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In this study, typical animal- and plant-derived biochars derived from pig carcass (PB) and green waste (GWB), and their iron-engineered products (Fe-PB and Fe-GWB) were added at the dose of 3% (w/w) to an acidic (pH = 5.8) soil, and incubated to test their efficacy in improving soil quality and immobilizing arsenic (As = 141.3 mg kg-1) and lead (Pb = 736.2 mg kg-1). Soil properties, microbial activities, and the geochemical fractions and potential availabilities of As and Pb were determined in the non-treated (control) and biochar-treated soil. Modification of PB (pH = 10.6) and GWB (pH = 9.3) with Fe caused a decrease in their pH to 4.4 and 3.4, respectively. The application of PB and GWB significantly increased soil pH, while Fe-PB and Fe-GWB decreased soil pH, as compared to the control. Application of Fe-GWB and Fe-PB decreased the NH4H2PO4-extractable As by 32.8 and 35.9%, which was more effective than addition of GWB and PB. However, PB and GWB were more effective than Fe-PB and Fe-GWB in Pb immobilization. Compared to the control, the DTPA-extractable Pb decreased by 20.6 and 21.7%, respectively, following PB and GWB application. Both biochars, particularly PB significantly increased the 16S rRNA bacterial gene copy numbers, indicating that biochar amendments enhanced the bacterial abundance, implying an alleviation of As and Pb bio-toxicity to soil bacteria. The results demonstrated that pristine pig carcass and green waste biochars were more effective in immobilizing Pb, while their Fe-engineered biochars were more effective in As immobilization in co-contaminated soils.Cadmium (Cd), a toxic non-essential metal, is easily accumulated in cacao tissues. This represents a risk for cacao exportation, and consequently it affects the economic well-being of the resource-poor-small-producers in Latin America. A greenhouse experiment was conducted with 53 wild and domesticated cacao genotypes to determine their response to Cd in terms of growth and Cd and essential nutrients accumulation. Cacao seedlings were grown for 6 months in an acidic soil with or without added Cd. The total concentration of macro (Ca, K, Mg, N and P) and micronutrients (B, Cu, Fe, Mn and Zn) as well as Cd were measured in shoots along with growth (biometric) parameters after harvest. The results revealed that even if there was a wide range of Cd concentrations among genotypes, there was a reduction in the concentration of essential nutrients in genotypes grown in Cd spiked soils, however these concentrations were not significantly different from the control. In the case of growth parameters, the effects of Cd were diverse across all genotypes some of them being more tolerant to Cd stress than others. Thus, different growth responses to Cd stress are related to a genotype effect. Based on their lower Cd concentration, a total of 11 cacao genotypes (AYP-22, PAS-105, UGU-126, ICT-1026, ICT-1087, ICT-1189, ICT-1292, PH-17, CCN-51, ICS-39 and TSH-565) are proposed here as low Cd-accumulating genotypes. Therefore, these genotypes are potentially useful as rootstock to reduce uptake and transport of Cd, especially in economically important cacao cultivars.The massive development of the Chinese economy is being hindered by the deteriorating air pollution problem. Many methods have been used by the Chinese government to solve this environmental dilemma, out of which environmental decentralization is one of the important measures. The transparency of environmental decentralization may be weakened by the existence of the corruption problem, resulting in further deterioration of the air pollution problem. To examine this problem, the provincial panel data of 30 provinces in China from 2005 to 2016 is selected and the spatial measurement method is used to study the relationship between environmental decentralization, government corruption, and air pollution. The results indicate that air pollution in different provinces of China is spatially dependent. Local environmental decentralization has a significant inhibitory effect on air pollution, while local air pollution is not inhibited by neighbor's environmental decentralization. However, air quality is significantly deteriorated by local or neighbor's corruption problem. After adding the interaction item of environmental decentralization and government corruption as the adjusting variable, it is found that the inhibitory effect of local environmental decentralization on air pollution is weakened by the problem of local government corruption, while the government corruption of neighbor does not have this effect. In addition, both local and neighbor's environmental decentralization have heterogeneous effects on air pollution from the spatial dynamic threshold regression results with regional corruption as the threshold variable.Cities in arid and semi-arid regions have been exploring urban sustainability policies, such as lowering the vegetation coverage to reduce residential outdoor water use. Meanwhile, urban residents express concerns that such policies could potentially impact home prices regardless of the reduced water costs because studies have shown that there is a positive correlation between vegetation coverage and home values. click here On the other hand, lower vegetation coverage in arid and semi-arid desert regions could increase surface temperatures, and consequently increases energy costs. The question is therefore where the point in which residential outdoor water use can be minimized without overly increasing surface temperatures and negatively impacting home values. This study examines the impacts of spatial composition of different vegetation types on land surface temperature (LST), outdoor water use (OWU), and property sales value (PSV) in 302 local residential communities in the Phoenix metropolitan area, Arizona using remotely sensed data and regression analysis. In addition, the spatial composition of vegetation cover was optimized to achieve a relatively lower LST and OWU and maintain a relatively higher PSV at the same time. We found that drought-tolerant landscaping that is composed of mostly shrubs and trees adapted to the desert environment is the most water efficient way to reduce LST, but grass contributes to a higher PSV. Research findings suggest that different residential landscaping strategies may be better suited for different neighborhoods and goal sets can be used by urban planners and city managers to better design urban residential landscaping for more efficient water conservation and urban heat mitigation for desert cities.
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