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The effect of economic along with politics changes in environmental functionality within establishing countries.
New ceramic materials based on two copper borates, CuB2O4 and Cu3B2O6, were prepared via solid state synthesis and sintering, and characterized as promising candidates for low dielectric permittivity substrates for very high frequency circuits. The sintering behavior, composition, microstructure, and dielectric properties of the ceramics were investigated using a heating microscope, X-ray diffractometry, scanning electron microscopy, energy dispersive spectroscopy, and terahertz time domain spectroscopy. The studies revealed a low dielectric permittivity of 5.1-6.7 and low dielectric loss in the frequency range 0.14-0.7 THz. The copper borate-based materials, owing to a low sintering temperature of 900-960 °C, are suitable for LTCC (low temperature cofired ceramics) applications.When designing embankments on a soft ground improved with columns (rigid inclusions) and with a geosynthetically reinforced load transfer platform (LTP), the methods of determining strains in reinforcement reduce the spatial problem to a two-dimensional one, and analytical calculations are carried out for reinforcement strips in the directions along and across the embankment. In addition, the two-dimensional FEM models do not allow for a complete analysis of the behavior of the reinforcement material. The aim of this research was to analyze the work of the membrane in the 3D space modeling of the LTP reinforcement, depending on the interaction with the column, the shape of the column's cap, the value of the Poisson's ratio, the value of the stiffness of the elastic foundation (subgrade reaction k) modeling of the soft soil resistance between the columns and the load distribution over membranes that model the reinforcement. The membranes were modeled in the framework of the theory of large deformations using the finite element method and slender shell elements as three-dimensional objects. This modeling method allowed for the analysis of the behavior of the LTP reinforcement in various directions. The conducted analyses showed, among others, that in the absence of soil resistance between the columns, regardless of the shape of the cap (square, circle), the greatest strains are located near the edge of the cap in the diagonal direction between the columns.It is well-known that the effect of interstitial fluid on the fracture pattern and strength of saturated high-strength concrete is determined by qualitatively different mechanisms at quasi-static and high strain rate loading. This paper shows that the intermediate range of strain rates (10-4 s-1 less then ε˙ less then 100 s-1) is also characterized by the presence of a peculiar mechanism of interstitial water effect on the concrete fracture and compressive strength. Using computer simulations, we have shown that such a mechanism is the competition of two oppositely directed processes deformation of the pore space, which leads to an increase in pore pressure; and pore fluid flow. The balance of these processes can be effectively characterized by the Darcy number, which generalizes the notion of strain rate to fluid-saturated material. We have found that the dependence of the compressive strength of high-strength concrete on the Darcy number is a decreasing sigmoid function. The parameters of this function are determined by both low-scale (capillary) and large-scale (microscopic) pore subsystems in a concrete matrix. The capillary pore network determines the phenomenon of strain-rate sensitivity of fluid-saturated concrete and logistic form of the dependence of compressive strength on strain rate. Microporosity controls the actual boundary of the quasi-static loading regime for fluid-saturated samples and determines localized fracture patterns. The results of the study are relevant to the design of special-purpose concretes, as well as the assessment of the limits of safe impacts on concrete structural elements.The present research study aims to investigate numerically the behavior of steel fiber-reinforced high-strength concrete (SFRHC) beam-column joints (BCJs) under seismic action. Based on the plastic damage constitutive model of concrete and elastic-plastic mixed-strengthen constitutive model of steel material, the finite element software ABAQUS was utilized to establish the 3D finite element (FE) model of BCJs. Additionally, the feasibility and accuracy of the numerical simulation were verified by comparing the computed results and experimental observations in terms of the hysteresis curves, skeleton curves, and failure mode. Furthermore, based on the validated FE modeling approach, load vs. displacement hysteresis curves of SFRHC-BCJs during the loading process were analyzed in detail; the failure process was also investigated. Furthermore, the effect of various parameters on the seismic behavior of BCJs was analyzed comprehensively, including the concrete strength, the volume ratio of steel fiber, and the stirrup ratio in the core area. Finally, parametric studies illustrated that increasing the concrete strength helps in enhancing the ultimate load, while the ductility decreased noticeably. Both adding the steel fiber and increasing the stirrup ratio can significantly improve the seismic performance of BCJs.This article reports the design and manufacture of colored microcapsules with specific functions and their application in architectural interior wall coating. Utilizing reactive dyes grafted SiO2 shell to encapsulate paraffin through interfacial polymerization and chemical grafting methods, this experiment successfully synthesized paraffin@SiO2 colored microcapsules. The observations of surface morphology demonstrated that the colored microcapsules had a regular spherical morphology and a well-defined core-shell structure. selleck compound The analysis of XRD and FT-IR confirmed the presence of amorphous SiO2 shell and the grafting reactive dyes, and the paraffin possessed high crystallinity. Compared with pristine paraffin, the thermal conductivity of paraffin@SiO2 colored microcapsules was significantly enhanced. The results of DSC revealed that the paraffin@SiO2 colored microcapsules performed high encapsulation efficiency and desirable latent heat storage capability. Besides, the examinations of UV-vis and TGA showed that the paraffin@SiO2 colored microcapsules exhibited good thermal reliability, thermal stability, and UV protection property.
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