with even-numbered clusters possessing longer lifetimes. Density functional theory calculations show the excited state lifetimes are correlated with charge carrier localization or polaron-like formation in the excited states of neutral clusters. Thus, structural rigidity is suggested as a feature for extending excited state lifetimes in titania materials.This paper deals with the synthesis, characterization, and photophysical behaviors of three Ru(II)-terpyridine complexes derived from a terpyridyl-imidazole ligand (tpy-HImzPh3Me2), wherein a terpyridine moiety has been coupled with a dimethylbenzil unit through a phenylimidazole spacer. The three complexes display strong emission at RT having excited-state lifetimes in the range of 2.3-43.7 ns, depending upon the co-ligand present and the solvents used. Temperature-dependent emission spectral measurements have demonstrated that the energy separation between emitting metal-to-ligand charge transfer state and non-emitting metal-centered state is increased relative to that of [Ru(tpy)2]2+. In contrast to our previously studied Ru(II) complexes containing similar terpyridyl-imidazole motif but differing by peripheral methyl groups, significant enhancement of RT emission intensity and quantum yield and remarkable increase of emission lifetime occur for the present complexes upon protonation of the imidazole nitrogen(s) with perchloric acid. Additionally, by exploiting imidazole NH motif(s), we have examined their anion recognition behaviors in organic and aqueous media. Interestingly, the complexes are capable of visually recognizing cyanide ions in aqueous medium up to the concentration limit of 10-8 M. Computational studies involving density functional theory (DFT) and time-dependent DFT methods have been carried out to obtain insights into their electronic structures and to help with the assignment of absorption and emission bands.Dronpa, a GFP (green fluorescent protein)-like fluorescent protein, allows its fluorescent and nonfluorescent states to be switched to each other reversibly by light or heat through E-Z isomerization of the GFP chromophore. In this article, a GFP chromophore (p-HBDI) in water is used as a model to explore this E-Z isomerization mechanism. selleckchem Based on the experimental solvent isotope effect (kH2O/kD2O = 2.30), the E-Z isomerization of p-HBDI in water is suggested to go through the remote-proton-dissociation-regulated direct mechanism with a proton transfer in the rate-determining step. The fractionation factor (ϕ) of the water-associated phenol proton of p-HBDI in the transition state is found to be 0.43, which is exactly in the range of 0.1-0.6 for the fractionation factor (ϕ) of the transferring proton in the transition state of R2O···H···O+H2 in water. This means that the phenol proton of E-p-HBDI in the transition state is on the way to the associated water oxygen during the E-Z isomerization. The proton dissociation from the phenol group of p-HBDI remotely regulates its E-Z isomerization. Less proton dissociation from the phenol group (pKa = 8.0) at pH = 1-4 results in a modest reduction in the E-Z isomerization rate of p-HBDI, while complete proton dissociation from the phenol group at pH = 11-12 also reduces its E-Z isomerization rate by one order of magnitude because of the larger charge separation in the transition state of the p-HBDI anion. All of these results are consistent with the remote-proton-dissociation-regulated direct mechanism but against the water-assisted addition/elimination mechanism.One of the factors that limits the application of the single active electron (SAE) formalism to simulate the high harmonic generation (HHG) spectra of atoms and molecules using the time-dependent Schrödinger equation (TDSE) is the unknown model effective one-dimensional potential energy (V(x)) curve for the SAE. In the present contribution, we show that V(x) can be constructed from the one-dimensional molecular electrostatic potential (MEP) of the respective cation to access theoretical HHG spectra not only for simple atoms but also for multielectron complex molecules.The ability to control and tune magnetic dissipation is a key concept of emergent spintronic technologies. Magnon scattering processes constitute a major dissipation channel in nanomagnets, redefine their response to spin torque, and hold the promise for manipulating magnetic states on the quantum level. Controlling these processes in nanomagnets, while being imperative for spintronic applications, has remained difficult to achieve. Here, we propose an approach for controlling magnon scattering by a switch that generates nonuniform magnetic field at nanoscale. We provide an experimental demonstration in magnetic tunnel junction nanodevices, consisting of a free layer and a synthetic antiferromagnet. By triggering the spin-flop transition in the synthetic antiferromagnet and utilizing its stray field, magnon interaction in the free layer is toggled. The results open up avenues for tuning nonlinearities in magnetic neuromorphic applications and for engineering coherent magnon coupling in hybrid quantum information technologies.Photoswitchable diarylethenes provide a unique opportunity to optically modulate frontier molecular orbital energy levels, thereby opening an avenue for the design of electronic devices such as photocontrollable organic field-effect transistors (OFETs). In the present work, the absolute position of the frontier orbital levels of nonsymmetrical diarylethenes based on a cyclopentenone bridge has been studied using cyclic voltammetry and density functional theory (DFT) calculations. It has been shown that varying heteroaromatic substituents make it possible to change the absolute positions of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of both diarylethene photoisomers. The data obtained are used to refine the operation mechanism of the previously developed OFET devices, employing the cyclopentenone-derived diarylethenes at the dielectric/semiconductor interface.
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