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Microcystin-LR induces ferroptosis throughout gut associated with common carp (Cyprinus carpio).
The main focus of this study is the emission of monoaromatic hydrocarbons because these are the preliminary factors of potential solvent and monomer residues present in single-use plastic barbecue and kitchen utensils comprising polystyrene, polypropylene, natural cellulose, and biodegradable polymers intended for use with hot meal or beverages. Herein, the emissions of monoaromatic hydrocarbons (styrene, benzene, toluene, ethylbenzene, and xylene compounds and the total volatile organic compounds (TVOC)) from nine types of disposable plastic utensils are reported. Seventy two samples of single-use plastic utensils were conditioned at 40 and 80 °C using a stationary emission microchamber system. The average TVOC released from the studied polystyrene, polypropylene, and natural or biodegradable utensils were (2.3 ± 1.3), (1.01 ± 0.15), and (0.48 ± 0.37) μg g-1, respectively, at 40 °C and (11.1 ± 1.2), (46.1 ± 9.5), and (5.5 ± 1.1) μg g-1, respectively, at 80 °C. Significant emissions of styrene (ranged from 3.5 up to 15.3 × 103 ng∙g-1), toluene (from 2.8 up to 0.53 × 103 ng∙g-1), and ethylbenzene (from 3.7 up to 5.7 × 103 ng∙g-1) from the studied samples were observed, especially at 80 °C. Thus, elevated temperatures increase the potential emission of solvent and monomer residues from plastics and could affect the quality of consumed meals or beverages, such as taste. Additionally, to determine the possible interactions between the measured chemical compounds in the plastic utensils, the Pearson's correlation coefficients were calculated. Managers tasked with repairing degraded stream ecosystems require restoration strategies that are tailored to local and regional characteristics. Emerging evidence suggests that local reach-scale approaches may be as effective, if not more so, than catchment-scale actions in highly permeable coastal landscapes, particularly if there is hydraulic connectivity to shallow groundwater and where recharge is strongly seasonal. This study assessed the relative influence of catchment-scale land use and reach-scale vegetation structure on the distribution of carbon and nutrient concentrations of streams within urban and agricultural catchments of the Perth region of south-western Australia. We used linear mixed-effects models to evaluate the extent to which phosphorus, nitrogen and carbon concentrations in different stream zones (streamwater, and fluvial and parafluvial sediments) were explained by catchment and reach-scale attributes and moderated by high versus low-flow periods, i.e., in wet versus dry months. We found that reach-scale vegetation (woody plant cover, annual plant cover) was a better predictor of nutrient concentrations than catchment-scale land use, particularly total imperviousness, a common measure of urbanisation. Flow was also important, with carbon and nutrient concentrations better described by reach- or catchment-scale attributes during the low flow period. The extent to which individual catchment and reach attributes influenced the distribution of nutrients in different stream zones was complex. However, our results suggest that planting woody vegetation can reduce nitrogen concentrations in surface water and fluvial sediments. Reducing the abundance of weedy annual species and restoring woody perennial species may further reduce phosphorus concentrations in surface water. We conclude that local riparian restoration can be a cost-effective strategy for managing excess nutrients and carbon in flat and permeable urban landscapes, particularly during low flow periods. Citrobacter sp. R1, a highly efficient algicidal bacterium, undergoes a serious degeneration after long-term preservation. Here, we prepared a Li-doped up-conversion material ([Y2SiO5; Li (1%)]) to recover the degenerated Strain R1. As a result, the [Y2SiO5; Li (1%)] successfully enhanced the maximum algicidal activity of Strain R1 from 43.2 ± 1.2 to 72.5 ± 1.3%. In terms of recovery mechanisms, 1) the [Y2SiO5; Li (1%)] could convert visible light into UVC and UVA with unusual wavelengths, creating conditions for inducing reverse mutation in Strain R1, affecting the metabolism of Strain R1 and then recovering the bacterium; 2) the [Y2SiO5; Li (1%)] did not only enhance the secretion of 3-hydroxypropionic acid, the algicidal compound which Strain R1 continues to produce even after degeneration, but also it recovered the ability of Strain R1 to secrete three new algicidal compounds. This study provides a new idea of employing up-conversion material [Y2SiO5; Li (1%)] in microbial degeneration recovery. Oxygen can enter into reductive aquifer through natural and artificial processes. However, the joint response of groundwater chemistry and functional microbial communities to oxygenation is not well understood due to the gap between taxonomic and functional microbial composition. Here, two wells named CZK15 and CZK22 at the second confined aquifer in Central China were in situ aerated, and the chemical parameters of groundwater and microbial communities in bio-trapping sand sediment were analysed during aeration. The microbial metabolic functions related to C, N, S, Fe transformation were predicted by Functional Annotation of Prokaryotic Taxa (FAPROTAX) approach and some key functional genes, such as phe, nah, narG, and soxB were verified by the real-time quantitative Polymerase Chain Reaction (qPCR) method. The biomass was promoted, microbial diversity fluctuated, and microbial composition changed remarkably with aeration mainly constrained by reduction-oxidation (redox) variation and SO42- concentration. Ame increased Fe(III) oxides formation. The findings of this study could have important implications in understanding the biogeochemical behaviours with cyclic redox conditions. Active pharmaceutical ingredients, especially antibiotics, are micropollutants whose continuous flow into hydrological cycles has the potential to mediate antibiotic resistance in the environment and cause toxicity to sensitive organisms. Here, we investigated the levels of selected antibiotics in four wastewater treatment plants and the receiving water bodies. check details The measured environmental concentrations were compared with the proposed compound-specific predicted no-effect concentration for resistance selection values. The concentration of doxycycline, amoxicillin, sulfamethoxazole, trimethoprim, ciprofloxacin and norfloxacin within the influents, effluents, surface waters and river sediments ranged between 0.2 and 49.3 μgL-1, 0.1 to 21.4 μgL-1; ˂ 0.1 and 56.6 μgL-1; and 1.8 and 47.4 μgkg-1, respectively. Compared to the effluent concentrations, the surface waters upstream and downstream one of the four studied treatment plants showed two to five times higher concentrations of ciprofloxacin, norfloxacin and sulfamethoxazole.
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