Notes

Fat Hydroperoxide Compromises the particular Membrane Composition Business and Softens Folding Hardness.
7 mg/g, and the kinetic study suggested the adsorption process conformed to a pseudo-second-order kinetic model. The isotherm results also showed that the modified lignin-based adsorbent exhibited monolayer adsorption. The adsorbent properties were mainly attributed to the incorporated amine functionalities as well as the increased specific surface area of the aminated CELF lignin. Copyright © 2020 American Chemical Society.The transition of amyloidogenic species into ordered structures (i.e., prefibrillar oligomers, protofibrils, mature fibrils, and amyloidogenic aggregates) is closely associated with many neurodegenerative disease pathologies. It is increasingly appreciated that the liquid-solid interface contributes to peptide aggregation under physiological conditions. However, much remains to be explored on the molecular mechanism of surface-directed amyloid formation. We herein demonstrate that physical environmental conditions (i.e., negatively charged surface) affect amyloid formation. Nontoxic amyloid aggregates quickly develop into intertwisting fibrils on a negatively charged mica surface. These fibrillar structures show significant cytotoxicity on both neuroblastoma cell-lines (SH-SY5Y) and primary neural stem cells. Our results suggest an alternative amyloid development pathway, following which Aβ peptides form large amyloidogenic aggregates upon stimulation, and later transit into neurotoxic fibrillar structures while being trapped and aligned by a negatively charged surface. Conceivably, the interplay between chemical and physical environmental conditions plays important roles in the development of neurodegenerative diseases. Copyright © 2020 American Chemical Society.Herein, a simplistic redox polymerization strategy was utilized for the fabrication of a poly(methacrylic acid)/montmorillonite hydrogel nanocomposite (PMA/nMMT) and probed as a sorbent for sequestration of two pharmaceutical contaminants, viz., amoxicillin (AMX) and diclofenac (DF), from wastewater. The synthesized hydrogel nanocomposite was characterized by the Fourier transform infrared, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy-energy dispersive X-ray spectroscopy, and transmission electron microscopy techniques to analyze structural characteristics and sorption interactions. The efficacy of PMA/nMMT was thoroughly investigated for the sequestration of AMX and DF from the aquatic phase with a variation in operative variables like agitation time, sorbent dosage, pH, and initial sorbate concentration. The reaction kinetics was essentially consistent with the pseudo-second-order model with rate dominated by the intraparticle diffusion model as well as the film diffusion mechanism. The Freundlich isotherm appropriated the equilibrium data over the entire range of concentration. Thermodynamic investigation explored the spontaneous and endothermic nature of the process. The most possible mechanism has been explained, which includes electrostatic interaction, hydrogen bonding, cationic exchange, and partition mechanism. Economic feasibility, better sorption capacity (152.65 for AMX and 152.86 mg/g for DF), and efficient regeneration and reusability even after four consecutive sorption-desorption cycles ascertained PMA/nMMT as a potential sorbent for AMX and DF uptake from the aqueous phase. Copyright © 2020 American Chemical Society.Catalytic degradation of organic water pollutants has emerged as a cost- and energy-effective technique to treat wastewater. In this work, new silver and magnetite nanoparticles (NPs) were prepared with a protic poly(ionic liquid) (PIL) based on a quaternized diethylethanolamine cation combined with 2-acrylamido-2-methylpropane sulfonate-co-vinylpyrrolidone (QAMPSA/VP) as a capping and a reducing agent. The morphology, particle size, surface charge, thermal stability, and magnetic properties of QAMPS/VP-Ag and Fe3O4 NPs were investigated to determine the efficiency of the PIL as a reducing and a capping agent to protect the produced NPs from oxidation or thermal degradation. The activation energy, enthalpy, and entropy of the catalytic degradation of the cationic methylene blue (MB) dye in the presence of QAMPS/VP-Ag and Fe3O4 NPs were determined. The data elucidated that MB was completely degraded in 8 min in the presence of QAMPS/VP-Fe3O4 NPs as a Fenton oxidation catalyst. Moreover, their good magnetic properties allowed their easy separation and reuse for five cycles without losing their magnetic or catalytic properties. Copyright © 2020 American Chemical Society.An empty fruit bunch (EFB) is a byproduct of the palm oil production process with an undried moisture content of 60-70%, which is too high for use as direct combustion fuel. OSI-930 price Drying processes are generally considered essential for the recent use of EFBs as power plant fuels because their high moisture content decreases the boiler efficiency. The lower moisture content of dried EFBs increases the heating value and boiler efficiency but creates a trade-off with the energy required for the drying process. This study developed an EFB-based 10 MW power plant model by integrating economic evaluations in order to obtain optimal drying conditions. A hot air dryer was used in the drying process. The EFB evaporation behavior was predicted by reflecting the drying kinetics of EFBs in Aspen Plus. The optimum drying conditions were found to be a steam recirculation ratio of 0.25 and drying time of 23 min, creating dried EFBs with a 9.91% moisture content, which reduced costs by 5.48% relative to the undried base scenario. In addition, the developed model was compared to the drying process of a real power plant currently under construction in Indonesia. This drying process reduces the EFB moisture content from 48 to 20%. Copyright © 2020 American Chemical Society.With the aim to develop chemical adsorbents that are inherently nontoxic to living beings and the environment, a gel system based on thiol-norbornene photoclick chemistry was developed. Norbornene was strategically functionalized with different poly(ethylene glycol) (PEG) chains to produce PEG-functionalized macromonomers. The influence of incorporating PEG in the cross-linked network was evaluated on the basis of its physical properties and dye-removing efficiency from aqueous solutions. The excellent swelling ability of the gels in organic solvents was found to improve with the PEG chain length. The rheological measurements of the as-synthesized materials also exhibited the presence of elasticity in the network, and a decrease in storage and loss moduli was observed with an increase in PEG molecular weight. The materials possess excellent thermal stability, which enhanced with an increase in PEG chain length, as revealed from thermogravimetric analysis (TGA). Differential scanning calorimetry (DSC) studies revealed the tendency of higher-molecular-weight PEG to form a crystalline phase in the network.
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