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A direct spectropolarimetric analysis involving arabinose 5-phosphate isomerase.
A reaction mechanism for the synergistic removal of Pb(II) and phenol by SBC/US process involving in four stages-namely adsorption, precipitation, reduction and Fenton-like oxidation processes was proposed. This study demonstrates that SBC/US process could be considered as a potential candidate for the remediation of real wastewaters containing Pb(II) and phenol.An unusual mortality event (UME) attributed to morbillivirus infection was identified in two Guiana dolphin populations from the Southeastern Brazilian coast. The aim of this study was to characterize total mercury (THg), methylmercury (MeHg) and selenium (Se) bioaccumulation and body burden in Guiana dolphins from Sepetiba Bay (RJ) collected before (n = 61) and during the UME (n = 20). Significantly lower Se concentrations were found in the livers of individuals collected during the UME (Mann-Whitney test; p = 0.03), probably due to impairment of the detoxification process in the liver. There were differences in THg and Se concentrations in the organs and tissues of individuals (Kruskal-Wallis test, p less then 0.05), but not MeHg (Kruskal-Wallis test, p = 0.07). For THg, the liver showed the higher concentrations and differed among organs and tissues analyzed such as blubber (Tukey's test for unequal N; p = 0.003). For Se concentrations, the skin and kidney presented the higher concentrations and varied among other tissues/organs, like muscle (Tukey's test for unequal N; p = 0.02). Differences in body burdens were observed among specimens collected previously and during the UME probably due to the remobilization and transport of the muscle-stored MeHg to other tissues/organs. This abrupt input of MeHg into the bloodstream may cause serious health damage. Indeed, evidences of methylmercury intoxication was observed in Guiana dolphins in Sepetiba Bay. In conclusion, bioaccumulation patterns, the detoxification process and body burden were affected by morbillivirus.In the past 20 years, the discharge of pharmaceuticals and their presence in the aquatic environment have been continuously increasing and this has caused serious public health and environmental concerns. Antineoplastic drugs are used in chemotherapy, in large quantities worldwide, for the treatment of continuously increasing cancer cases. Antineoplastic drugs also contaminate water sources and possess mutagenic, cytostatic and eco-toxicological effects on microorganisms present in the aquatic environment as well as on human health. Due to the recalcitrant nature of antineoplastic drugs, the commonly used wastewater treatment processes are not able to eliminate these drugs. Globally, various anticancer drugs are being consumed during chemotherapy in hospitals and households by out-patients. These anti-cancer agents enter the water bodies in their original form or as metabolites via urine and faeces of the out-patients or the patients admitted in hospitals. Due to its high lipid solubility, the antineoplastic drugs accumulate in the fatty tissues of the organisms. These drugs enter through the food chain and cause adverse health effects on humans due to their cytotoxic and genotoxic properties. The United States Environmental Protection Agency (US-EPA) and the Organization for Economic Cooperation and Development (OECD) elucidated new regulations for the management of hazardous pharmaceuticals in the water environment. In this paper, the role of antineoplastic agents as emerging water contaminants, its transfer through the food chain, its eco-toxicological properties and effects, technological solutions and management aspects were reviewed.Perfluoroalkyl acids (PFAAs) have emerged as global concerning contaminants because of their persistence, bioaccumulation, and toxicological effects. The transport and fate of PFAAs on dimension of plain river networks (PRNs) are difficult to model due to the unique regional characteristics (i.e., undirectional flows, low slope, complicated structure and connectivity) and the lack of data on PFAAs concentrations and compositions. A typical PRN (Taihu Basin, China) was selected to elucidate the spatial patterns of PFAAs in multi-matrices, including colloidal phase, soluble phase, suspended particles, and sediment. PFAAs were ubiquitously detected in plain rivers with total concentrations of 18.48-1220 ng/L in colloids, 139.07-721.37 ng/L in soluble phase, 97.69-2247 ng/g dw in suspended particles, and functional connectivity (0.4780). click here These results suggested that the effects of catchment characteristics should be taken into account in understanding PFAAs fate in the PRNs.The activities of indigenous bacterial communities in polychlorinated biphenyls (PCBs) contaminated environments is closely related to the efficiency of bioremediation processes. Using resuscitation promoting factor (Rpf) from Micrococcus luteus is a promising method for resuscitation and stimulation of functional bacterial populations under stressful conditions. This study aims to use the Rpf to accelerate the biodegradation of Aroclor 1242, and explore putative PCB degraders which were resuscitated by Rpf addition. The Rpf-responsive bacterial populations were investigated using culture-dependent and culture-independent approaches, respectively. The results confirm that Rpf was capable of enhancing PCB degradation of enriched cultures from PCB-contaminated soils, and improving the activities of cultures with low tolerance to PCBs. High-throughput 16S rRNA analysis displays that the Rpf greatly altered the composition and abundance of bacterial populations in the phylum Proteobacteria. Identification of the resuscitated strains further suggests that the Rpf-responsive population was mostly represented by Sphingomonas and Pseudomonas, which are most likely the key PCB-degraders for enhanced biodegradation of PCBs.Removal of brominated flame retardants (BFRs) from polymers before disposal or recycling will alleviate negative environmental effects and ensure safe usage of recycled products. Extraction of BFRs in supercritical CO2 is appealing but also presents challenges to industries due to limited solubility and lack of kinetic studies. For a more comprehensive evaluation of supercritical extraction potentialities, we (i) developed an on-line pressure apparatus that is compatible with both the FTIR and UV-vis spectrometers to enable kinetic and thermodynamic studies; (ii) studied kinetic extraction involving three conventional and two novel BFRs as well as three typical polymeric matrix. Solubilities were determined using the gravimetric method or X-ray fluorescence. FTIR exhibited a superior applicability compared to UV-vis in the following BFR extraction's time-dependency binary and ternary systems. We observed that faster stirring speed, higher temperature, and finer particle size can accelerate the overall extraction kinetics.
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