Notes

Combination regarding functionalized luminescent gold nanoclusters pertaining to acid solution phosphatase detecting.
The uptake of the fission product technetium (Tc) by chukanovite, an FeII hydroxy carbonate mineral formed as a carbon steel corrosion product in anoxic and carbonate-rich environments, was studied under anoxic, alkaline to hyperalkaline conditions representative for nuclear waste repositories in deep geological formations with cement-based inner linings. The retention potential of chukanovite towards TcVII is high in the pH range 7.8 to 12.6, evidenced by high solid-water distribution coefficients, log Rd ~ 6, and independent of ionic strength (0.1 or 1 M NaCl). Using Tc K-edge X-ray absorption spectroscopy (XAS) two series of samples were investigated, Tc chukanovite sorption samples and coprecipitates, prepared with varying Tc loadings, pH values and contact times. From the resulting 37 XAS spectra, spectral endmembers and their dependence on chemical parameters were derived by self-organizing (Kohonen) maps (SOM), a neural network-based approach of machine learning. see more X-ray absorption near-edge structure (Xironmental transport.Urban agriculture, while being a promising solution to increase food sovereignty in cities, can lead to an unprecedented discharge of nutrient and fertilizer-related emissions into the urban environment. Especially relevant are nitrogen (N) and phosphorus (P), due to their contribution to marine and freshwater eutrophication. Therefore, alternative methods of fertilization need to be put into practice to avoid such impacts to the surrounding environment. Struvite, has been studied as a potential slow releasing fertilizer due to its high P content, while the bacteria rhizobium has been used to fix N directly from the atmosphere. Legumes, like the common bean are N-demanding crops capable of symbiosis with the bacteria rhizobium and have previously shown positive responses to fertilization with struvite. This study aims to analyze the environmental performance of plant production in hydroponic systems combining rhizobium inoculation and struvite (2 g, 5 g, 10 g, 20 g) irrigated with a N and P deficient nutrient solution, using life cycle analysis (LCA). The nutrient content of in- and out-going irrigation was analyzed as well as in plants and beans. The functional unit for the LCA was 1 kg of fresh beans. The results obtained indicate a yield reduction of 60% to 50% in comparison to the control which was irrigated with a full nutrient solution. The impacts from operational stage are less in all impact categories, where most significant reductions up to 69% and 59% are seen in marine-eutrophication and global warming respectively. Although the infrastructure does not change between treatments, its impacts increase due to the lower yields. We determine that below a 10% of the control yield, the alternative systems have more impact than the use of conventional mineral fertilizers in almost all impact categories, thus pointing to the importance of infrastructure to truly reduce environmental impacts for urban agriculture.The interaction of microplastics (MPs) and common environmental organic pollutants has been a frequently discussed topic in recent years. Although the estimated contamination caused by MPs in terrestrial ecosystems is one order of magnitude higher than that in the oceans, experiments have been conducted solely in an aqueous matrix. Therefore, an experiment was carried out with two soils differing in their concentrations of polycyclic aromatic hydrocarbons (PAHs) and polyurethane foams used for scent fences along roads and crop fields. Two types of polyurethane foam (biodegradable and conventional in aged and unaged form) were exposed to soils containing PAHs that originated from historically contaminated localities. The exposure lasted 28 days, and a newly developed three-step procedure to separate MPs from soil was then applied. Biodegradable polyurethane MPs exhibited a strong tendency to accumulate PAHs after 7 days, and their concentrations significantly grew over time. In contrast, the sorption of PAHs on conventional polyurethane MPs was substantially lower (a maximum of 3.6 times higher concentration than that in the soil). Neither type of foam changed their sorption behaviors after the aging procedure. The results indicate that the flexibility of the polyurethane polymeric network could be the main driving factor for the sorption.Triple-layered thin film composite (TFC) forward osmosis (FO) membranes prepared on interlayer-based supports have overcome the limitations of conventional porous substrates due to the formation of ultrathin and highly selective polyamide (PA) layers. However, mitigating the internal concentration polarization (ICP) and biofouling of TFC membranes remain a great challenge. Herein, we designed a novel triple-layered thin film nanocomposite (TFN) FO membrane with incorporation of silver (Ag) decorated graphene oxide quantum dots (GOQD) into PA layer via interfacial polymerization on a carbon nanotube (CNT) interlayer-based polyether sulfone substrate. By contrast with the TFC membranes, the newly developed GOQD/Ag incorporated triple-layered TFN membrane (TFN-GOQD/Ag) exhibited a great alleviation for ICP accompanied with a prominently enhanced water flux of 65.8 L·m-2·h-1 and decreased specific reverse salt flux of 1.4 g·m-2·h-1 by employing 1 M NaCl solution as draw solution. Moreover, the TFN-GOQD/Ag membrane possessed prominent antibacterial activity against both E. coli (99.8%) and S. aureus (97.3%). Noteworthy, the obtained TFN membrane demonstrated a controlled release of Ag+ along with long-term antibacterial potential and outstanding fouling resistance during the FO process. This work provides a new avenue to fabricate newly FO membranes with superior performance for water cleaning treatment.Application of animal manure to soils results in the introduction of manure-derived bacteria and their antimicrobial resistance genes (ARGs) into soils. ResCap is a novel targeted-metagenomic approach that allows the detection of minority components of the resistome gene pool without the cost-prohibitive coverage depths and can provide a valuable tool to study the spread of antimicrobial resistance (AMR) in the environment. We used high-throughput sequencing and qPCR for 16S rRNA gene fragments as well as ResCap to explore the dynamics of bacteria, and ARGs introduced to soils and adjacent water ditches, both at community and individual scale, over a period of three weeks. The soil bacteriome and resistome showed strong resilience to the input of manure, as manuring did not impact the overall structure of the bacteriome, and its effects on the resistome were transient. Initially, manure application resulted in a substantial increase of ARGs in soils and adjacent waters, while not affecting the overall bacterial community composition.
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