Notes

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n NPP in Anhui province. The NPP changes of different land use types were closely related to climatic factors, land cover area, and vegetation types.In the present study, commercial PES, PVDF, PTFE ultrafilter membranes, and two different nanomaterial (TiO2 and TiO2/CNT composite)-covered PVDF ultrafilter membranes (MWCO = 100 kDa) were used for the purification of an industrial oil-contaminated (produced) wastewater, with and without ozone pretreatment to compare the achievable fouling mitigations by the mentioned surface modifications and/or pre-ozonation. Fluxes, filtration resistances, foulings, and purification efficiencies were compared in detail. Pre-ozonation was able to reduce the total filtration resistance in all cases (up to 50%), independently from the membrane material. During the application of nanomaterial-modified membranes were by far the lowest filtration resistances measured, and in these cases, pre-ozonation resulted in a slight further reduction (11-13%) of the total filtration resistance. The oil removal efficiency was 83-91% in the case of commercial membranes and > 98% in the case of modified membranes. Moreover, the highest fluxes (301-362 L m-2 h-1) were also measured in the case of modified membranes. Overall, the utilization of nanomaterial-modified membranes was more beneficial than pre-ozonation, but with the combination of these methods, slightly higher fluxes, lower filtration resistances, and better antifouling properties were achieved; however, pre-ozonation slightly decreased the oil removal efficiency.The unique geographical location of waterworks and wastewater treatment plant (WWTP) in Graulhet (France) profited the environmental resource integration and "Circular Economy." Alum sludge from a local waterworks was introduced to co-conditioning and dewatering with waste-activated sludge from a nearby WWTP to examine the role of the alum sludge in improving the dewaterability of the mixed sludge. Experiments demonstrated that the optimal mixing ratio was 11 (waste-activated sludge/alum sludge, v/v). Alum sludge has been shown to beneficially enhance mixed sludge dewaterability, by decreasing both the specific resistance to filtration (SRF) and the capillary suction time (CST). Moreover, the optimal polymer (Sueprfloc-492HMW) dose for the mixed sludge (mix ratio 11) was 200 mg/L, highlighting a huge savings (14 times) in polymer addition without alum sludge involvement. In addition, cost-effective analysis of its potential full-scale application has demonstrated that the initial investment could be returned in 11 years. The co-conditioning and dewatering strategy can be viewed as a "win-win" strategy for the Graulhet, France, water and wastewater industry. Graphical abstract.The aim of the current research was to systematically review and summarize the studies that evaluated the concentration of lead (Pb) and cadmium (Cd) in cow milk in different regions of Iran and to perform a meta-analysis of the findings. Moreover, the non-carcinogenic and carcinogenic risks of Pb and Cd through milk consumption in adult and child consumers were assessed. As a result of a systematic search in the international and national databases between January 2008 and October 2018, 17 reports involving 1874 samples were incorporated in our study for meta-analysis. The pooled concentrations of Pb and Cd were estimated to be 13.95 μg mL-1 (95% CI 9.72-18.11 μg mL-1) and 3.55 μg mL-1 (95% CI - 2.38-9.48 μg mL-1), respectively, which were lower than the WHO/FAO and national standard limits. The estimated weekly intake (EWI) of Pb and Cd through consuming milk was 16.65 and 7 μg day-1 for adults of 70 kg and 45 and 34 μg day-1 for children of 26 kg, respectively, which was well below the risk values set by Joint FAO/WHO Expert Committee on Food Additives (JECFA). The maximum target hazard quotient values (THQs) of Pb and Cd were 5.55E-5 and 5.55E-5 for adults and 5.55E-5 and 5.55E-5 for children, respectively, which were lower than 1 value, suggesting that Iranian consumers are not exposed to non-carcinogenic risk through consuming milk. Moreover, the incremental lifetime cancer risk (ILCR) of Pb estimated to be 2.96E-04 in adults and 1.0E-03 in children, indicating that consumers in Iran are at threshold carcinogenic risk of Pb through consuming milk (ILCR > 10-4). Therefore, planning and policy making for the sustainable reduction of these toxic metals in milk, particularly in industrial regions of Iran, are crucial.Road dust was investigated within Philadelphia, a major United States city with a long history of industrial activities, in order to determine pollution levels. Almost all of the investigated minor elements were enriched relative to the continental crust. Furthermore, mean concentrations of Cr, Co, Cu, and Pb were high compared with those reported in cities in other countries. Lead pollution should be investigated further in Philadelphia, where 8 of the 30 sample sites, including those heavily trafficked by civilians, were at or above the EPA's child safety threshold for Pb in bare soil. High Spearman correlations between Zn and Cu, Zn and Cr, Cu and Cr, and Sn and V, as well as factor analysis of minor elements suggests that the primary sources of these elements were anthropogenic. Potential sources included the breakdown of alloys, non-exhaust traffic emissions, paint, smelting, and industry. We found that higher organic content in road dust may be related to higher traffic densities, which could be due to tire-wear particles. Additionally, higher mean concentrations of Fe, Cr, Cu, and Zn were found at sites with elevated traffic densities. Land use impacted some of the elements not influenced by traffic density, including Co, Sn, and Pb. find more Bulk mineral content was similar across different land uses and traffic densities and, thus, did not appear to be influenced by these factors. Our research emphasized the complexity of road dust and utilized a more comprehensive approach than many previous studies. This study established fundamental groundwork for future risk assessment in Philadelphia, as it identified several key pollutants in the city. Overall, this assessment serves as an informative reference point for other formerly heavily industrialized cities in the USA and abroad.
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