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Pathological evaluation of chronic kidney ailment using Drunk driving: Is there an added price regarding diffusion kurtosis imaging?
Urban rivers were heavily polluted, which resulted in blackening and odorization (i.e., black-odor rivers). Nevertheless, very limited information is available on sediment contamination levels of black-odor rivers and their linkage to the patterns of microbial functional genes. This study investigated distribution of polycyclic aromatic hydrocarbons (PAHs) and phthalates (PAEs) and their linkages to bacterial community and related functional genes in river sediments. The results demonstrate that higher average levels of ∑16PAHs (1405 μg/kg, dry weight) and ∑6PAEs (7120 μg/kg) were observed in sediments from heavy black-odor rivers than the moderate ones (∑16PAHs 462 μg/kg; ∑6PAEs 2470 μg/kg). The taxon composition and diversities of bacterial community in sediments varied with significantly lower diversity indices in heavy black-odor rivers than moderate ones. Sediments from heavy black-odor rivers enriched certain PAH and PAE degrading bacteria and genes. Unfortunately, PAH and PAE contamination demonstrated negative influences on nitrogen and phosphorus metabolism related bacteria and function genes but significant positive influences on certain sulfur metabolism related bacterial taxa and sulfur reduction gene, which might cause nitrogen and phosphorus accumulation and black-odor phenomenon in heavy black-odor rivers. This study highlights PAH and PAE contamination in urban rivers may shift bacterial community and detrimentally affect their ecological functions.Purification of insoluble emulsified oils and soluble organic pollutants from sewage has attracted tremendous attention in today's society. Herein, a stable and environmentally friendly nanofibrous membrane with hierarchical caterpillar-like structure was fabricated via in-situ hydrothermal growing the nickel-cobalt layered double hydroxides (NiCo-LDHs) on tche polyacrylonitrile (PAN) electrospun nanofibers. The wrapped hydrophilic NiCo-LDHs constructed the hierarchical structure and endowed the membrane attractive superhydrophilicity (≈ 0°)/underwater superoleophobicity (≈ 161°) and enhanced oil-repellency performance. Meanwhile, the NiCo-LDH@PANI/oPAN NFMs can display the ultra-fast flux of SSEs (xylene/water emulsion, 4175 L m-2 h-1) and satisfactory separation efficiency (99.07%). Moreover, the introduction of positively charged NiCo-LDHs increased plentiful adsorption active sites for membranes, which is beneficial to demulsify ionic SSEs and adsorb organic pollutants. Finally, for simultaneous purification of complex sewage by the dead-end and cross-flow filtration experiment, the composite membrane both displayed splendid removal rate of oil (> 99.0%) and dyes (> 99.0%), robust regeneration recycle-ability and no secondary pollution. Hence, it is expected that such strategy of combining electrospun and chelating-assisted in-situ hydrothermal can provide a low energy consumption and high decontamination technology for severe environmental crisis.Irrigation with treated wastewater could lead to the accumulation of caffeine in agricultural fresh. Caffeine is one of the most frequently detected compounds in treated wastewater; however, little is known about its subcellular distribution and metabolism in vegetables. This study reported the uptake, subcellular distribution, and metabolism of 14C-caffeine in Chinese flowering cabbage and water spinach. The results showed that 98% of caffeine lost from solution after 768 h of cultivation. Caffeine was taken up by vegetables and most 14C-activity was accumulated in the bottom leaves. At the subcellular level, 14C-activity was mainly distributed in the organelles in root and stem cells, while in the leafy cells it was dominant in the solution. The metabolism of caffeine was investigated using LC-QTOF-MS. Caffeine underwent demethylation forming xanthine and theobromine, and mineralization to release CO2. Approximately 40.2% of the initially applied caffeine was accumulated in Chinese flowering cabbage as the parent compound (28.3%) and metabolites (11.9%), and 50.9% of the added caffeine was mineralized to CO2 after 768 h of exposure. The knowledge obtained herein is key to evaluating potential risks of caffeine present in treated wastewater, and the quality and safety of agricultural fresh produced by irrigation with treated wastewater.The current study represents the first attempt to analyse quantitatively, within a phylogenetic framework, uptake and partitioning patterns of copper (Cu), zinc (Zn), cadmium (Cd) and lead (Pb) in extant saltmarsh taxa globally, and to assess associations of these patterns with various plant traits indicative of their halophytic adaptations. Despite saltmarsh being diverse taxonomically, most saltmarsh taxa accumulate metals to roots at, or above, unity (> 1). Further, there is significant translocation from roots to shoot for Cu, Zn and Cd (≤ 1), however, Pb is less mobile (TF = 0.65). Patterns of accumulation were similar among families, except greater Cd accumulation to roots in members of Juncaceae. Patterns of uptake to roots and translocation to leaves were broadly similar among plant type, plant form, habitat and photosynthetic mode. Zinc is lower in the leaves of salt-secreting species for some closely related taxa, suggesting some species co-excrete sodium (Na+) and Zn2+ through glands in leaf tissue. Crenolanib Salinity tolerance has no relationship to metal uptake and translocation. Translocation of Zn is greater at lower Zn sediment exposures, reflecting its active uptake and essentiality, but such bias does not affect outcomes of analyses when included as a covariate.A new resourcezation way has been proposed to address the treatment challenges of the light phenolic distillation residue (LPDR) from the coal-based phenolic distillation residue. Herein, the LPDR, which was collected at 20 kPa and 220 °C from the phenolic distillation residue, has been further used to synthesize the phenolic resin (named as RPF) for MgO-C refractories. It is found that the conversion efficiency of crude phenol mixture to RPF is 71.3%, which is lower than that of pure phenol. To increase the conversion efficiency and improve the properties of RPF, the crude phenolic mixture was blended with pure phenol for the synthesis. The optimal addition mass ratio of phenol in the crude phenol mixture (phenol/total phenolic compounds) is determined to be 0.8, where the obtained RPF could satisfy or even better than the national standard. Further addition of 10 wt% of urotropine (HMTA) as curing agent and 9 wt% of ferrocene (Fc) as modifier (named as MRPF) are found to significantly improve the graphitization of RPF.
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