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We apply a recently developed thermal form factor expansion method to evaluate the real-time longitudinal spin-spin correlation functions of the spin-1/2 XXZ chain in the antiferromagnetically ordered regime at zero temperature. An analytical result incorporating all types of excitations in the model is obtained, without any approximations. buy Gefitinib This allows for the accurate calculation of the real-time correlations in this strongly interacting quantum system for arbitrary distances and times.We characterize a high-density sample of negatively charged silicon-vacancy (SiV^-) centers in diamond using collinear optical multidimensional coherent spectroscopy. By comparing the results of complementary signal detection schemes, we identify a hidden population of SiV^- centers that is not typically observed in photoluminescence and which exhibits significant spectral inhomogeneity and extended electronic T_2 times. The phenomenon is likely caused by strain, indicating a potential mechanism for controlling electric coherence in color-center-based quantum devices.Heavy fermion compounds exhibiting a ferromagnetic quantum critical point have attracted considerable interest. Common to two known cases, i.e., CeRh_6Ge_4 and YbNi_4P_2, is that the 4f moments reside along chains with a large interchain distance, exhibiting strong magnetic anisotropy that was proposed to be vital for the ferromagnetic quantum criticality. Here, we report an angle-resolved photoemission study on CeRh_6Ge_4 in which we observe sharp momentum-dependent 4f bands and clear bending of the conduction bands near the Fermi level, indicating considerable hybridization between conduction and 4f electrons. The extracted hybridization strength is anisotropic in momentum space and is obviously stronger along the Ce chain direction.The hybridized 4f bands persist up to high temperatures, and the evolution of their intensity shows clear band dependence. Our results provide spectroscopic evidence for anisotropic hybridization between conduction and 4f electrons in CeRh_6Ge_4, which could be important for understanding the electronic origin of the ferromagnetic quantum criticality.We employ electric circuit networks to study topological states of matter in non-Hermitian systems enriched by parity-time symmetry PT and chiral symmetry anti-PT (APT). The topological structure manifests itself in the complex admittance bands which yields excellent measurability and signal to noise ratio. We analyze the impact of PT-symmetric gain and loss on localized edge and defect states in a non-Hermitian Su-Schrieffer-Heeger (SSH) circuit. We realize all three symmetry phases of the system, including the APT-symmetric regime that occurs at large gain and loss. We measure the admittance spectrum and eigenstates for arbitrary boundary conditions, which allows us to resolve not only topological edge states, but also a novel PT-symmetric Z_2 invariant of the bulk. We discover the distinct properties of topological edge states and defect states in the phase diagram. In the regime that is not PT symmetric, the topological defect state disappears and only reemerges when APT symmetry is reached, while the topological edge states always prevail and only experience a shift in eigenvalue. Our findings unveil a future route for topological defect engineering and tuning in non-Hermitian systems of arbitrary dimension.A semi-device-independent framework for prepare-and-measure experiments is introduced in which an experimenter can tune the degree of distrust in the performance of the quantum devices. In this framework, a receiver operates an uncharacterized measurement device and a sender operates a preparation device that emits states with a bounded fidelity with respect to a set of target states. No assumption on Hilbert space dimension is required. The set of quantum correlations is investigated and bounded from both the interior and the exterior. Furthermore, the optimal performance of quantum state discrimination with bounded distrust is derived and applied to certification of detection efficiency. Quantum-over-classical advantages are demonstrated and the magnitude of distrust compatible with such advantages is explored. Finally, efficient schemes for semi-device-independent random number generation are developed.We expose the polar covalent bond between a single Au atom terminating the apex of an atomic force microscope tip and a C atom of graphene on SiC(0001) to an external electric field. For one field orientation, the Au─C bond is strong enough to sustain the mechanical load of partially detached graphene, while for the opposite orientation, the bond breaks easily. Calculations based on density-functional theory and nonequilibrium Green's function methods support the experimental observations by unveiling bond forces that reflect the polar character of the bond. Field-induced charge transfer between the atomic orbitals modifies the polarity of the different electronegative reaction partners and the Au─C bond strength.Quantum Monte Carlo simulations of quantum many-body systems are plagued by the Fermion sign problem. The computational complexity of simulating Fermions scales exponentially in the projection time β and system size. The sign problem is basis dependent and an improved basis, for fixed errors, leads to exponentially quicker simulations. We show how to use sign-free quantum Monte Carlo simulations to optimize over the choice of basis on large two-dimensional systems. We numerically illustrate these techniques decreasing the "badness" of the sign problem by optimizing over single-particle basis rotations on one- and two-dimensional Hubbard systems. We find a generic rotation which improves the average sign of the Hubbard model for a wide range of U and densities for L×4 systems. In one example improvement, the average sign (and hence simulation cost at fixed accuracy) for the 16×4 Hubbard model at U/t=4 and n=0.75 increases by exp[8.64(6)β]. For typical projection times of β⪆100, this accelerates such simulation by many orders of magnitude.Photon coincidences represent an important resource for quantum technologies. They expose nonlinear quantum processes in matter and are essential for sources of entanglement. We derive broadly applicable criteria for quantum non-Gaussian two-photon coincidences that certify a new quality of photon sources. The criteria reject states emerging from Gaussian parametric processes, which often limit applications in quantum technologies. We also analyze the robustness of the quantum non-Gaussian coincidences and compare it to the heralded quantum non-Gaussianity of single photons based on them.
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