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Carbonyl umpolung as a possible organometallic reagent surrogate.
A spatially oscillating pair potential Δ(r)=Δ_0e^2iK·r with momentum K>Δ_0/ℏv drives a deconfinement transition of the Majorana bound states in the vortex cores of a Fu-Kane heterostructure (a 3D topological insulator with Fermi velocity v, on a superconducting substrate with gap Δ_0, in a perpendicular magnetic field). In the deconfined phase at zero chemical potential the Majorana fermions form a dispersionless Landau level, protected by chiral symmetry against broadening due to vortex scattering. The coherent superposition of electrons and holes in the Majorana Landau level is detectable as a local density of states oscillation with wave vector sqrt[K^2-(Δ_0/ℏv)^2]. The striped pattern also provides a means to measure the chirality of the Majorana fermions.Simple tuneup of fast two-qubit gates is essential for the scaling of quantum processors. We introduce the sudden variant (SNZ) of the net zero scheme realizing controlled-Z (CZ) gates by flux control of transmon frequency. SNZ CZ gates realized in a multitransmon processor operate at the speed limit of transverse coupling between computational and noncomputational states by maximizing intermediate leakage. Beyond speed, the key advantage of SNZ is tuneup simplicity, owing to the regular structure of conditional phase and leakage as a function of two control parameters. SNZ is compatible with scalable schemes for quantum error correction and adaptable to generalized conditional-phase gates useful in intermediate-scale applications.We explore the finite-temperature dynamics of the quasi-1D orbital compass and plaquette Ising models. We map these systems onto a model of free fermions coupled to strictly localized spin-1/2 degrees of freedom. At finite temperature, the localized degrees of freedom act as emergent disorder and localize the fermions. Although the model can be analyzed using free-fermion techniques, it has dynamical signatures in common with typical many-body localized systems Starting from generic initial states, entanglement grows logarithmically; in addition, equilibrium dynamical correlation functions decay with an exponent that varies continuously with temperature and model parameters. These quasi-1D models offer an experimentally realizable setting in which natural dynamical probes show signatures of disorder-free many-body localization.Quantum effects in condensed matter normally only occur at low temperatures. Here we show a large quantum effect in high-pressure liquid hydrogen at thousands of Kelvins. We show that the metallization transition in hydrogen is subject to a very large isotope effect, occurring hundreds of degrees lower than the equivalent transition in deuterium. We examined this using path integral molecular dynamics simulations which identify a liquid-liquid transition involving atomization, metallization, and changes in viscosity, specific heat, and compressibility. EPZ005687 nmr The difference between H_2 and D_2 is a quantum mechanical effect that can be associated with the larger zero-point energy in H_2 weakening the covalent bond. Our results mean that experimental results on deuterium must be corrected before they are relevant to understanding hydrogen at planetary conditions.In a quantum-noise limited system, weak-value amplification using postselection normally does not produce more sensitive measurements than standard methods for ideal detectors the increased weak value is compensated by the reduced power due to the small postselection probability. Here, we experimentally demonstrate recycled weak-value measurements using a pulsed light source and optical switch to enable nearly deterministic weak-value amplification of a mirror tilt. Using photon counting detectors, we demonstrate a signal improvement by a factor of 4.4±0.2 and a signal-to-noise ratio improvement of 2.10±0.06, compared to a single-pass weak-value experiment, and also compared to a conventional direct measurement of the tilt. The signal-to-noise ratio improvement could reach around six for the parameters of this experiment, assuming lower loss elements.Information causality is a physical principle which states that the amount of randomly accessible data over a classical communication channel cannot exceed its capacity, even if the sender and the receiver have access to a source of nonlocal correlations. This principle can be used to bound the nonlocality of quantum mechanics without resorting to its full formalism, with a notable example of reproducing the Tsirelson's bound of the Clauser-Horne-Shimony-Holt inequality. Despite being promising, the latter result found little generalization to other Bell inequalities because of the limitations imposed by the process of concatenation, in which several nonsignaling resources are put together to produce tighter bounds. In this work, we show that concatenation can be successfully replaced by limits on the communication channel capacity. It allows us to rederive and, in some cases, significantly improve all the previously known results in a simpler manner and apply the information causality principle to previously unapproachable Bell scenarios.We present a study of the IR behavior of a three-dimensional superrenormalizable quantum field theory consisting of a scalar field in the adjoint of SU(N) with a φ^4 interaction. A bare mass is required for the theory to be massless at the quantum level. In perturbation theory, the critical mass is ambiguous due to IR divergences, and we indeed find that at two loops in lattice perturbation theory the critical mass diverges logarithmically. It was conjectured long ago in [R. Jackiw et al., Phys. Rev. D 23, 2291 (1981)PRVDAQ0556-282110.1103/PhysRevD.23.2291, T. Appelquist et al., Phys. Rev. D 23, 2305 (1981)PRVDAQ0556-282110.1103/PhysRevD.23.2305] that superrenormalizable theories are nonperturbatively IR finite, with the coupling constant playing the role of an IR regulator. Using a combination of Markov Chain Monte Carlo simulations of the lattice-regularized theory, frequentist and Bayesian data analysis, and considerations of a corresponding effective theory, we gather evidence that this is indeed the case.
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