Notes

Cutaneous Several Myeloma.
The coexistence of Cu0, Cu+, and Cu2+ in CF-AA-Cu make it effective in broader pH conditions via the redox reaction between Cu0 and Cu2+. Overall, iodide adsorbents in the form of filters with high adsorption capacity, selectivity, and ability over a wide pH range are potentially useful for removing iodide from water.Recently, there has been increasing interest in reducing methylmercury (MeHg) phytoavailability using biochar, although the underlying mechanisms are not fully understood. By combining lab-scale batch incubation with pot and field validations, we demonstrate that biochar-impacted sulfur cycling in soils and MeHg-soil binding play key roles in controlling MeHg phytoavailability. (1) Under anoxic conditions, biochar-associated sulfate and biochar-facilitated microbial sulfate reduction enhanced the production of reduced inorganic sulfur species as acid-volatile sulfide (AVS) in soils by 122%, facilitating MeHg binding with soils and thus reducing MeHg phytoavailability. (2) In contrast, under oxic conditions, the reduced inorganic sulfur was oxidized (resulting in a 68-91% decrease in AVS), which released soil-bound MeHg and increased MeHg phytoavailability. The proposed mechanisms could explain the distinct effects of biochar amendment on MeHg bioaccumulation observed under anoxic (10-88% lower in rice grains) and oxic conditions (48-84% higher in wheat grains). Our results dispute the commonly held assumption that reduced MeHg phytoavailability under biochar amendment can be primarily attributed to MeHg-biochar binding. Therefore, the potential increased risk of MeHg in oxic soils following biochar amendment should be evaluated in more detail.Plastic debris as the main portion of urban litters could be transported via storm runoff to the water resources. In this study the influence of microplastics (MPs) weathering on their Pb2+ and Zn2+ uptake in stormwater was examined. Low-density polyethylene (LDPE) and polyethylene terephthalate (PET) MPs were subjected to weathering through mechanical interaction with a mixture of silt/sand, and in synthetic stormwater. The surface analysis revealed significant physio-chemistry alterations of LDPE MPs due to the silt/sand weathering. However, this weathering mostly resulted in the surface morphology alterations of PET MPs. The kinetics of heavy metals adsorptions onto the new and stormwater weathered LDPE MPs were best described by pseudo 1st and 2nd models, respectively. Despite increasing Pb2+ uptake by weathered PET MPs, Zn2+ uptake by both new and weathered PET MPs was below the detection limit. Both Pb2+ and Zn2+ were released from new and silt/sand weathered LDPE MPs during five days exposure to the synthetic stormwater. This study underscores the critical role of plastic type and weathering conditions on heavy metal transport by MPs from the urban environment to the water resources.In this work, orange emission fluorescent multifunctional carbon dots (O-CDs) were designed for the label-free detection of vitamin B12 (VB12)，endogenous/exogenous peroxynitrite (ONOO-) sensing, cell imaging, and fluorescent flexible film preparation. The O-CDs with excitation-independent were prepared using safranine T and ethanol as precursors via one-step hydrothermal process. VB12 was utilized as a quencher to quench the fluorescence of O-CDs due to the internal filtration effect (IFE). click here Two-segment linear ranges are 1-65 μM and 70-140 μM, and the detection limit was calculated as 0.62 μM. Besides, ONOO- can reduce the fluorescence intensity of O-CDs based on static quenching (SQ). The linear ranges are 0.3-9 μM and 9-48 μM, and the detection limit was 0.06 μM. Moreover, the O-CDs were exploited as a cellular imaging reagent for intracellular VB12 and endogenous/exogenous ONOO- imaging owing to its great biocompatibility, low toxicity and strong photostability. These results indicate that O-CDs have the potential to be used as a sensitive fluorescence probe to rapidly monitor VB12 and endogenous/exogenous ONOO- with high selectivity in living cells. Also, the as-proposed O-CDs can be employed to fabricate O-CDs/PVA composites as fluorescent flexible films. All of the above prove that the O-CDs present great prospect in multiple applications such as biosensing, cellular labeling, biomedical optical imaging, and fluorescent films.Arsenic (As) removal is a huge challenge, since several million people are potentially exposed (>10 μg/L World Health Organization guideline limit) through As contaminated drinking water worldwide. Review attempts to address the present situation of As removal, considering key topics on nano-technological and biological process and current progress and future perspectives of possible mitigation options have been evaluated. Different physical, chemical and biological methods are available to remove As from contaminated water/soil/wastes, where removal efficiency mainly depends on absorbent type, initial adsorbate concentration, speciation and interfering species. Oxidation is an important pretreatment step in As removal, which is generally achieved by several media such as O2/O3, HClO, KMnO4 and H2O2. The Fe-based-nanomaterials (α/β/γ-FeOOH, Fe2O3/Fe3O4-γ-Fe2O3), Fe-based-composite-compounds, activated-Al2O3, HFO, Fe-Al2O3, Fe2O3-impregnated-graphene-aerogel, iron-doped-TiO2, aerogel-based- CeTiO2, and iron-oxide-coated-manganese are effective to remove As from contaminated water. Biological processes (phytoremediation/microbiological) are effective and ecofriendly for As removal from water and/or soil environment. Microorganisms remove As from water, sediments and soil by metabolism, detoxification, oxidation-reduction, bio-adsorption, bio-precipitation, and volatilization processes. Ecofriendly As mitigation options can be achieved by utilizing an alternative As-safe-aquifer, surface-water or rainwater-harvesting. Application of hybrid (biological with chemical and physical process) and Best-Available-Technologies (BAT) can be the most effective As removal strategy to remediate As contaminated environments.Emerging metallic contaminants (EMCs) are of concern due their presence in aquatic ecosystems and the lack of environmental regulations in several countries. This study verifies the presence of EMCs in two neotropical mangrove estuarine ecosystems (Espírito Santo Brazil) by evaluating abiotic and biotic matrices across six trophic levels (plankton, oyster, shrimp, mangrove trees, crabs and fish) and hence interrogates the trophic transfer of these elements and their possible input sources. Using the oyster Crassostrea rhizophorae as a biomonitor, ten EMCs (Bi, Ce, La, Nb, Sn, Ta, Ti, W, Y and Zr) were determined. Bi input was from iron export and pelletizing industries; Ce, La and Y inputs were mainly associated with solid waste from steel production, while Zr, Nb and Ti were related to atmospheric particulate matter emissions. EMCs were detected at various trophic levels, showing biomagnification for most of them in the Santa Cruz estuary but biodilution in Vitória Bay. These contrasting results between the estuaries could be attributed to different pollution degrees, needing further research to be fully understood.
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