Notes

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The hybrid surface expresses thermo-responsive properties and serves as a pattern to perfectly align and control the assembly of inorganic particles at the nanoscale.The vapor-liquid-solid (VLS) method is vastly employed to grow hierarchical structures with unique properties. However, key questions remain, such as what controls the branched structures and what the roles of the catalyst droplet size are during the growth. Here, an in-depth understanding of the kinetics of the nucleation, growth, and subsequent coalescence processes of Bi liquid catalyst droplets is provided by direct observation of PbSe branched wire growth in an environmental transmission electron microscope. This brings a kinetic control of the branch density by varying the parameters, such as temperature. In addition, the dependence of the wire growth rate on the catalyst droplet size is revealed, i.e., the smaller the catalyst size the larger the wire growth rate, unlike the wire growth controlled by the Gibbs-Thomson effect, possibly due to different mass transport pathways and atomic surface diffusion. These results extend the fundamental understanding of the VLS growth mechanism of branched structures and benefit the structure design of hierarchical materials with tailored properties.Efficient electrocatalysts are needed for both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), while the influence of electron transfer from the adjacent layer of multilayered electrocatalysts on their catalytic performance is usually neglected. Here, we used the single cobalt atom trapped graphyne catalyst (Co@GY) to study the feasibility of modulating its water-splitting catalytic activity through interfacial electron transfer. A series of Co@GY/transition-metal doped graphyne double-layered structures (Co@GY/GY and Co@GY/TM@GY, TM = Mn, Fe, Co, Ni, Cu) are systematically evaluated for water splitting via theoretical computations. The electronic structure analyses of different stacking cases revealed that the atomic metals on the adjacent TM@GY layer remarkably tune the electronic structures of the Co atom in the Co@GY layer. A strong linear correlation between ΔGH* and the d band center of the Co atom was found, suggesting that the HER activity on the Co atom can be tailored by adjusting the TM on the adjacent TM@GY layer with different d-electron occupations. The volcano-type trend of OER catalytic performance is obtained to show the best Co@GY/Ni@GY catalyst for the OER with an over-potential of 0.38 V, indicating that higher catalytic performance arises from moderate interfacial electron transfer. These results arouse a re-thinking of the intrinsic activity origins of single-atom catalysts (SACs) and offer a new strategy for the structure designing of SACs.Several studies published in the last decade suggest that the beneficial role of extra-virgin olive oil (EVOO) in human health is mostly attributable to the main secoiridoid derivatives (oleuropein, oleocanthal, and oleacein). Anti-cancer properties have also been demonstrated for certain compounds present in small quantities in EVOO, including oleuropein and hydroxytyrosol, which have been extensively studied, while minor attention has been given to the most abundant secoiridoid oleacein. The aim of our research was to study the molecular mechanisms underlying the anti-proliferative and anti-metastatic capacity of oleacein in the SH-SY5Y human neuroblastoma cell line. Our results demonstrate that oleacein is able to reduce the proliferation of the SH-SY5Y cells by blocking the cell cycle in the S phase and inducing apoptotic cell death through the increase in both Bax and p53 as well as a reduction in the Bcl-2 expression and STAT3 phosphorylation. Moreover, oleacein caused reduction in the SH-SY5Y cell adhesion and migration. Overall, these findings indicate that oleacein exerts anti-cancer effects against neuroblastoma cells, suggesting a promising role as a candidate against this type of cancer.In the last few decades, two-dimensional monolayer films of gold nanoparticles (2D MFGS) have attracted increasing attention in various fields, due to their superior attributes of macroscopic size and accessible fabrication, controllable electromagnetic enhancement, distinctive optical harvesting and electron transport capabilities. This review will focus on the recent progress of 2D monolayer films of gold nanoparticles in construction approaches, surface engineering strategies and functional applications in the optical and electric fields. The research challenges and prospective directions of 2D MFGS are also discussed. Bismuth subnitrate This review would promote a better understanding of 2D MFGS and establish a necessary bridge among the multidisciplinary research fields.The reaction of Co(OAc)2·4H2O with a sterically hindered phosphate ester, LH2, afforded a tetranuclear complex, [CoII(L)(CH3CN)]4·5CH3CN (1) [LH2 = 2,6-(diphenylmethyl)-4-isopropyl-phenyl phosphate]. The molecular structure of 1 reveals that it is a tetranuclear assembly where the Co(ii) centers are present in the alternate corners of a cube. The four Co(ii) centers are held together by four di-anionic [L]2- ligands. The fourth coordination site on Co(ii) is taken by an acetonitrile ligand. Changing the Co(ii) precursor from Co(OAc)2·4H2O to Co(NO3)2·6H2O afforded a mononuclear complex [CoII(LH)2(CH3CN)2(MeOH)2](MeOH)2 (2). In 2, the Co(ii) centre is surrounded by two monoanionic [LH]- ligands and a pair of methanol and acetonitrile solvents in a six-coordinate arrangement. 1 has been found to be an efficient catalyst for electrochemical water oxidation under highly basic conditions while the mononuclear analogue, 2, does not respond to electrochemical water oxidation. The tetranuclear catalyst has excellent electrochemical stability and longevity, as established by chronoamperometry and >1000 cycle durability tests under highly alkaline conditions. Excellent current densities of 1 and 10 mA cm-2 were achieved with overpotentials of 354 and 452 mV respectively. The turnover frequency of this catalyst was calculated to be 5.23 s-1 with an excellent faradaic efficiency of 97%, indicating the selective oxygen evolution reaction (OER) occurring with the aid of this catalyst. A mechanistic insight into the higher activity of complex 1 towards the OER compared to that of complex 2 is also provided using density functional theory based calculations.
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