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Guaranteeing Biomarkers regarding Radiation-Induced Bronchi Injuries: A Review.
Due to the excellent hydrogen affinity and high conductivity, palladium nanoparticles (Pd NPs) were considered as a potential strategy to regulate bacterial electron transfer and energy metabolism. Herein, Citrobacter freundii JH, capable of in-situ biosynthesizing Pd(0) NPs, was employed to promote Pt(IV) reduction. The results showed that the Pt(IV) reduction to Pt(II) was accomplished mainly via the flavins-mediated extracellular electron transfer (EET) process, while Pt(II) reduction to Pt(0) was limit step, and proceeded via two intracellular respiratory chains, including FDH/Hases-based short chain (S-chain) and typical CoQ-involved long respiratory chain (L-chain). Noteworthily, the incorporation of Pd(0) NPs mainly diverted the electrons to S-chain (as high as 71.7%-73.4%) by improving the hydrogenases (Hases) activity. Furthermore, Pd(0) NPs could stimulate the secreting of flavins and the combination between flavins and cytochrome c (c-Cyt), which converted electron transfer manner of L-chain. Additionally, Pd(0) NPs might also act as alternative proton channels to improve the energy metabolism. These findings provided significant insights into the promotion by Pd(0) NPs in terms of electron generation, electron consumption and proton translocation.Sulfur hexafluoride (SF6) is the most potent greenhouse gas contributed by the power and semiconductor industries. The global emissions of gas in the past 10 years have increased tremendously due to lack of disposal routes. This was brought to 190 nations' attention in the Kyoto Protocol for the need of emission control measures to reduce its impacts of climate change and global warming. Various novel techniques have surfaced to tackle this issue, such as non-thermal plasma (NTP) which includes radio frequency plasma, microwave plasma, dielectric barrier discharge, and electron beam. The main by-products resulting from the decomposition of SF6 by these techniques are sulfur oxyfluorides, sulfur dioxide, hydrofluoric acid, and fluorine gas. This environmental and health effects as well as global emission of SF6 gas are considered a threat to humans and the climate, where modern disposal methods of contaminated SF6 gas and its by-products should replace the conventional approaches. Relevant government policies on the safety and disposal concern of SF6 gas are reviewed and challenges and further research directions for the disposal of SF6 gas are highlighted in this review article.1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH), as an emerging brominated flame retardant (EBFR) pollutant, has been often observed in the air, and to comprehend its fate in the environment is still challenging due to the diversity of its stereoisomers. In this work, the environmental transformation behavior and potential toxicological implications of TBECH stereoisomers under the oxidation of OH· in the gas phase were investigated by computational chemistry. Our results indicate the complexity of the TBECH transformation reactions and the diversity of its transformation products in the atmosphere. Although the reactions of TBECH enantiomers with OH· exhibit highly consistency, it is obvious that the reactions of the four diastereoisomers of TBECH with OH· and their subsequent reactions have both specificity and similarity. The dehydrogenation intermediates produced by H-abstraction of OH· in the initial reactions may undergo oxidative debromination, hydroxylation and decomposition reactions, leading to the transformation into low bromine and monohydroxy substituted compounds, as well as debrominated or unbrominated unsaturated fatty ketones. The toxicity assessments show that all transformation products are less toxic to aquatic organisms than TBECH, but some of them are still classified at toxic or harmful levels. More importantly, some transformation products still exhibit carcinogenic and teratogenic activity. To our knowledge, this study provides, for the first time, a deep insight into the transformation mechanism, kinetics, and environmental impacts of atmospheric TBECH by theoretical calculations.The extensive use of graphene oxide (GO) results in its inevitable entry into the environment, raising risks to the environment, especially the ecological risks when coexisting with other contaminants. Nevertheless, how GO affects the biological behavior of Cd in plants remains poorly understood. Here, we report that the transcript levels of Cd transporters, including OsIRT1, OsIRT2, OsNramp1, OsNramp5, and OsHMA2, were decreased by 56-96% in Cd-stressed rice seedlings with exposure to 400 mg L-1 GO compared with those without GO exposure. The in situ non-invasive microelectrodes test revealed that GO clearly reduced the net Cd influx of rice roots. Thus, GO exposure decreased the level of Cd in rice seedlings by approximately 60%, compared with the GO-free condition. However, the analyses of biomass, chlorophyll fluorescence parameters and Evans blue staining, indicated that GO had adverse effects on the robustness of plants under the Cd co-contaminated condition. Taken together, although GO reduced the accumulation of Cd in rice seedlings, it still negatively affected plant growth. Therefore, the positive and negative impacts of GO on crop production are of concern. Our findings provide new information for establishing a wider phytotoxicity evaluation system for the safe manufacture and use of GO.Genetic improvement could play a significant role in enhancing the Cd accumulation, translocation and tolerance in plants. In this study, for the first time, we constructed transgenic tall fescue overexpressing a class II (CII) sHSP gene FaHSP17.8-CII, which enhanced Cd tolerance and the root-to-shoot Cd translocation. After exposed to 400 μM CdCl2, two FaHSP17.8-CII overexpressing lines (OE#3 and OE#7) exhibited 30% and 40% more shoot fresh weight, respectively, relative to the wild-type (WT). selleck products Both transgenic lines showed higher tolerance to Cd, as evidenced by lower levels of electrolyte leakage and malondialdehyde compared to the WT plants under Cd stress. FaHSP17.8-CII overexpression increased shoot Cd contents 49-59% over the WT plants. The Cd translocation factor of root-to-shoot in OE grasses was 69-85% greater than WT under Cd stress. Furthermore, overexpression of FaHSP17.8-CII reduced Cd-induced damages of chloroplast ultra-structure and chlorophyll synthesis, and then improved photosystem II (PSII) function under Cd stress, which resulted in less reactive oxygen species (ROS) accumulation in OE grasses than that in WT exposed to Cd stress.
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