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Although the impacts of teleconnection indices on climate metrics such as precipitation and temperature in California have been widely studied, less attention has been given to the impact on integrated climate indices such as chill accumulation. This study investigates the linkages between large-scale teleconnections and winter chill accumulation for specialty crops in California, which may enable more effective and dynamic adaptation to in-season climate variability. Three large-scale teleconnection indices were selected Oceanic Nino Index (ONI), Pacific-North American teleconnection pattern (PNA), and Pacific Decadal Oscillation (PDO) index to assess their effects on chill accumulation. The Chill Hours Model and Dynamic Model are adopted to calculate chill accumulation in Chill Hours (CH) and Chill Portions (CP) from November to January. Three major crop-producing regions, including the Central Coast, Sacramento Valley, and San Joaquin Valley, are used as the focused regions. Our results suggest CP generallrisk control for agricultural producers and policymakers.Previous studies found Fe dissolution in atmosphere correlates to biomass burning, while the underlying mechanisms need to be further investigated. In this study, we reported a laboratory investigation about Fe dissolution behavior of two model Fe-bearing clay minerals of montmorillonite (SWy-2) and illite (IMt-2), and one standard mineral dust of Arizona test dust (AZTD) in atmospheric condition (pH = 2), after the minerals engaging into the brown-carbonization reaction with guaiacol, which is a commonly detected volatile phenol substance in biomass burning. The results show that the pre-brown-carbonization reaction promoted Fe dissolution from all the three minerals, attributing to the reduction of Fe(III) by gaseous guaiacol. The Fe dissolution from SWy-2, IMt-2 and AZTD were also compared under both light and dark conditions to simulate the daytime and nighttime atmospheric processes. As a result, model solar irradiation further promoted Fe dissolution from IMt-2 and AZTD, since both minerals contain moderate photo-reducible Fe(III) oxide or/and Fe(III) oxyhydroxide. The promotive effect of solar irradiation on Fe dissolution from AZTD would be gradually diminished because the photo-reactive Fe(III) is also guaiacol-reducible. Whereas, it was on the contrary for SWy-2 which does not contain the Fe(III) (oxyhydr-)oxide phase. And more dependently, the photo-induced hydroxyl radical (OH) on SWy-2 would re-oxidize the formed Fe(II), unless sufficient amount of guaiacol or brown-carbonization products on SWy-2 consumed the OH and complexed with surface coordinated Fe(III) forming photo-reducible Fe(III). The results of this study suggested the brown carbonization process on minerals would greatly mediate the Fe dissolution behavior from the Fe-bearing mineral dusts in atmosphere. selleck chemical Similar processes might need to be taken into consideration to accurately evaluate the input of Fe from atmosphere to open oceans.Enhanced secondary aerosol formation was observed during the COVID-19 lockdown in Xi'an, especially for polluted episodes. More oxidized‑oxygenated organic aerosol (MO-OOA) and sulfate showed the dominant enhancements, especially in large particle-mode. Meanwhile, relative humidity (RH) showed a positive promotion on the formation of sulfate and MO-OOA during the lockdown, but had no obvious correlation with less oxidized‑oxygenated organic aerosol (LO-OOA) or nitrate. Organosulfurs (OS) displayed a higher contribution (~58%) than inorganic sulfate to total sulfate enhancement in the polluted episode during the lockdown. Although the total nitrate (TN) decreased during the lockdown ascribing to a larger reduction of inorganic nitrate, organic nitrate (ON) showed an obvious increase from pre-lockdown (0.5 ± 0.6 μg m-3 and 1 ± 2% of TN) to lockdown (5.3 ± 3.1 μg m-3 and 17 ± 9% of TN) in the polluted case (P less then 0.05). In addition, RH also displayed a positive promotion on the formation of ON and OS, and the increases of both OS and ON were much efficient in the nighttime than in the daytime. These results suggest that higher RH and stagnant meteorology might facilitate the sulfate and MO-OOA enhancement, especially in the nighttime, which dominated the secondary aerosol enhancement in haze pollution during the lockdown.Coastal beaches are a vital transitional zone in which terrestrial microplastics (MPs) enter the oceans. However, little is known about the impact of coastal currents on the dispersion and accumulation of MPs, especially in semi-enclosed bays. To address this knowledge gap, we investigated the spatiotemporal variation of MPs in the coastal sediments of Haizhou Bay. The abundance of MPs ranged from 10.94 n/kg to 1309.02 n/kg. Overall, a higher amount of MPs was found in intertidal sediment than in the supratidal zone. Significant seasonal variation was observed only in the intertidal areas of Haizhou Bay, suggesting that hydrodynamics plays a critical role shaping MP abundance. Statistical analyses revealed a roughly exponential increase of MP abundance with distance from the coast, and that a relatively higher abundance of MPs would be found at offshore sites in downstream areas. These results suggest that coastal currents are important contributors of MPs. A numerical model of vertical profiles estimated the total inventory of MPs in coastal areas to be 13.83-580 trillion pieces. Our results suggest a neglected sink of MPs in the sedimentary environments of coastal regions. As a result, the amount of MPs in coastal regions in previous studies could have been underestimated.Microorganisms in activated sludge are widely recognized for their roles in wastewater treatment. However, previous studies were mainly concerned with the diversity and driving factors of microbial communities within domestic wastewater treatment, and those of domestic wastewater treatment systems mixed with industrial wastewater are poorly understood. In this research, three different full-scale aerobic activated sludge (AS) wastewater treatment systems fed with municipal, textile-dyeing, and mixed wastewater, respectively, were monitored over the operation course of three months. 16S rRNA amplicon sequencing analysis revealed that the microbial communities in textile-dyeing wastewater activated sludge (AS) exhibited significantly lower richness and diversity (p less then 0.01, Adonis) compared to those fed with municipal wastewater. In contrast, textile-dyeing derived AS selectively enriched microbial taxa with aromatic degradation and denitrification potentials. Further, FARPROTAX and metabolomics indicated the inhibition of 72.
My Website: https://www.selleckchem.com/products/gw4869.html
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