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A pH of 2 was the most appropriate for the adsorption experiments. The equilibrium data fitted pseudo-first-order kinetics and Freundlich models, while the thermodynamic parameters confirmed that the adsorption process was endothermic.It was found that mesoporous graphite carbon nitride (mpg-C3N4) prepared using melamine as the precursor and ammonium chloride as the bubble template, has good photocatalytic activity under visible light irradiation. In order to improve the photocatalytic performance of mpg-C3N4, it was combined with metal-organic framework ZIF-8. Taking tetracycline hydrochloride (TC) solution as a model pollutant, the photocatalytic activity of composites was studied to select the optimal composite ratio and pH value. The initial concentration of hydrogen peroxide and active oxidation species were also investigated. The results showed that when the loading of ZIF-8 was 40 wt%, the removal efficiency was the best and 74.8% of TC could be removed. The degradation efficiency of TC was negatively affected under extreme pH conditions, but the composite photocatalyst mpg-C3N4-ZIF-8 had a relatively higher degradation efficiency on TC at mild pH values (4-8). The removal efficiency was the best at pH 8, and 75.1% of TC could be removed; the adsorption capacity was 430.7 mg·g-1 and the photodegradation capacity was 548.6 mg·g-1. The order of active species affecting the photocatalytic degradation of TC by mpg-C3N4-ZIF-8 was hole > superoxide radical > hydroxyl radical.Pharmaceutical compounds contribute to the emerging pollutants in water and in many cases, they are not efficiently mineralized by conventional treatment methods. At the same time, landfills remain the main final destination of discarded drugs. In the present study, the mineralization of the Ibuprofen medicinal commercial product (Algofren®) in aqueous solutions using UV irradiation, hydrogen peroxide, titanium dioxide and ferric ions was examined. All experiments were conducted in a batch photoreactor operated for 120-150 min. The main target was to select the most effective operating conditions for the mineralization of the solutions treated. Single photolysis or TiO2 photocatalysis were proved inefficient in eliminating the total organic carbon (TOC). By adjusting the initial amounts of Ibuprofen product and hydrogen peroxide, 81% TOC removal was achieved after 120 min. Adding iron in the solution led to a higher mineralization degree, especially during the first 30 min of the process. Iron was shown also to decrease the environmental footprint of the process as expressed via the electric energy per order, EEo.The activated sludge process suffers from rapid load changes of ammonium (NH4), which may result in process failure during wastewater treatment. In this study, the response of activated sludge properties in terms of microfauna composition and sludge volume index (SVI5 and SVI30) on short-term increase of NH4 concentration (from 55 mg/l to 105 mg/l) was evaluated in batch scale reactors over 72 h. The results show that the first-step nitrification (NH4 transformation to nitrite (NO2)) was inhibited after 24 h, whereas the second-step nitrification (NO2 transformation to nitrate (NO3)) was not significantly affected. Sludge volume indices (sedimentation ability characteristics) SVI5 and SVI30 in the reactor with NH4-N shock concentration increased, whereas microfauna diversity decreased (Shannon-Weaver index decreased from 2.12 at 48 h to 1.23 at 72 h) leading to dominance of stalked ciliate Epistylis sp. IDE397 Notable changes in inorganic carbon concentration (IC) were observed, indicating that rapid decrease of IC concentration leads to nitrification inhibition and challenges the overall process recovery. To conclude, short-term exposure of about two times higher concentration of NH4 caused significant changes in activated sludge properties by inhibiting NH4-oxidizing bacteria, reducing sludge microfauna diversity and deteriorating sludge sedimentation ability.In an extensive monitoring programme, event mean concentrations of 12 heavy metals, 16 polycyclic aromatic hydrocarbons (PAH), nine pesticides/biocides, three pharmaceuticals, three benzotriazoles, acesulfame, and DEHP (di-(2-ethylhexyl)phthalate) were measured at 10 combined sewer overflow (CSO) facilities throughout Bavaria, Germany, for more than 110 overflow events. A harmonised approach with large volume samplers was used to produce volume-proportional event composite samples. A wide range of event durations and volumes was covered successfully. All substances analysed were detected in CSO samples and the majority were quantified in more than 80% of the samples. Our results confirm that CSOs need to be considered in the debate on micropollutant emissions, and knowledge regarding their concentrations at a regional level needs to be solidified. Distinct substance-specific patterns can be observed in the variability between events and sites as well as in a correlation analysis of substance concentrations. These trends underline the need for differentiation of the substances by their predominant sources, pathways, and transport behaviours. Compared to wastewater treatment plants, CSOs are an important pollution source especially for ubiquitous, primarily stormwater-transported pollutants, including substances causing failure to achieve good chemical status of surface waters, such as the uPBT (ubiquitous, persistent, bioaccumulative and toxic) substances Hg and PAH.Removal of an endocrine disrupting compound, Bisphenol A (BPA), from water was investigated using two treatment processes, UV/H2O2 advanced oxidation (AOP) and reverse osmosis (membrane separation). Furthermore, changes in estrogenic activity using in vitro yeast estrogen screen assay as well as the adsorption of BPA by the membrane surface were evaluated. The best UV/H2O2 performance was obtained using the highest established values of all parameters, reaching 48% BPA removal. Within the investigated conditions of the AOP, when lower doses of UV were used, a higher removal efficiency was achieved at a higher initial concentration of BPA. However, the same behavior was not observed for the highest UV dose, in which the removal efficiency was not dependent on BPA initial concentration. In both cases, removal efficiency increased as H2O2 concentration increased. The formation of estrogenic by-products was observed in UV/H2O2. The membrane rejection efficiency varied from 60% to 84% and all experiments showed adsorption of BPA by the membrane surface.
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