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The paper reports development of graphene/ZnO heterojunction Schottky diode structure and its structural and electrical characterization. Graphene is grown on copper substrate using chemical vapor deposition (CVD) and transferred on flexible substrate (indium Tin Oxide coated PET). The grown thin layer is characterized using scanning electron microscopy and Raman spectroscopy which confirm uniformity and high-quality graphene layer. The sputtered ZnO is deposited and characterized which confirms c-axis (002) orientation and uniform growth of ZnO film. Silver (Ag) as a top electrode has been deposited and I-V measurement has been done. The effect of operating temperature (300 K to 425 K) on I-V characteristics of the fabricated structure has been measured experimentally. The other diode parameters such as ideality factor and effective barrier height have been derived. The reliability of the heterojunction synthesized is proved by the diode ideality factor of 1.03 attained at 425 K. The excellent C-V characteristics (capacitance of 48pF) of the device prove that the device is an excellent candidate for application as supercapacitors. The fabricated structure can be utilized as an ultraviolet photodetector, solar cell, energy storage devices, etc.Lycopene and resveratrol are well-known for their high bioactivity, anti-inflammatory effects, and strong antioxidant properties. The combination of lycopene and resveratrol was synergistic in the potentializing immunity of the mammal body. Caffeic Acid Phenethyl Ester In this study, the scalable co-encapsulation of lycopene and resveratrol into polymeric nanoparticles was performed using lycopene extracted from ripe gac fruit. These nanoparticles exhibited excellent water dispersion and spherical morphology with average particle diameters of 66.102 nm. The particle size was proportional to the lycopene/resveratrol ratio. The combinative use of lecithin and Tween® as surfactants and the use of a polylactide-polyethylene glycol copolymer as an encapsulation agent generated well-defined lycopene/resveratrol nanoparticles although the total content of these active compounds reached 12%. The stability of lycopene was enhanced when combined with resveratrol and antioxidants such as vitamin E and butylated hydroxytoluene. After 3 months of storage at -16 °C, the lycopene content in the lycopene/resveratrol nanopowder remained at ∼95%.MnO₂ nanoparticles were incorporated in reduced graphene oxide (rGO) sheets employing an in-situ, one-step and eco-friendly method. The X-ray diffraction result shows that MnO₂ nanoparticles encapsulation increases the interlayer spacing of rGO. The UV-Vis, FTIR, X-ray photoelectron and Raman spectroscopic studies show that MnO₂ nanoparticles are well intercalated within reduced graphene oxide sheets. The electrochemical studies were executed in 0.5 M aqueous sulphuric acid. The maximum 'specific capacitance' value for MnO₂/reduced graphene oxide nanocomposite was 152.5 F/g at 0.05 V/s. The MnO₂/reduced graphene oxide (MnO₂/rGO) nanocomposite sample displayed an excellent charge retention capacity of 92% after 1000 cycles.A large amount of vinegar residue (VR) is generated every year in China, causing serious environmental pollutions. Meanwhile, as a kind of persistent organic pollutants, polycyclic aromatic hydrocarbons (PAHs) ubiquitously exist in environments. With a goal of reusing VR and reducing PAHs pollutions, we herein isolated one B. subtilis strain, ZL09-26, which can degrade phenanthrene and produce biosurfactants. Subsequently, raw VR was dried under different temperatures (50 °C, 80 °C, 100 °C and 120 °C) or pyrolyzed under 350 °C and 700 °C, respectively. After being characterized by various approaches, the treated VR were mixed with ZL09-26 as carriers to degrade phenanthrene. We found that VR dried at 50 °C (VR50) was the best in promoting the growth of ZL09-26 and the degradation of phenanthrene. This result may be attributed to the residual nutrients, suitable porosity and small surface charge of VR50. Our results demonstrate the potential of VR in the biodegradation of phenanthrene, which may be meaningful for developing new VR-based approaches to remove PAHs in aqueous environments.Foamed paste has attracted much attention because of its excellent thermal insulation performance and diverse applications in infrastructure projects. However, there are still some shortcomings hindering the further application of foamed paste, such as the low mechanical strength and the lack of effective methods to evaluate the properties of foaming bubbles. In this study, surface tension was used as the key parameter to characterize the properties of bubbles. A novel nanomaterial, graphene oxide was employed to enhance the mechanical strength of foamed paste, which was also effective in decreasing the surface tension of aqueous solution. A central composite design scheme was employed to evaluate the influence of three selected factors, surface tension, Sodium Phosphate/foaming reagents mass ratio, and graphene oxide/binder mass ratio, on the engineering properties of foamed paste. Additionally, mercury intrusion porosimetry and scanning electron microscope were employed to elucidate the structure of pores, X-ray diffraction and thermogravimetric analysis were employed to further analyze the hydration products at the microscopic scale. This study reveals that surface tension holds great potential in predicting the engineering properties or performances of foamed paste, and a new mechanism may be developed for explaining the influence of graphene oxide on the pore structure of cementitious materials by evaluating the surface tension of pore solution.Glancing angle deposition (GLAD) oriented electron beam (e-beam) evaporation process has been employed to develop 1D In₂O₃ nanorod array over n-Si substrate. The morphology of as-deposited In₂O₃ thin film (∼70 nm) and GLAD 1D In₂O₃ nanorod array (∼400 nm) were explored using field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS) and high resolution transmission electron microscopy (HRTEM) analysis. The structural analysis were perceived by high-resolution X-ray diffraction (HRXRD) and atomic force microscopy (AFM) techniques. The clampdown of ∼4.4 fold photoluminescence (PL) emission intensity was observed for In₂O₃ nanorod array. Metallization were done to measure the current (I)-voltage (V) characteristics for n-Si/In₂O₃ thin film and n-Si/In₂O₃ nanorod devices. The In₂O₃ nanorod device displayed ∼2.2 fold enhancement in current conduction at -4.6 V and an averagely ∼1.1 fold augmentation in photosensitivity were also observed. The photoresponsivity of ∼28 μA/W, maximum specific detectivity of ∼9.
My Website: https://www.selleckchem.com/products/caffeic-acid-phenethyl-ester.html
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