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The results indicate that the ecological risk of CTC in the soil is possible and can be controlled by slurry pit farm practices.Ecological theories can be applied to improve agricultural sustainability. In our study, a core hypothesis behind this claim is that "selfish behaviour" of rice cultivars results in "aversion" to a toxic substance in a multi-cropping system. We studied Changliangyou 772, a low-cadmium rice cultivar, cultivated with 11 different rice cultivars in intercropping and mixed systems. Rice cultivars with medium grain yield, ranging from 25 to 45 g plant-1, had distinctly higher yields in mixtures. Rice varieties with lower grain cadmium concentrations in monocultures had greater reductions in grain cadmium in the mixtures. In the intercropping systems, the yields of Changliangyou 772 were positively correlated with those of the neighbouring rice cultivars, while the grain cadmium showed a negative correlation with the grain cadmium of intercrops in the monocultures. The neighbouring cultivars with low grain cadmium concentrations in the intercropping showed higher cadmium concentrations in the monocultures. The intercropping and mixtures reduced the grain cadmium in two ways 1) they increased the soil pH, resulting in lower cadmium bioavailability; and 2) they enhanced the iron plaque (Ip). However, a high Ip or cadmium concentration that was too high in the Ip weakened the Ip to block cadmium uptake by the roots.Understanding the behavior of heavy metals in wastewater is critical for the development of metal removal and detection techniques. In this study, we characterize the dynamic and evolving size and partitioning behavior of lead (Pb), cadmium (Cd), and arsenite (As(III)) throughout the wastewater treatment train (WWTT). Metal concentrations were determined in three size fractions (>0.45 μm, 0.45 μm - 5 kDa, and less then 5 kDa), and the partitioning/complexation of the metals was quantified for the less then 0.45 μm fraction. Cd was found to be highly mobile, with the fraction of dissolved Cd gradually increasing throughout the WWTT. As(III) was also highly mobile, with its size distribution and partitioning remaining largely steady, except when FeCl3 was used as a flocculation agent, which led to the formation of arsenic/iron complexes. However, Pb was found primarily in complex forms or adsorbed onto inorganic particulates. The WWTT had little impact on the size and partitioning of Pb, except that the formation of the Pb/iron complex occurred after flocculation with FeCl3. An increase of water hardness slightly increased the metals in the dissolved fraction. Overall, this study provides insight into the evolution of metals throughout the WWTT, offering guidance to users and researchers regarding their treatment and detection.Although it has recently been reported that notable amounts of rare earth elements (REEs) are present in the residual coal ash, little is currently known regarding the association of these elements with the coal ash matrix, thereby limiting the potential for extraction of REEs from coal ash. In this study, we analyzed the binding characteristics of REEs within coal ash via sequential extraction and examined REE recovery during a coal ash recycling process. Major components of coal ash were found to be mineral oxides, mainly composed of Si, Fe, Al, and Ca, and residual carbons. Bottom and fly ashes were found to contain 185.8 mg/kg and 179.2 mg/kg of REEs, respectively. Tessier sequential extraction confirmed that 85 % of REEs are included in the residual fraction of both bottom and fly ashes. Furthermore, BCR sequential extraction revealed that 60-70 % of REEs are contained within the residual fraction, thereby indicating that REEs are strongly bound in both bottom and fly ashes and the use of very strong acids is required for the thorough extraction of REEs from coal ash. Additionally, it was found that 46.3 % of REEs can be recovered from the wastewaters produced during the process of coal ash-derived zeolite synthesis.Microwave-assisted pyrolysis (MAP) of waste printed circuit boards (WPCB) was performed to investigate the characteristics of pyrolysis product and Br fixation. Pyrolysis conversion increased with increasing temperature, reaching 93.3 % at 650 °C. However, increasing heating time did not exhibit remarkable influence on pyrolysis conversion. CFT8634 At 350 °C, phenols were main compounds in the oil accounting for 91.15 %. As the temperature increased to 650 °C, polycyclic aromatic hydrocarbons and monocyclic aromatic hydrocarbons (except phenols) increased to 20.55 % and 19.03 %, respectively. Meanwhile, the total content of CO2, CO, CH4 and H2 in the non-condensable gases increased significantly. Addition of ZSM-5 and kaolin promoted the recombination reaction of pyrolysis products, increased the relative percentage of monocyclic aromatic hydrocarbons (except phenols) and C11-C20 compounds in the oil, and reduced non-condensable gases. The oxygen bomb-ion chromatography was used to evaluate the Br content of pyrolysis residues. Higher pyrolysis temperature enhanced transfer of Br to pyrolysis gas. K2CO3, Na2CO3 and NaOH reacted with hydrogen bromide to generate KBr and NaBr, which significantly improved the Br fixation efficiency of pyrolysis residues (i.e. from 29.11%-99.80%, 96.39 % and 86.69 %, respectively) and reduced Br content in pyrolysis gas.In this study, Pretilachlor polyurea microencapsulate suspension (PMS) with effective controlled release function was carefully prepared. Under the optimal conditions, wall material PM-200 dosage 4%, emulsifier T-60 dosage 4% with S-20 as solvent, the prepared PMS was demonstrated to have encapsulation efficiency approaching to 95.27 ± 0.57 % and high suspension rates of 97.33 ± 0.49 %. Afterwards, PMS was proved to possess average release rate reached to 85.56 %, 55.46 % and 15.85 % respectively in acidic, basic and natural medium. Subsequently, the herbicidal activity of PMS on barnyard grass and the growth safety of rice were evaluated. PMS showed enhanced herbicidal activity against barnyard grass and had lower toxicity to rice growth compared with technical pretilachlor at dose 270-540 g (a.i.)/hm2. In addition, the use safety of PMS was validated to be comparable to that of commercially available pretilachlor emulsifiable concentrate containing additive safener at dose 270-540 g (a.i.)/hm2. Moreover, inhibitory effect of PMS on rice growth was demonstrated to completely eliminated by cooperatively treatment with fenclorim.
My Website: https://www.selleckchem.com/products/cft8634.html
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