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Chain-End Consequences in Supramolecular Poly(ethylene glycerin) Polymers.
The ice giant planets provide some of the most interesting natural laboratories for studying the influence of large obliquities, rapid rotation, highly asymmetric magnetic fields and wide-ranging Alfvénic and sonic Mach numbers on magnetospheric processes. The geometries of the solar wind-magnetosphere interaction at the ice giants vary dramatically on diurnal timescales due to the large tilt of the magnetic axis relative to each planet's rotational axis and the apparent off-centred nature of the magnetic field. There is also a seasonal effect on this interaction geometry due to the large obliquity of each planet (especially Uranus). With in situ observations at Uranus and Neptune limited to a single encounter by the Voyager 2 spacecraft, a growing number of analytical and numerical models have been put forward to characterize these unique magnetospheres and test hypotheses related to the magnetic structures and the distribution of plasma observed. Yet many questions regarding magnetospheric structure and dynamics, magnetospheric coupling to the ionosphere and atmosphere, and potential interactions with orbiting satellites remain unanswered. find more Continuing to study and explore ice giant magnetospheres is important for comparative planetology as they represent critical benchmarks on a broad spectrum of planetary magnetospheric interactions, and provide insight beyond the scope of our own Solar System with implications for exoplanet magnetospheres and magnetic reversals. This article is part of a discussion meeting issue 'Future exploration of ice giant systems'.We aim at investigating whether the chemical composition of the outer region of the protosolar nebula can be consistent with current estimates of the elemental abundances in the ice giants. To do so, we use a self-consistent evolutionary disc and transport model to investigate the time and radial distributions of H2O, CO, CO2, CH3OH, CH4, N2 and H2S, i.e. the main O-, C-, N and S-bearing volatiles in the outer disc. We show that it is impossible to accrete a mixture composed of gas and solids from the disc with a C/H ratio presenting enrichments comparable to the measurements (approx. 70 times protosolar). We also find that the C/N and C/S ratios measured in Uranus and Neptune are compatible with those acquired by building blocks agglomerated from solids condensed in the 10-20 arb. units region of the protosolar nebula. By contrast, the presence of protosolar C/N and C/S ratios in Uranus and Neptune would imply that their building blocks agglomerated from particles condensed at larger heliocentric distances. Our study outlines the importance of measuring the elemental abundances in the ice giant atmospheres, as they can be used to trace the planetary formation location, the origin of their building blocks and/or the chemical and physical conditions of the protosolar nebula. This article is part of a discussion meeting issue 'Future exploration of ice giant systems'.Uranus and Neptune possess highly tilted/offset magnetic fields whose interaction with the solar wind shapes unique twin asymmetric, highly dynamical, magnetospheres. These radiate complex auroral emissions, both reminiscent of those observed at the other planets and unique to the ice giants, which have been detected at radio and ultraviolet (UV) wavelengths to date. Our current knowledge of these radiations, which probe fundamental planetary properties (magnetic field, rotation period, magnetospheric processes, etc.), still mostly relies on Voyager 2 radio, UV and in situ measurements, when the spacecraft flew by each planet in the 1980s. These pioneering observations were, however, limited in time and sampled specific solar wind/magnetosphere configurations, which significantly vary at various timescales down to a fraction of a planetary rotation. Since then, despite repeated Earth-based observations at similar and other wavelengths, only the Uranian UV aurorae have been re-observed at scarce occasions by the Hubble Space Telescope. These observations revealed auroral features radically different from those seen by Voyager 2, diagnosing yet another solar wind/magnetosphere configuration. Perspectives for the in-depth study of the Uranian and Neptunian auroral processes, with implications for exoplanets, include follow-up remote Earth-based observations and future orbital exploration of one or both ice giant planetary systems. This article is part of a discussion meeting issue 'Future exploration of ice giant systems'.Comparatively little is known about atmospheric chemistry on Uranus and Neptune, because remote spectral observations of these cold, distant 'Ice Giants' are challenging, and each planet has only been visited by a single spacecraft during brief flybys in the 1980s. Thermochemical equilibrium is expected to control the composition in the deeper, hotter regions of the atmosphere on both planets, but disequilibrium chemical processes such as transport-induced quenching and photochemistry alter the composition in the upper atmospheric regions that can be probed remotely. Surprising disparities in the abundance of disequilibrium chemical products between the two planets point to significant differences in atmospheric transport. The atmospheric composition of Uranus and Neptune can provide critical clues for unravelling details of planet formation and evolution, but only if it is fully understood how and why atmospheric constituents vary in a three-dimensional sense and how material coming in from outside the planet affects observed abundances. Future mission planning should take into account the key outstanding questions that remain unanswered about atmospheric chemistry on Uranus and Neptune, particularly those questions that pertain to planet formation and evolution, and those that address the complex, coupled atmospheric processes that operate on Ice Giants within our solar system and beyond. This article is part of a discussion meeting issue 'Future exploration of ice giant systems'.Future missions to an ice giant planet, especially orbital missions, are technologically challenging. But with one exception, radioisotope power sources (RPSs), the technologies that would enable such missions are currently available. RPSs are not a new technology, but devices used in the past that are appropriate to an ice giant mission are no longer available without engineering development work (currently unfunded), and it is uncertain whether the new NASA unit under development will be available for flight in time to take advantage of the best transfer trajectories of the next 15 years. This paper describes technologies already in hand that enable an ice giant mission, but for them to be useful they must be maintained. If an enabling technology is lost a replacement must be developed, potentially impacting the cost and schedule of a mission. In addition to the enabling technologies, there are a number of technologies that, while not enabling, could greatly enhance the science return and science value of a mission, making the programmatic aspects of approval an easier task and the funding of those development tasks a high priority.
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