Notes

Incline NMR Method for Studies of Water Translational Diffusion throughout Vegetation.
Mathematical modelling of biological treatment is an effective tool to predict effluent quality. Model calibration is critical to improve the accuracy of simulation, which is normally carried out by fine-tuning the values of parameters according to the practical data. It indicated that huge amount of practical date will be consumed, and it cannot predict the treatment performance of new wastewater. In this study, the main objective was to investigate the feasibility of application BioWin software coupled with determination of sensitive parameters to predict the treatment performance of membrane biological reactors (MBRs) treating real petrochemical wastewater (PW). Model calibrations, i.e., COD fractions of petrochemical wastewater and kinetic parameters of biomass, were carried out using the respirometry method and the relationship between observed and true growth yield coefficients of the three lab-scale MBRs which were operated under different solid retention time (SRT). All the three MBRs had good organic and ammonium removal, with removal efficiencies higher than 80% and 99.9%, respectively. Simulation using the calibrated model also obtained good fit for effluent COD concentration, effluent nitrate concentration and bioreactor's MLSS concentration of all the three MBRs. The mean absolute percentage errors (MAPE) of the simulation mostly were lower than 22%. The results indicated that it is feasible to using BioWin, incorporated with appropriate determination methods of sensitive parameters, to simulate and monitor the treatment performance of MBR treating petrochemical wastewater. This is more time-saving and effective than fine-tuning values of all parameters. This study provides a valuable reference for simulation of industrial wastewater treatment using BioWin.Given the large transformation and fast-growing population that the Greater Toronto Area (GTA) is facing, and the increasing impact of climate change in urbanized areas, it is crucial to investigate strategies that could mitigate the effects of heat waves. In this paper, the effects of greenery enhancements are investigated using mesoscale and microscale simulations performed by the Weather Research and Forecasting model and the ENVI-met model, respectively. In particular, two vulnerable areas located in the GTA are investigated. Comparing the results of simulations with measurements show the differences in how mesoscale and microscale models predict the meteorological processes happening within the urban canopy and the local climate. Then, two mitigation scenarios, a moderate green scenario (MGS) and an intensive green scenario (IGS) are assessed considering different increases in the vegetation area. The results of the mesoscale simulations show that by increasing the greenery canopy, the maximum daily air temperature decreases by 1.6 to 2.3 °C, while the relative humidity increases by 10% to 12%. The microscale simulations show that increasing the tree canopy would cool the air temperature by 0.5 °C to 1.4 °C locally. Overall, depending on wind conditions and the arrangement of buildings and existing green areas, the cooling effect is shown to have an impact on up to 250 m downwind from the new green area locations. Finally, this study demonstrates that both mesoscale (WRF) and microscale (ENVI-met) modeling confirm similar results in how greenery enhancements may improve the human thermal comfort in the continental climate of the GTA.To determine the effect of vitamin supplements on the oral bioaccessibility of Pb in soils, Pb bioaccessibility was measured in the presence of 9 vitamins by a physiologically based extraction test. Gastric Pb bioaccessibility (G-BA, 2.6-83.3%) was found to be mostly reduced (1.1-3.1 fold) in the presence of B vitamins, specifically vitamins B1, B6, and B9. In contrast, a significant increase in Pb G-BA was observed with vitamin C and E involved. In the small intestinal phases, Pb bioaccessibility (I-BA) ranged from 0.1% to 16.0%, being 5-50 fold lower than the corresponding G-BA values. Vitamin C supplementation showed a 7-fold increase in Pb I-BA, with a similar increase presented in approximately 30% of samples treated to vitamin B involvement. Lead liberation in gastrointestinal digests was associated with the dissolution of Fe and Mn regulated by vitamins. In conclusion, the addition of B vitamins resulted in the reduction of gastric Pb bioaccessibility, but the bioaccessibility value increased in participation of vitamin C and E. Elevated intestinal bioaccessibility was found especially for vitamin C. This should contribute to more accurate assessment of health risks from contaminated soils. Nutritional management aimed at preventing Pb-induced toxicity can benefit from knowledge of vitamin influence on soil Pb bioaccessibility.Mixed litter decomposition is a common phenomenon in nature and is very important for the circulation of material through an ecosystem. Different plant functional groups (PFGs) are likely to interact during decomposition. It is unclear how mixed decomposition influences the release of multiple metallic elements, and the biogeochemical circulation mechanism in the alpine ecosystem remains elusive. In this study, a two-year experiment on decomposition of mixed litter from six dominant PFGs was conducted at two elevations in an alpine timberline ecotone using the litterbag method. First, the results suggested that PFG identity had greater impacts on the release of all metallic elements than elevation. The release rates of potassium (K), calcium (Ca), magnesium (Mg) and copper (Cu) in graminoid, deciduous shrub and forb litter were significantly higher than those in evergreen conifer, evergreen shrub and mixed litter. Second, the release of metallic elements showed non-additive effects during mixed litter decomposition. K, Ca, Mg, sodium (Na), Cu, and aluminium (Al) exhibited antagonistic effects, while Fe exhibited a synergistic effect. The antagonistic effects on Na, K, Ca and Cu release increased with increasing elevation, while the antagonistic effects on Mg, Al and Mn release decreased with increasing elevation. Third, Al and Fe showed high levels of accumulation. The K release rate decreased while Al and Fe accumulation increased with plant litter upward shift. In conclusion, mixtures of PFGs inhibits the release of multiple metallic elements during litter decomposition in the alpine timberline ecotone. see more We speculate that an upward shift in PFGs in response to climate warming will slow the release of K and accelerate the enrichment of Fe and Al in alpine timberline ecotones.
Here's my website: https://www.selleckchem.com/products/azd9291.html