Notes

In direction of powerful offloading systems throughout mist precessing.
Oceanic processes such as coastal upwelling and mesoscale eddy, could influence the spatial distribution and environmental behaviors of semi-volatile organic pollutants in the marine environment. Seawater samples were collected from the full-depth water columns from the South China Sea (SCS), and PAH concentrations (∑14PAH) in the continental shelf and the open basin areas were 16-110 and 10-93 ng/L respectively. Results of isomeric ratios and principal component analysis illustrated PAHs' mixed sources (petrogenic and pyrogenic). PAH inventory of the SCS seawater was estimated as 100 ± 58 thousand tons, and the majority of them was stored in the intermediate and deep water masses. Generally, full-depth profiles of dissolved PAHs showed an "enrichment in surface and exhaustion in the deep" pattern, and this might be influenced by the oceanic processes such as coastal upwelling or eddy diffusion. In the cross-shelf area, upwelling could enhance the scavenging efficiency of PAHs on the upper layer, and increase the pollutant concentration in the medium and deep water. While in the open-basin area, PAHs were more likely influenced by the halocline stratification and eddy diffusion, and their vertical fluxes due to eddy diffusion was estimated to be 1.2 × 10-6 g s-1. This study highlighted the influences of oceanic processes in transport PAHs in the marginal sea, further study is needed to investigate their seasonal variations related to the monsoon characteristics.Neurotransmitters are endogenous metabolites that play a crucial role within an organism, at the chemical synapses. There is a growing interest in their analytical determination for understanding the neurotoxic effect of contaminants. Daphnia magna represents an excellent aquatic model for these environmental studies, due to its similarities with vertebrates in several neurotransmitters and related gene pathways and because of its wide application in ecotoxicological studies. Within this study, an accurate and sensible method of analysis of 17 neurotransmitters and related precursors and metabolites was developed. The method was validated in terms of sensitivity, reproducibility, precision, and accuracy, and also matrix effect was evaluated. As an independent probe of method validation and applicability, the method was applied to two different scenarios. First, it was used for the study of neurotransmitter levels in genetically mutated tryptophan hydrolase D. magna clones, confirming the absence of serotonin and its metabolite 5-HIAA. Additionally, the method was applied for determining the effects of chemical compounds known to affect different neurotransmitter systems and to alter Daphnia behavior. Significant changes were observed in 13 of the analyzed neurotransmitters across treatments, which were related to the neurotransmitter systems described as being affected by these neurochemicals. These two studies, which provide results on the ways in which the neurotransmitter systems in D. magna are affected, have corroborated the applicability of the presented method, of great importance due to the suitability of this organism for environmental neurotoxicity studies.This work develops a halophilic biocarriers-MBR for saline pharmaceutical wastewater treatment. The system has effectively treated the ampicillin-containing saline wastewater for 32 days, when the ampicillin concentration is lower than 20 mg/L. The system can tolerate the saline organic wastewater with a reasonable biodegradability (removals of COD over 75%) when the ampicillin concentration is 50 mg/L. The system has a bad performance in biodegradation (COD removals around 60-70%) and fouled within 16 days at a high ampicillin concentration of 100 mg/L. At high transmembrane pressures over 30 KPa, some ampicillin molecules may permeate through the membrane causing decreases in the ampicillin removal. The concentrations of protein and carbohydrate in EPS and SMP have increased over time and with increasing the ampicillin concentration. The method of biofouling control in MBR for the ampicillin situations has been proposed based on monitoring the concentrations of EPS and SMP. The drying-assisted monitoring of membrane biofoulants has showed a better efficiency than the monitoring of transmembrane pressure for membrane anti-biofouling in the treatment of pharmaceutical saline wastewaters where a spectroscopic detection can be hardly applied. This work may benefit relative research works for the control of biodegradation performance and membrane biofouling to better treat saline pharmaceutical wastewaters.Malathion is an organophosphorus insecticide and pesticide commonly used in crops and residential applications. The negative effects of Malathion on human health and ecosystems are of great concern. In this work, a mathematical model pivot on Fuzzy Cognitive Map (FCM) is used to analyse the causes and hazardous effects of Malathion to the environmental components (air, water and soil). Based on expert's opinion the possible factors that cause damage to health and ecosystems due to Malathion is identified, which serve as the input to the FCM. The FCM mathematically establishes the causal relation between these factors. The mathematical simulation is done by Python Programming. This approach can be used to study the interdependencies between the adverse effects of any pesticide in human health and environment due to prolonged exposure.In addition to nitrogen, carbonyl compounds such as formaldehyde, acetaldehyde, isobutyraldehyde and crotonaldehyde can be released from slow release fertilizers based on urea-aldehyde by hydrolytic or biotic processes. A possible relevance of such releases in the practical application of corresponding products was investigated in laboratory experiments. In the first part, emissions of organic compounds from the pure products were determined in desiccators under static conditions in dry and water-saturated air as well as during direct contact with water. Significant emissions of isobutyraldehyde were found for products containing isobutylidene diurea. Several formulations emitted acetaldehyde and formaldehyde, especially in the case of higher air humidity and when solved in water. Olaparib inhibitor However, crotonaldehyde was not detected in the desiccator air. Other organic components such as herbicides or their degradation products and nitrification inhibitors were released from fertilizers containing these compounds. In further experiments, sticks and granules were applied into potting soil and the release of organic compounds in emission chambers was examined under dynamic conditions.
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