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Massive Cavernomas: Massive Propositions to get a Lilliputian Problem?
The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical reservoirs that subsequently evolve via geological cycles. Current theoretical techniques are limited in exploring the anticipated range of compositional and thermal scenarios of early planetary evolution, even though these are of prime importance to aid astronomical inferences on the environmental context and geological history of extrasolar planets. Here, we present a coupled numerical framework that links an evolutionary, vertically resolved model of the planetary silicate mantle with a radiative-convective model of the atmosphere. Using this method, we investigate the early evolution of idealized Earth-sized rocky planets with end-member, clear-sky atmospheres dominated by either H2, H2O, CO2, CH4, CO, O2, or N2. We find central metrics of early planetary evolution, such as energy gradient, sequence of mantle solidification, surface pressure, or vertical stratification of the atmosphere, to be intimately controlled by the dominant volatile and outgassing history of the planet. Thermal sequences fall into three general classes with increasing cooling timescale CO, N2, and O2 with minimal effect, H2O, CO2, and CH4 with intermediate influence, and H2 with several orders of magnitude increase in solidification time and atmosphere vertical stratification. Our numerical experiments exemplify the capabilities of the presented modeling framework and link the interior and atmospheric evolution of rocky exoplanets with multiwavelength astronomical observations.We describe the capabilities, radiometric stability, and calibration of a custom vacuum environment chamber capable of simulating the near-surface conditions of airless bodies. Here we demonstrate the collection of spectral measurements of a suite of fine particulate asteroid analogs made using the Planetary Analogue Surface Chamber for Asteroid and Lunar Environments (PASCALE) under conditions like those found on Earth and on airless bodies. The sample suite includes anhydrous and hydrated physical mixtures, and chondritic meteorites (CM, CI, CV, CR, and L5) previously characterized under Earth- and asteroid-like conditions. And for the first time, we measure the terrestrial and extra-terrestrial mineral end members used in the olivine- and phyllosilicate-dominated physical mixtures under the same conditions as the mixtures and meteorites allowing us better understand how minerals combine spectrally when mixed intimately. Our measurements highlight the sensitivity of thermal infrared emissivity spectra to small amounts of low albedo materials and the composition of the sample materials. As the albedo of the sample decreases, we observe smaller differences between Earth- and asteroid-like spectra, which results from a reduced thermal gradient in the upper hundreds of microns in the sample. These spectral measurements can be compared to thermal infrared emissivity spectra of asteroid (101955) Bennu's surface in regions where similarly fine particulate materials may be observed to infer surface compositions.In the Late Noachian to Early Hesperian period, rivers transported detritus from igneous source terrains to a downstream lake within Gale crater, creating a stratified stack of fluviolacustrine rocks that is currently exposed along the slopes of Mount Sharp. Controversy exists regarding the paleoclimate that supported overland flow of liquid water at Gale crater, in large part because little is known about how chemical and mineralogical paleoclimate indicators from mafic-rock dominated source-to-sink systems are translated into the rock record. Here, we compile data from basaltic terrains with varying climates on Earth in order to provide a reference frame for the conditions that may have prevailed during the formation of the sedimentary strata in Gale crater, particularly focusing on the Sheepbed and Pahrump Hills members. compound library inhibitor We calculate the chemical index of alteration for weathering profiles and fluvial sediments to better constrain the relationship between climate and chemical weathering in mafic terrains, a method that best estimates the cooler limit of climate conditions averaged over time. We also compare X-ray diffraction patterns and mineral abundances from fluvial sediments in varying terrestrial climates and martian mudstones to better understand the influence of climate on secondary mineral assemblages in basaltic terrains. We show that the geochemistry and mineralogy of most of the fine-grained sedimentary rocks in Gale crater display first-order similarities with sediments generated in climates that resemble those of present-day Iceland, while other parts of the stratigraphy indicate even colder baseline climate conditions. None of the lithologies examined at Gale crater resemble fluvial sediments or weathering profiles from warm (temperate to tropical) terrestrial climates.TanSat is the 1st Chinese carbon dioxide (CO2) measurement satellite, launched in 2016. In this study, the University of Leicester Full Physics (UoL-FP) algorithm is implemented for TanSat nadir mode XCO2 retrievals. We develop a spectrum correction method to reduce the retrieval errors by the online fitting of an 8th order Fourier series. The spectrum-correction model and its a priori parameters are developed by analyzing the solar calibration measurement. This correction provides a significant improvement to the O2 A band retrieval. Accordingly, we extend the previous TanSat single CO2 weak band retrieval to a combined O2 A and CO2 weak band retrieval. A Genetic Algorithm (GA) has been applied to determine the threshold values of post-screening filters. In total, 18.3% of the retrieved data is identified as high quality compared to the original measurements. The same quality control parameters have been used in a footprint independent multiple linear regression bias correction due to the strong correlation with the XCO2 retrieval error. Twenty sites of the Total Column Carbon Observing Network (TCCON) have been selected to validate our new approach for the TanSat XCO2 retrieval. We show that our new approach produces a significant improvement on the XCO2 retrieval accuracy and precision when compared to TCCON with an average bias and RMSE of -0.08 ppm and 1.47 ppm, respectively. The methods used in this study can help to improve the XCO2 retrieval from TanSat and subsequently the Level-2 data production, and hence will be applied in the TanSat operational XCO2 processing.
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